Appendix to: High-resolution synchrotron far infrared spectroscopy of acrolein: the vibrational levels below 700 cm-1 by A.R.W. McKellar and D.R.T. Appadoo Table A8. Observed transitions and assignments in the 13(1)18(2) - 18(2) hot band of acrolein (Obs and Obs-Calc in units of (1/cm)). Note: When Kc'=Kc"=0, it means that the observed line was fitted to the mean of the unresolved asymmetry doublet. -------------------------------------------------------------- J' Ka' Kc' J" Ka" Kc" Obs Obs-Calc Weight -------------------------------------------------------------- 6 5 0 7 6 0 311.49109 0.00009 0.10 8 5 0 9 6 0 310.89196 0.00006 0.10 10 5 0 11 6 0 310.29235 0.00000 1.00 11 5 0 12 6 0 309.99245 0.00002 1.00 12 5 0 13 6 0 309.69238 -0.00004 1.00 13 5 0 14 6 0 309.39228 -0.00006 1.00 14 5 0 15 6 0 309.09222 0.00001 0.00 15 5 0 16 6 0 308.79201 -0.00001 1.00 16 5 0 17 6 0 308.48995 -0.00185 0.00 18 5 0 19 6 0 307.89116 -0.00016 1.00 19 5 0 20 6 0 307.59096 -0.00013 1.00 21 5 0 22 6 0 306.99080 0.00003 1.00 22 5 0 23 6 0 306.69060 -0.00011 1.00 23 5 0 24 6 0 306.39076 0.00000 1.00 24 5 0 25 6 0 306.09099 0.00006 1.00 25 5 0 26 6 0 305.79133 0.00008 1.00 14 5 0 13 4 0 344.51480 0.00016 0.00 7 6 0 8 7 0 308.92136 -0.00004 1.00 8 6 0 9 7 0 308.62192 0.00011 1.00 9 6 0 10 7 0 308.32204 -0.00007 1.00 10 6 0 11 7 0 308.02230 0.00000 1.00 11 6 0 12 7 0 307.72251 0.00013 1.00 12 6 0 13 7 0 307.42220 -0.00016 1.00 13 6 0 14 7 0 307.12233 0.00008 1.00 14 6 0 15 7 0 306.82209 0.00003 1.00 15 6 0 16 7 0 306.52197 0.00018 1.00 16 6 0 17 7 0 306.22131 -0.00015 1.00 17 6 0 18 7 0 305.92100 -0.00006 0.00 18 6 0 19 7 0 305.62065 0.00003 1.00 19 6 0 20 7 0 305.32002 -0.00013 1.00 20 6 0 21 7 0 305.01971 0.00006 1.00 21 6 0 22 7 0 304.71926 0.00011 1.00 22 6 0 23 7 0 304.41865 0.00001 1.00 23 6 0 24 7 0 304.11810 -0.00006 0.10 24 6 0 25 7 0 303.81790 0.00020 1.00 25 6 0 26 7 0 303.51735 0.00006 1.00 26 6 0 27 7 0 303.21690 -0.00005 1.00 27 6 0 28 7 0 302.91690 0.00022 0.10 7 7 0 8 8 0 306.69662 0.00001 0.10 9 7 0 10 8 0 306.09753 0.00003 1.00 10 7 0 11 8 0 305.79778 -0.00001 1.00 11 7 0 12 8 0 305.49803 0.00005 1.00 12 7 0 13 8 0 305.19822 0.00015 1.00 16 7 0 17 8 0 303.99763 0.00003 1.00 17 7 0 18 8 0 303.69735 0.00005 1.00 18 7 0 19 8 0 303.39697 0.00003 1.00 20 7 0 21 8 0 302.79616 0.00008 1.00 21 7 0 22 8 0 302.49570 0.00011 0.10 22 7 0 23 8 0 302.19499 -0.00010 1.00 23 7 0 24 8 0 301.89437 -0.00019 1.00 24 7 0 25 8 0 301.59415 0.00011 1.00 27 7 0 28 8 0 300.69280 0.00027 0.10 9 7 0 8 6 0 349.17986 0.00000 1.00 10 7 0 9 6 