Appendix to: High-resolution synchrotron far infrared spectroscopy of acrolein: the vibrational levels below 700 cm-1 by A.R.W. McKellar and D.R.T. Appadoo Table A6. Observed transitions and assignments in the 18(4) - 18(3) hot band of acrolein (Obs and Obs-Calc in units of (1/cm)). Note: When Kc'=Kc"=0, it means that the observed line was fitted to the mean of the unresolved asymmetry doublet. -------------------------------------------------------------- J' Ka' Kc' J" Ka" Kc" Obs Obs-Calc Weight -------------------------------------------------------------- 5 0 5 5 1 5 151.47988 -0.00106 0.00 7 0 7 7 1 7 151.56802 -0.00069 0.00 8 0 8 8 1 8 151.62076 0.00002 1.00 9 0 9 9 1 9 151.67677 -0.00073 0.10 10 0 10 10 1 10 151.73763 -0.00073 0.10 11 0 11 11 1 11 151.80262 -0.00006 1.00 12 0 12 12 1 12 151.86984 0.00006 1.00 13 0 13 13 1 13 151.93899 0.00005 1.00 14 0 14 14 1 14 152.00966 0.00020 1.00 15 0 15 15 1 15 152.08055 -0.00012 0.10 16 0 16 16 1 16 152.15193 0.00000 1.00 17 0 17 17 1 17 152.22193 -0.00071 0.10 18 0 18 18 1 18 152.29242 0.00011 1.00 20 0 20 20 1 20 152.42692 -0.00002 1.00 21 0 21 21 1 21 152.49136 0.00002 1.00 22 0 22 22 1 22 152.55351 -0.00007 0.10 23 0 23 23 1 23 152.61358 -0.00003 1.00 24 0 24 24 1 24 152.67146 0.00002 1.00 25 0 25 25 1 25 152.72722 0.00005 1.00 26 0 26 26 1 26 152.78105 0.00014 1.00 27 0 27 27 1 27 152.83296 0.00013 1.00 28 0 28 28 1 28 152.88312 -0.00001 1.00 29 0 29 29 1 29 152.93195 -0.00006 1.00 30 0 30 30 1 30 152.97967 -0.00001 1.00 31 0 31 31 1 31 153.02633 -0.00002 1.00 32 0 32 32 1 32 153.07224 0.00002 1.00 33 0 33 33 1 33 153.11749 -0.00001 0.10 34 0 34 34 1 34 153.16230 -0.00006 1.00 35 0 35 35 1 35 153.20695 -0.00004 1.00 36 0 36 36 1 36 153.25155 0.00002 1.00 37 0 37 37 1 37 153.29605 -0.00008 1.00 38 0 38 38 1 38 153.34093 0.00001 1.00 39 0 39 39 1 39 153.38586 -0.00015 1.00 40 0 40 40 1 40 153.43156 0.00005 1.00 12 1 11 12 2 11 149.28020 0.00002 0.00 13 1 12 13 2 12 149.36869 0.00004 1.00 15 1 14 15 2 14 149.56345 -0.00011 1.00 17 1 16 17 2 16 149.78078 -0.00008 1.00 18 1 17 18 2 17 149.89722 0.00003 1.00 19 1 18 19 2 18 150.01820 0.00004 1.00 20 1 19 20 2 19 150.14335 -0.00004 1.00 21 1 20 21 2 20 150.27246 0.00005 0.10 22 1 21 22 2 21 150.40479 0.00005 0.10 24 1 23 24 2 23 150.67706 -0.00009 0.00 25 1 24 25 2 24 150.81613 0.00011 1.00 26 1 25 26 2 25 150.95577 -0.00006 1.00 27 1 26 27 2 26 151.09591 0.00001 1.00 28 1 27 28 2 27 151.23552 -0.00003 1.00 29 1 28 29 2 28 151.37413 0.00002 1.00 30 1 29 30 2 29 151.51107 0.00015 1.00 32 1 31 32 2 31 151.77669 -0.00015 1.00 33 1 32 33 2 32 151.90487 0.00001 1.00 34 1 33 34 2 33 152.02899 -0.00001 1.00 35 1 34 35 2 34 152.14895 0.00004 1.00 37 1 36 37 2 36 152.37516 0.00005 1.00 38 1 37 38 2 37 152.48125 0.00006 1.00 39 1 38 39 2 38 152.58261 0.00002 1.00 40 1 39 40 2 39 152.67946 0.00005 1.00 6 1 6 6 0 6 153.82319 -0.00037 0.10 7 1 7 7 0 7 153.78909 -0.00002 0.10 8 1 8 8 0 8 153.75119 -0.00002 0.10 9 1 9 9 0 9 153.71046 0.00004 0.10 10 1 10 10 0 10 153.66780 0.00042 0.10 11 1 11 11 0 11 153.62282 0.00005 1.00 12 1 12 12 0 12 153.57750 0.00021 0.10 13 1 13 13 0 13 153.53162 -0.00007 0.10 14 1 14 14 0 14 153.48668 0.00000 1.00 15 1 15 15 0 15 153.44334 0.00035 0.10 16 1 16 16 0 16 153.40057 -0.00071 0.01 17 1 17 17 0 17 153.36211 -0.00005 0.10 18 1 18 18 0 18 153.32617 0.00000 1.00 19 1 19 19 0 19 153.29367 -0.00007 1.00 20 1 20 20 0 20 153.26528 0.00004 1.00 21 1 21 21 0 21 153.24094 0.00004 1.00 22 1 22 22 0 22 153.22093 0.00004 1.00 23 1 23 23 0 23 153.20531 0.00003 1.00 24 1 24 24 0 24 153.19399 -0.00007 1.00 25 1 25 25 0 25 153.18718 0.00002 1.00 26 1 26 26 0 26 153.18448 0.00003 1.00 28 1 28 28 0 28 153.19096 -0.00002 1.00 29 1 29 29 0 29 153.19976 -0.00006 1.00 30 1 30 30 0 30 153.21199 -0.00011 1.00 31 1 31 31 0 31 153.22761 0.00000 0.10 32 1 32 32 0 32 153.24614 -0.00001 1.00 33 1 33 33 0 33 153.26754 0.00002 1.00 34 1 34 34 0 34 153.29155 0.00001 1.00 35 1 35 35 0 35 153.31801 -0.00002 1.00 36 1 36 36 0 36 153.34680 -0.00003 1.00 37 1 37 37 0 37 153.37769 -0.00012 1.00 38 1 38 38 0 38 153.41091 0.00007 1.00 39 1 39 39 0 39 153.44599 0.00021 1.00 40 1 40 40 0 40 153.48301 0.00046 0.10 16 2 14 16 3 14 146.32573 0.00006 0.10 17 2 15 17 3 15 146.38814 0.00000 0.10 19 2 17 19 3 17 146.53879 0.00002 0.10 21 2 19 21 3 19 146.72540 0.00001 0.10 22 2 20 22 3 20 146.83213 -0.00032 0.10 23 2 21 23 3 21 146.94877 0.00015 1.00 24 2 22 24 3 22 147.07364 -0.00012 1.00 25 2 23 25 3 23 147.20760 -0.00002 1.00 26 2 24 26 3 24 147.34957 -0.00034 0.10 31 2 29 31 3 29 148.17493 