Vibration-Torsion-Rotation Study of the nu5 State of CH3CF3 by S.-X. Wang, J. Schroderus, I. Ozier, N. Moazzen-Ahmadi, V.-M. Horneman, V. V. Ilyushyn, E. A. Alekseev, A. A. Katrich and S. F. Dyubko Table S1: Infrared Transitions Calculated and Observed Frequencies, Experimental Uncertainties, and Identifications Submitted to the Journal of Molecular Spectroscopy as Supplementary Material. ********************************************************************************************** ********************************************************************************************** IN THIS SECTION, THE CHARACTERISTICS OF THE FIT ARE GIVEN. SEE TABLE 1 OF THE MANUSCRIPT FOR FURTHER DETAILS. NUMBER OF DATA POINTS 5084 NUMBER OF CONSTANTS 36 DEGREES OF FREEDOM 5048 Chi- N Standard Average J K Sigma square Deviation Error Range Range cm-1 cm-1 MB1 0.3 1 0.01151 0.02000 0- 0 0- 0 * * * * MWFT1 1.8 6 0.00408 0.01167 0- 1 0- 0 * * * * MWST 2.3 4 0.03039 0.04250 2- 3 1- 1 * * * * MMW1 3.2 26 0.02083 0.06923 8-10 4-10 * * * * MMW2 7.6 44 0.02072 0.05000 18-44 4-44 * * * * MMW3 27.5 116 0.24335 0.50000 59-86 2-69 * * * * MB2 0.7 6 0.00633 0.01800 2- 6 2- 2 0, -1 MB3 4.0 6 0.00060 0.00078 2- 6 2- 2 1,-1 MWFT2 86.1 194 0.01790 0.03673 27-75 3- 8 0,1, MWFT3 15.3 40 0.02206 0.06375 50-67 5- 7 0,1,-1 MMW4 0NU6 28.4 165 0.00195 0.01238 4-34 3-32 * * * * MMW4 1NU6 17.7 117 0.00171 0.02309 4-34 3-34 * * * * MMW4 2NU6 58.8 163 0.02210 0.07988 7-34 3-26 0,1,-1* MMW4 3NU6 53.5 224 0.00820 0.06616 7-34 0-31 0,1,-1 (0,0),(1,0),(2,0) 21.4 65 0.00115 0.00200 3-35 3- 3 * * * * (8,-1),(10,1) 6.4 49 0.00054 0.00150 9-34 8- 8 * * * * (10,0),(9,1),(7,-1) 5.0 51 0.00047 0.00150 10-36 7- 7 * * * * (12,0),(12,1),(10,-1) 6.7 44 0.00058 0.00150 13-35 12-12 0 sigma=0,K=13 13.4 45 0.00082 0.00150 13-36 13-13 * * * * sigma=0,K=15 3.3 38 0.00044 0.00150 15-35 15-15 * * * * (14,0),(14,1),(12,-1) 5.1 32 0.00060 0.00150 17-34 14-14 * * * * sigma=0,K=18 1.2 34 0.00029 0.00150 18-36 18-18 * * * * (21,0) 3.7 24 0.00059 0.00150 22-38 21-21 0, Nu5 fundamenta P-Branch 89.3 1289 0.00008 0.00030 10-70 9-46 * * * * Nu5 fundamenta R-Branch 183.4 1527 0.00010 0.00030 10-70 9-45 * * * * mmw for nu5=1, nu6=0 32.1 73 0.00385 0.01630 4-34 3-30 * * * * Nu5 hot band, R-Branch, sigma= 0 55.5 284 0.00013 0.00030 7-64 6-13 0, Nu5 hot band, P-Branch, sigma= 0 20.0 184 0.00010 