0 349.47740 0.00016 1.00 11 7 0 10 6 0 349.77457 0.00008 1.00 14 7 0 13 6 0 350.66533 -0.00011 1.00 16 7 0 15 6 0 351.25878 0.00009 1.00 17 7 0 16 6 0 351.55500 -0.00008 1.00 8 8 0 9 9 0 304.21741 0.00007 1.00 9 8 0 10 9 0 303.91791 0.00010 0.10 10 8 0 11 9 0 303.61817 -0.00001 1.00 11 8 0 12 9 0 303.31837 -0.00009 1.00 12 8 0 13 9 0 303.01858 -0.00007 1.00 13 8 0 14 9 0 302.71874 -0.00001 1.00 14 8 0 15 9 0 302.41879 0.00002 1.00 15 8 0 16 9 0 302.11870 -0.00002 1.00 16 8 0 17 9 0 301.81841 -0.00018 1.00 17 8 0 18 9 0 301.51826 -0.00014 1.00 18 8 0 19 9 0 301.21810 -0.00005 0.10 19 8 0 20 9 0 300.91780 -0.00004 0.10 23 8 0 24 9 0 299.71628 0.00007 1.00 24 8 0 25 9 0 299.41571 -0.00003 1.00 25 8 0 26 9 0 299.11523 -0.00003 1.00 26 8 0 27 9 0 298.81474 -0.00004 1.00 27 8 0 28 9 0 298.51425 -0.00006 0.00 29 8 0 30 9 0 297.91338 -0.00006 0.00 30 8 0 30 9 0 306.87023 -0.00010 0.10 31 8 0 31 9 0 306.86884 0.00013 0.10 32 8 0 32 9 0 306.86696 -0.00020 0.10 33 8 0 33 9 0 306.86574 0.00005 0.10 34 8 0 34 9 0 306.86437 0.00005 0.10 35 8 0 35 9 0 306.86292 -0.00014 0.10 9 9 0 10 10 0 301.78506 -0.00009 1.00 10 9 0 11 10 0 301.48551 -0.00007 1.00 11 9 0 12 10 0 301.18583 -0.00008 1.00 12 9 0 13 10 0 300.88616 0.00000 1.00 13 9 0 14 10 0 300.58625 -0.00008 1.00 16 9 0 17 10 0 299.68637 -0.00002 1.00 17 9 0 18 10 0 299.38616 -0.00011 1.00 18 9 0 19 10 0 299.08582 -0.00027 1.00 22 9 0 23 10 0 297.88489 -0.00002 1.00 23 9 0 24 10 0 297.58450 -0.00003 0.10 24 9 0 25 10 0 297.28409 -0.00003 1.00 25 9 0 26 10 0 296.98378 0.00009 1.00 28 9 0 29 10 0 296.08249 0.00008 1.00 29 9 0 30 10 0 295.78194 -0.00006 1.00 9 9 0 8 8 0 355.52135 0.00027 0.00 13 9 0 12 8 0 356.71197 0.00015 1.00 14 9 0 13 8 0 357.00934 0.00005 1.00 15 9 0 14 8 0 357.30641 -0.00026 1.00 16 9 0 15 8 0 357.60403 0.00008 1.00 18 9 0 17 8 0 358.19835 0.00014 1.00 10 10 0 11 11 0 299.40294 0.00001 1.00 11 10 0 12 11 0 299.10333 0.00004 1.00 12 10 0 13 11 0 298.80281 -0.00075 0.10 13 10 0 14 11 0 298.50400 0.00024 1.00 14 10 0 15 11 0 298.20379 -0.00009 1.00 15 10 0 16 11 0 297.90391 -0.00002 1.00 16 10 0 17 11 0 297.60389 -0.00003 1.00 17 10 0 18 11 0 297.30384 0.00000 1.00 18 10 0 19 11 0 297.00368 -0.00002 1.00 19 10 0 20 11 0 296.70371 0.00020 1.00 20 10 0 21 11 0 296.40318 -0.00008 1.00 21 10 0 22 11 0 296.10316 0.00018 1.00 23 10 0 24 11 0 295.50233 0.00003 1.00 24 10 0 25 11 0 295.20197 0.00005 1.00 26 10 0 27 11 0 294.60100 -0.00011 1.00 27 10 0 28 11 0 294.30067 -0.00003 1.00 15 10 0 14 9 0 360.55582 -0.00004 1.00 16 10 0 15 9 0 360.85277 -0.00050 0.10 