0.00005 0.10 33 2 31 33 3 31 148.55432 -0.00033 0.10 15 2 14 15 1 14 155.75721 0.00016 1.00 17 2 16 17 1 16 155.58705 0.00006 1.00 18 2 17 18 1 17 155.49670 0.00012 1.00 19 2 18 19 1 18 155.40307 0.00000 1.00 20 2 19 20 1 19 155.30699 0.00009 1.00 22 2 21 22 1 21 155.10848 0.00002 1.00 23 2 22 23 1 22 155.00726 -0.00002 0.10 24 2 23 24 1 23 154.90548 -0.00010 1.00 25 2 24 25 1 24 154.80400 -0.00001 1.00 26 2 25 26 1 25 154.70309 -0.00015 1.00 27 2 26 27 1 26 154.60394 -0.00003 1.00 28 2 27 28 1 27 154.50690 -0.00002 1.00 29 2 28 29 1 28 154.41282 0.00002 1.00 30 2 29 30 1 29 154.32227 -0.00003 1.00 31 2 30 31 1 30 154.23619 0.00012 0.10 32 2 31 32 1 31 154.15468 -0.00004 1.00 33 2 32 33 1 32 154.07886 0.00005 1.00 34 2 33 34 1 33 154.00867 -0.00011 1.00 35 2 34 35 1 34 153.94502 0.00001 1.00 37 2 36 37 1 36 153.83720 -0.00009 0.10 38 2 37 38 1 37 153.79359 -0.00002 0.10 39 2 38 39 1 38 153.75684 0.00011 0.10 40 2 39 40 1 39 153.72650 -0.00007 1.00 18 2 16 17 1 16 161.39608 -0.00043 0.00 19 2 17 18 1 17 161.69541 -0.00020 0.00 21 2 19 20 1 19 162.32132 0.00004 1.00 25 2 23 24 1 23 163.70360 -0.00002 0.10 26 2 24 25 1 24 164.08021 -0.00006 0.10 27 2 25 26 1 25 164.47047 0.00002 0.10 29 2 27 28 1 27 165.29295 -0.00035 0.10 3 3 0 4 4 0 142.04326 -0.00003 0.00 4 3 0 5 4 0 141.74713 -0.00001 0.00 7 3 0 8 4 0 140.86350 -0.00006 0.10 4 4 0 5 5 0 138.88570 -0.00005 0.10 5 4 0 6 5 0 138.59033 -0.00002 1.00 6 4 0 7 5 0 138.29568 -0.00005 1.00 7 4 0 8 5 0 138.00187 -0.00003 1.00 8 4 0 9 5 0 137.70886 -0.00002 1.00 9 4 0 10 5 0 137.41664 -0.00003 1.00 10 4 0 11 5 0 137.12527 -0.00004 0.00 11 4 0 12 5 0 136.83479 0.00000 0.00 14 4 0 15 5 0 135.96859 -0.00003 1.00 15 4 0 16 5 0 135.68174 -0.00003 1.00 4 4 0 3 3 0 162.34082 -0.00001 0.10 5 4 0 4 3 0 162.64409 0.00011 0.10 6 4 0 5 3 0 162.94792 0.00003 0.10 7 4 0 6 3 0 163.25252 -0.00002 1.00 8 4 0 7 3 0 163.55790 0.00001 0.10 5 5 0 6 6 0 135.65676 -0.00005 1.00 8 5 0 9 6 0 134.77530 0.00006 1.00 9 5 0 10 6 0 134.48297 0.00001 1.00 10 5 0 11 6 0 134.19160 0.00012 1.00 11 5 0 12 6 0 133.90079 -0.00003 1.00 13 5 0 14 6 0 133.32202 0.00006 1.00 17 5 0 18 6 0 132.17462 0.00010 1.00 18 5 0 19 6 0 131.88984 -0.00005 1.00 19 5 0 20 6 0 131.60617 -0.00002 1.00 5 5 0 4 4 0 164.88719 -0.00001 0.00 6 5 0 5 4 0 