SUPPLEMENTARY TABLE 1 OBSERVED WAVENUMBERS FOR THE B- X 0-0 TRANSITION OF CALCIUM METHOXIDE CaO12CH3 ISOTOPOLOGUE br wavenumber obs-calc N" P11 17682.1966 -0.0069 1 K' = K" = 0 17681.9626 -0.0057 2 17681.7332 -0.0031 3 17681.4999 -0.0073 4 17681.2727 -0.0085 5 17681.0474 -0.0108 6 17680.8277 -0.0105 7 17680.6099 -0.0114 8 17680.4012 -0.0063 9 17680.1917 -0.0049 10 17679.9823 -0.0066 11 17679.7735 -0.0106 12 17679.5738 -0.0086 13 17679.3759 -0.0078 14 17679.1838 -0.0043 15 17678.9894 -0.0061 16 17678.8053 -0.0006 17 17678.6168 -0.0025 18 17678.4355 -0.0003 19 17678.2572 0.0019 20 17678.0828 0.0049 21 17677.9205 0.0171 22 17677.7415 0.0095 23 17677.5771 0.0135 24 17677.4183 0.0201 25 17677.2602 0.0244 26 17677.1088 0.0323 27 R11 17682.6586 -0.0078 0 17682.8922 -0.0071 1 17683.1273 -0.0080 2 17683.3661 -0.0082 3 17683.6083 -0.0081 4 17683.8554 -0.0061 5 17684.1024 -0.0072 6 17684.3522 -0.0086 7 17684.6046 -0.0103 8 17684.8596 -0.0125 9 17685.1243 -0.0081 10 17685.3856 -0.0100 11 17685.6527 -0.0092 12 17685.9254 -0.0058 13 17686.1978 -0.0057 14 17686.4744 -0.0044 15 17686.7507 -0.0064 16 17687.0375 -0.0010 17 17687.3254 0.0026 18 17687.6093 -0.0009 19 17687.9005 0.0000 20 17688.2007 0.0069 21 17688.5012 0.0111 22 17688.8047 0.0153 23 17689.1126 0.0209 24 17689.4278 0.0308 25 P22 17681.9835 -0.0022 2 17681.7649 0.0001 3 17681.5477 0.0006 4 17681.3350 0.0027 5 17681.1221 0.0015 6 17680.9158 0.0039 7 17680.7110 0.0048 8 17680.5085 0.0050 9 17680.3141 0.0102 10 17680.1219 0.0146 11 17679.9287 0.0149 12 17679.7354 0.0122 13 17679.5535 0.0178 14 17679.3667 0.0155 15 17679.1838 0.0141 16 17679.0036 0.0124 17 17678.8326 0.0169 18 17678.6628 0.0196 19 17678.4887 0.0150 20 17678.3229 0.0157 21 17678.1567 0.0130 22 17677.9900 0.0068 23 17677.8306 0.0049 24 17677.6702 -0.0009 25 17677.5087 -0.0108 26 17677.3483 -0.0226 27 17677.1875 -0.0378 28 R22 17682.9251 -0.0020 1 17683.1726 -0.0017 2 17683.4258 0.0012 3 17683.6837 0.0058 4 17683.9423 0.0080 5 17684.2012 0.0076 6 17684.4645 0.0085 7 17684.7285 0.0071 8 17685.0001 0.0103 9 17685.2745 0.0133 10 17685.5463 0.0107 11 17685.8284 0.0154 12 17686.1097 0.0162 13 17686.3901 0.0132 14 17686.6760 0.0127 15 17686.9678 0.0152 16 17687.2600 0.0150 17 17687.5515 0.0112 18 17687.8488 0.0101 19 17688.1496 0.0097 20 17688.4505 0.0063 21 17688.7530 0.0017 22 17689.0562 -0.0053 23 17689.3611 -0.0135 24 17689.6665 -0.0241 25 17689.9731 -0.0364 26 ------------------------------------------------- P11 17681.9505 -0.0024 2 K' = K" = 1 17681.7167 -0.0026 3 17681.4834 -0.0061 4 17681.2552 -0.0078 5 17681.0305 -0.0092 6 17680.8096 -0.0100 7 17680.5932 -0.0093 8 17680.3790 -0.0095 9 17680.1711 -0.0065 10 17679.9626 -0.0071 11 17679.7549 -0.0100 12 17679.5535 -0.0096 13 17679.3564 -0.0080 14 17679.1609 -0.0078 15 17678.9692 -0.0068 16 17678.7818 -0.0046 17 17678.5960 -0.0038 18 17678.4113 -0.0050 19 17678.2341 -0.0016 20 17678.0589 0.0007 21 17677.8876 0.0039 22 R11 17682.8756 -0.0068 1 17683.1102 -0.0074 2 17683.3487 -0.0075 3 17683.5894 -0.0085 4 17683.8370 -0.0058 5 17684.0850 -0.0057 6 17684.3374 -0.0043 7 17684.5849 -0.0109 8 17684.8405 -0.0124 9 17685.1042 -0.0088 10 17685.3677 -0.0085 11 17685.6306 -0.0118 12 17685.9048 -0.0069 13 17686.1765 -0.0074 14 17686.4501 -0.0091 15 17686.7306 -0.0068 16 17687.0145 -0.0042 17 17687.3020 -0.0010 18 17687.5872 -0.0031 19 17687.8784 -0.0022 20 17688.1750 0.0011 21 P22. 17681.7394 -0.0010 3 17681.5236 -0.0005 4 17681.3108 0.0007 5 17681.0992 0.0004 6 17680.8936 0.0032 7 17680.6876 0.0026 8 17680.4849 0.0024 9 17680.2911 0.0081 10 17680.0996 0.0131 11 17679.9027 0.0097 12 17679.7130 0.0105 13 17679.5257 0.0107 14 17679.3400 0.0095 15 17679.1609 0.0118 16 17678.8053 0.0102 18 17678.6287 0.0061 19 17678.4559 0.0027 20 17678.2864 -0.0003 21 17678.1126 -0.0106 22 17677.9434 -0.0193 23 R22 17682.8993 -0.0031 1 17683.1494 -0.0019 2 17683.4016 -0.0008 3 17683.6610 0.0049 4 17683.9193 0.0065 5 17684.1778 0.0055 6 17684.4421 0.0073 7 17684.7048 0.0045 8 17684.9773 0.0085 9 17685.2500 0.0097 10 17685.5232 0.0084 11 17685.8035 0.0113 12 17686.0842 0.0115 13 17686.3629 0.0068 14 17686.6506 0.0081 15 17686.9401 0.0082 16 17687.2300 0.0057 17 17687.5202 0.0006 18 17687.8117 -0.0062 19 17688.1076 -0.0116 20 17688.4025 -0.0209 21 --------------------------------------------------- P11 17681.4303 -0.0062 4 K' = K" = 2 17681.2048 -0.0039 5 17680.9787 -0.0058 6 17680.7582 -0.0055 7 17680.5455 -0.0006 8 17680.3310 -0.0008 9 17679.4851 -0.0203 13 17679.2940 -0.0126 14 17679.1010 -0.0097 15 R11. 17683.0601 -0.0045 2 17683.2956 -0.0061 3 17683.5371 -0.0054 4 17683.7832 -0.0035 5 17684.0336 -0.0005 6 17684.2861 0.0013 7 17685.2997 -0.0185 11 17685.5693 -0.0150 12 17685.8469 -0.0064 13 17686.1174 -0.0080 14 P22 17681.6633 -0.0032 3 17681.4501 -0.0050 4 17679.8520 0.0212 12 17679.6561 0.0156 13 17679.4596 0.0064 14 17679.2708 0.0019 15 R22 17683.0766 -0.0055 2 17685.7339 0.0039 12 17686.0136 0.0030 13 17686.2854 -0.0087 14 17686.5607 -0.0199 15 17688.2982 -0.0636 21 17688.6044 -0.0646 22 --------------------------------------------------- P11 17680.6745 0.0038 7 K' = K" = 3 17680.4594 0.0070 8 17680.2510 0.0135 9 17680.0418 0.0160 10 17679.8379 0.0205 11 17679.6356 0.0235 12 17679.4355 0.0255 13 17679.2421 0.0311 14 R11 17683.7005 0.0070 5 17683.9470 0.0069 6 17684.2010 0.0109 7 17684.4588 0.0154 8 17684.7119 0.0121 9 17684.9779 0.0184 10 17685.2474 0.0252 11 17685.5157 0.0276 12 P22 17680.9283 0.0034 6 17680.7285 0.0094 7 17680.5233 0.0079 8 17680.3275 0.0132 9 R22 17683.4900 0.0083 4 17683.7495 0.0087 5 17684.0126 0.0104 6 17684.2724 0.0064 7 ======================================================================================= =======================================================================================