17 10 0 16 9 0 361.15093 0.00033 0.10 12 11 0 13 12 0 296.77375 0.00008 0.10 13 11 0 14 12 0 296.47388 0.00002 1.00 14 11 0 15 12 0 296.17397 0.00000 1.00 16 11 0 17 12 0 295.57406 0.00007 1.00 17 11 0 18 12 0 295.27390 0.00000 1.00 18 11 0 19 12 0 294.97376 0.00000 1.00 19 11 0 20 12 0 294.67356 0.00001 1.00 20 11 0 21 12 0 294.37333 0.00003 1.00 21 11 0 22 12 0 294.07306 0.00006 1.00 24 11 0 25 12 0 293.17196 0.00008 1.00 25 11 0 26 12 0 292.87148 0.00002 1.00 26 11 0 27 12 0 292.57098 -0.00003 1.00 27 11 0 28 12 0 292.27045 -0.00012 1.00 29 11 0 30 12 0 291.66972 0.00005 0.10 12 12 0 13 13 0 294.79867 0.00001 1.00 13 12 0 14 13 0 294.49888 0.00007 1.00 14 12 0 15 13 0 294.19899 0.00011 1.00 15 12 0 16 13 0 293.89887 -0.00001 1.00 16 12 0 17 13 0 293.59881 0.00000 1.00 17 12 0 18 13 0 293.29868 0.00001 1.00 18 12 0 19 13 0 292.99848 0.00001 1.00 19 12 0 20 13 0 292.69801 -0.00020 0.10 20 12 0 21 13 0 292.39848 0.00058 0.10 22 12 0 23 13 0 291.79715 0.00003 0.10 23 12 0 24 13 0 291.49666 -0.00001 1.00 24 12 0 25 13 0 291.19606 -0.00013 0.10 26 12 0 27 13 0 290.59511 -0.00003 0.10 28 12 0 29 13 0 289.99390 -0.00014 0.10 29 12 0 30 13 0 289.69327 -0.00021 0.10 13 13 0 14 14 0 292.58004 0.00000 1.00 14 13 0 15 14 0 292.28006 0.00008 1.00 15 13 0 16 14 0 291.97977 -0.00006 1.00 18 13 0 19 14 0 291.07877 -0.00012 1.00 19 13 0 20 14 0 290.77865 0.00023 1.00 21 13 0 22 14 0 290.17758 0.00032 0.10 23 13 0 24 14 0 289.57572 -0.00008 1.00 24 13 0 25 14 0 289.27496 0.00000 0.00 25 13 0 26 14 0 288.97407 0.00004 1.00 16 14 0 17 15 0 289.81739 -0.00016 1.00 17 14 0 18 15 0 289.51707 -0.00008 1.00 18 14 0 19 15 0 289.21659 -0.00008 0.00 19 14 0 20 15 0 288.91605 -0.00007 1.00 20 14 0 21 15 0 288.61555 0.00005 1.00 21 14 0 22 15 0 288.31478 -0.00004 1.00 22 14 0 23 15 0 288.01409 0.00002 0.10 23 14 0 24 15 0 287.71305 -0.00022 0.10 24 14 0 25 15 0 287.41225 -0.00016 0.00 25 14 0 26 15 0 287.11145 -0.00006 0.10 26 14 0 27 15 0 286.81048 -0.00008 0.10 27 14 0 28 15 0 286.50947 -0.00011 0.10 28 14 0 29 15 0 286.20851 -0.00005 0.10 16 15 0 17 16 0 288.01194 -0.00005 1.00 17 15 0 18 16 0 287.71139 0.00008 1.00 18 15 0 19 16 0 287.41062 0.00007 1.00 19 15 0 20 16 0 287.10971 -0.00002 1.00 20 15 0 21 16 0 286.80886 0.00002 1.00 21 15 0 22 16 0 286.50788 -0.00001 1.00 22 15 0 23 16 0 286.20700 0.00012 0.10 23 15 0 24 16 0 285.90588 0.00006 1.00 16 16 0 17 17 0 286.26881 -0.00004 1.00 17 16 0 18 17 0 285.97566 -0.00001 1.00 19 16 0 20 17 0 285.39840 -0.00007 1.00 --------------------------------------------------------------