165.19109 -0.00007 1.00 7 5 0 6 4 0 165.49587 -0.00002 1.00 8 5 0 7 4 0 165.80094 -0.00044 1.00 9 5 0 8 4 0 166.10757 -0.00004 1.00 10 5 0 9 4 0 166.41456 -0.00001 1.00 11 5 0 10 4 0 166.72220 -0.00004 1.00 12 5 0 11 4 0 167.02999 -0.00059 0.10 14 5 0 13 4 0 167.64906 -0.00016 1.00 15 5 0 14 4 0 167.95954 0.00009 1.00 16 5 0 15 4 0 168.27005 -0.00020 1.00 17 5 0 16 4 0 168.58164 0.00007 0.00 7 6 0 6 5 0 167.66273 0.00002 1.00 8 6 0 7 5 0 167.96826 0.00000 1.00 9 6 0 8 5 0 168.27460 0.00002 1.00 10 6 0 9 5 0 168.58164 -0.00001 1.00 11 6 0 10 5 0 168.88951 0.00004 1.00 12 6 0 11 5 0 169.19796 -0.00007 1.00 14 6 0 13 5 0 169.81736 0.00006 1.00 15 6 0 14 5 0 170.12816 0.00019 1.00 16 6 0 15 5 0 170.43926 -0.00006 1.00 17 6 0 16 5 0 170.75142 0.00009 1.00 18 6 0 17 5 0 171.06395 -0.00002 1.00 19 6 0 18 5 0 171.37747 0.00025 0.10 22 6 0 21 5 0 172.32006 -0.00034 0.10 23 6 0 22 5 0 172.63593 0.00008 1.00 24 6 0 23 5 0 172.95184 0.00006 1.00 25 6 0 24 5 0 173.26815 -0.00001 1.00 26 6 0 25 5 0 173.58510 0.00014 1.00 7 7 0 6 6 0 169.75493 0.00001 1.00 8 7 0 7 6 0 170.06059 0.00008 1.00 10 7 0 9 6 0 170.67401 0.00000 1.00 11 7 0 10 6 0 170.98186 -0.00005 1.00 12 7 0 11 6 0 171.29049 -0.00008 1.00 13 7 0 12 6 0 171.59991 -0.00008 1.00 14 7 0 13 6 0 171.91026 0.00012 0.10 16 7 0 15 6 0 172.53268 0.00004 1.00 17 7 0 16 6 0 172.84481 -0.00016 1.00 18 7 0 17 6 0 173.15802 0.00004 1.00 19 7 0 18 6 0 173.47171 0.00002 1.00 20 7 0 19 6 0 173.78608 0.00002 1.00 21 7 0 20 6 0 174.10131 0.00022 0.10 22 7 0 21 6 0 174.41678 0.00002 1.00 23 7 0 22 6 0 174.73301 -0.00004 0.10 24 7 0 23 6 0 175.04976 -0.00019 1.00 25 7 0 24 6 0 175.36748 0.00005 1.00 26 7 0 25 6 0 175.68553 0.00005 1.00 28 7 0 27 6 0 176.32304 -0.00015 0.00 29 7 0 28 6 0 176.64269 -0.00012 0.00 30 7 0 29 6 0 176.96294 0.00004 0.00 8 8 0 9 9 0 125.54384 0.00015 1.00 9 8 0 10 9 0 125.25183 0.00007 1.00 10 8 0 11 9 0 124.96084 0.00016 1.00 11 8 0 12 9 0 124.67061 0.00017 1.00 12 8 0 13 9 0 124.38098 -0.00007 1.00 8 8 0 7 7 0 172.08010 0.00015 1.00 9 8 0 8 7 0 172.38657 0.00018 1.00 11 8 0 10 7 0 173.00150 -0.00013 1.00 12 8 0 11 7 0 173.31038 -0.00004 1.00 13 8 0 12 7 0 173.61989 -0.00009 1.00 14 8 0 13 7 0 173.93011 -0.00020 1.00 15 8 0 14 7 0 174.24081 -0.00059 0.00 16 8 0 15 7 0 174.55336 0.00012 1.00 17 8 0 16 7 0 174.86586 0.00002 1.00 18 8 0 17 7 0 175.17914 -0.00003 1.00 19 8 0 18 7 0 175.49322 -0.00002 1.00 20 8 0 19 7 0 175.80815 0.00012 1.00 21 8 0 20 7 0 176.12362 0.00008 1.00 22 8 0 21 7 0 176.43936 -0.00039 0.10 23 8 0 22 7 0 176.75670 0.00004 1.00 24 8 0 23 7 0 177.07423 -0.00003 1.00 25 8 0 24 7 0 177.39245 -0.00008 1.00 26 8 0 25 7 0 177.71157 0.00010 1.00 27 8 0 26 7 0 178.03109 0.00004 1.00 29 8 0 28 7 0 178.67219 0.00005 0.10 30 8 0 29 7 0 178.99364 0.00002 0.10 28 9 0 28 8 0 171.93392 -0.00022 0.00 9 9 0 8 8 0 174.33465 0.00003 1.00 10 9 0 9 8 0 174.64199 0.00000 1.00 11 9 0 10 8 0 174.95016 0.00000 1.00 12 9 0 11 8 0 175.25913 0.00000 1.00 13 9 0 12 8 0 175.56885 -0.00005 1.00 14 9 0 13 8 0 175.87950 0.00004 1.00 15 9 0 14 8 0 176.19081 -0.00001 1.00 16 9 0 15 8 0 176.50299 0.00002 1.00 17 9 0 16 8 0 176.81591 0.00001 1.00 18 9 0 17 8 0 177.12968 0.00006 1.00 20 9 0 19 8 0 177.75922 -0.00018 0.10 21 9 0 20 8 0 178.07539 -0.00005 0.10 22 9 0 21 8 0 178.39224 -0.00002 1.00 23 9 0 22 8 0 178.70981 -0.00002 1.00 24 9 0 23 8 0 179.02810 -0.00005 1.00 25 9 0 24 8 0 179.34711 -0.00009 1.00 26 9 0 25 8 0 179.66687 -0.00004 1.00 27 9 0 26 8 0 179.98682 -0.00006 1.00 28 9 0 27 8 0 180.31430 -0.00006 1.00 29 9 0 28 8 0 180.63277 0.00000 1.00 32 9 0 31 8 0 181.60336 -0.00002 0.10 34 9 0 33 8 0 182.25468 -0.00004 0.10 36 9 0 35 8 0 182.90921 -0.00010 0.10 37 9 0 36 8 0 183.23782 -0.00004 0.10 38 9 0 37 8 0 183.56724 -0.00001 0.10 10 10 0 9 9 0 176.52029 0.00000 1.00 11 10 0 10 9 0 176.82873 -0.00001 1.00 12 10 0 11 9 0 177.13799 -0.00004 1.00 13 10 0 12 9 0 177.44822 0.00005 1.00 14 10 0 13 9 0 177.75922 0.00007 0.10 15 10 0 14 9 0 178.07096 -0.00002 1.00 16 10 0 15 9 0 178.38368 0.00003 1.00 17 10 0 16 9 0 178.69721 0.00002 1.00 18 10 0 17 9 0 179.01153 -0.00006 1.00 19 10 0 18 9 0 179.32671 -0.00014 0.10 20 10 0 19 9 0 179.64303 0.00004 1.00 21 10 0 20 9 0 179.96014 0.00012 0.10 22 10 0 21 9 0 180.27792 -0.00003 1.00 23 10 0 22 9 0 180.59675 -0.00003 1.00 24 10 0 23 9 0 180.91655 0.00000 1.00 25 10 0 24 9 0 181.23728 0.00001 0.10 11 11 0 12 12 0 114.78418 -0.00010 1.00 12 11 0 13 12 0 114.49690 -0.00014 0.10 13 11 0 14 12 0 114.21111 0.00003 1.00 14 11 0 15 12 0 113.92670 0.00021 0.10 15 11 0 16 12 0 113.64334 -0.00004 1.00 11 11 0 10 10 0 178.63822 0.00000 1.00 12 11 0 11 10 0 178.94800 -0.00006 1.00 13 11 0 12 10 0 179.25881 -0.00002 1.00 14 11 0 13 10 0 179.57090 0.00036 0.10 15 11 0 14 10 0 179.88320 -0.00001 1.00 16 11 0 15 10 0 180.19686 0.00001 1.00 18 11 0 17 10 0 180.82718 0.00000 0.10 19 11 0 18 10 0 181.14400 0.00007 0.10 20 11 0 19 10 0 181.46169 -0.00009 1.00 21 11 0 20 10 0 181.78085 0.00005 0.10 22 11 0 21 10 0 182.10111 0.00008 1.00 23 11 0 22 10 0 182.42270 0.00015 1.00 24 11 0 23 10 0 182.74565 0.00020 1.00 25 11 0 24 10 0 183.06993 0.00010 1.00 13 12 0 14 13 0 110.76527 0.00006 0.00 14 12 0 15 13 0 110.47942 0.00006 0.00 12 12 0 11 11 0 180.69021 -0.00001 1.00 13 12 0 12 11 0 181.00184 -0.00002 1.00 15 12 0 14 11 0 181.62766 -0.00086 0.10 16 12 0 15 11 0 181.94400 0.00037 0.10 18 12 0 17 11 0 182.57785 0.00003 1.00 19 12 0 18 11 0 182.89672 -0.00036 1.00 22 12 0 21 11 0 183.86494 -0.00019 1.00 23 12 0 22 11 0 184.19235 0.00051 0.10 24 12 0 23 11 0 184.52046 -0.00049 0.10 13 13 0 14 14 0 107.23838 0.00017 0.00 13 13 0 12 12 0 182.66665 0.00010 1.00 14 13 0 13 12 0 182.97987 0.00013 1.00 15 13 0 14 12 0 183.29399 -0.00020 1.00 16 13 0 15 12 0 183.61005 0.00008 1.00 17 13 0 16 12 0 183.92725 0.00004 1.00 18 13 0 17 12 0 184.24603 0.00002 1.00 19 13 0 18 12 0 184.56661 0.00009 1.00 20 13 0 19 12 0 184.88893 -0.00001 1.00 21 13 0 20 12 0 185.21341 -0.00004 1.00 22 13 0 21 12 0 185.54023 -0.00005 1.00 23 13 0 22 12 0 185.86970 0.00002 1.00 24 13 0 23 12 0 186.20173 -0.00012 1.00 14 14 0 13 13 0 184.58797 0.00006 1.00 15 14 0 14 13 0 184.90171 0.00002 1.00 17 14 0 16 13 0 185.53273 -0.00001 1.00 18 14 0 17 13 0 185.85015 -0.00009 1.00 19 14 0 18 13 0 186.16929 0.00011 1.00 20 14 0 19 13 0 186.48979 0.00010 1.00 21 14 0 20 13 0 186.81179 -0.00012 1.00 22 14 0 21 13 0 187.13608 0.00003 1.00 24 14 0 23 13 0 187.79106 0.00009 1.00 25 14 0 24 13 0 188.12239 0.00008 1.00 26 14 0 25 13 0 188.45656 -0.00009 0.10 27 14 0 26 13 0 188.79452 0.00018 0.10 15 15 0 14 14 0 186.44092 0.00005 1.00 16 15 0 15 14 0 186.75434 -0.00007 1.00 17 15 0 16 14 0 187.06880 -0.00014 1.00 18 15 0 17 14 0 187.38448 0.00000 1.00 19 15 0 18 14 0 187.70113 0.00007 1.00 20 15 0 19 14 0 188.01874 0.00000 1.00 --------------------------------------------------------------