0.00030 12-51 6-13 0, Nu5 hot band, R-Branch, sigma=+1 2.9 67 0.00010 0.00050 8-46 1- 4 1, * Nu5 hot band, P_Branch, sigma=+1 5.9 55 0.00016 0.00050 13-49 1- 4 1, * Nu5 hot band, R-Branch, sigma=-1 3.8 46 0.00014 0.00050 9-27 2- 5 -1 Nu5 hot band, P-Branch, sigma=-1 6.9 65 0.00016 0.00050 12-35 2- 5 -1 TOTAL 773.2 5084 0.00014 VARIANCE 0.39 *********************************************************************************************** IN THIS SECTION, THE BEST FIT VALUES OF THE MOLECULAR PARAMETERS ARE GIVEN. SEE TABLE 3 OF THE MANUSCRIPT FOR FURTHER DETAILS. FINAL VALUE ERROR 1 1 A 5498.1478653 0.0044659 0 2 2 B 5189.3415789 0.0000825 0 3 3 D-J 1.2689025 0.0000523 0 4 4 D-JK 2.0205774 0.0001769 0 5 5 D-K -2.0051523 0.0035417 0 6 6 RHO 0.0350004 0.0000054 0 7 7 V3 1112.2419811 0.1568650 0 0 11 FM 0.0000000 0 0 12 DM 0.0000000 0 8 13 DJM 0.0717610 0.0003214 0 9 14 DKM -0.2100136 0.0060441 0 0 15 DSM 0.0000000 0 10 16 DSJ -0.0215562 0.0001426 0 0 17 DSK 0.0000000 0 11 18 F3J -53.7313596 0.0194151 0 12 19 F3K 53.2092664 1.0853562 0 13 20 F6J -3.7258007 0.0160781 0 0 21 F6K 0.0000000 0 14 22 F3JJ(Hz) -15.8360923 2.9700934 0 15 23 F3KK(Hz) -365.6286176 61.7294856 0 16 24 F3JK(Hz) 630.2163993 12.5896042 0 17 25 HJJJ(Hz) 0.0005559 0.0000044 0 18 26 HJJK(Hz) 0.0006427 0.0000187 0 19 27 HJKK(Hz) 0.0044589 0.0000596 0 0 28 HKKK(Hz) 0.0000000 0 20 29 HJJM(Hz) 0.6022939 0.0185045 0 0 30 HKKM(Hz) 0.0000000 0 21 31 HJKM(Hz) -1.5256375 0.0759271 0 22 32 HJMM(Hz) 50.7288159 1.2616673 0 0 35 F6JK(Hz) 0.0000000 0 23 36 EP (Hz) 249.4822163 0.2362466 0 24 37 EPJ(Hz) -0.0004358 0.0000464 0 0 38 EPK(Hz) 0.0000000 0 25 106 DEL A5 -1.9563002 0.0036836 1 26 107 DEL B5 0.2822243 0.0007482 1 27 108 DEL D-J 0.0190375 0.0002272 1 28 109 DEL D-JK -0.0326200 0.0009440 1 29 110 DEL D-K 0.0394221 0.0006726 1 0 111 RHO5 0.0000000 0 30 112 DEL V35 -3.2267423 0.0399807 1 0 113 V65 0.0000000 0 0 118 DEL DJM5 0.0000000 1 0 119 DEL DKM5 0.0000000 1 31 123 DEL F3J5 -11.8437441 0.0630231 1 0 124 DEL F3K5 0.0000000 1 0 125 F6J5 0.0000000 0 0 126 F6K5 0.0000000 0 32 127 DEL F3JJ5(Hz) 150.6490546 5.6834298 1 0 128 DEL F3KK5(Hz) 0.0000000 1 0 129 DEL F3JK5(Hz) 0.0000000 1 0 130 DEL HJJJ5(Hz) 0.0000000 1 33 131 DEL HJJK5(Hz) 0.0003892 0.0001026 1 0 132 DEL HJKK5(Hz) 0.0000000 1 34 135 ANU0 5 1156.8609707 0.0618811 0 35 137 FER3 193.6252327 0.2077996 0 36 138 CDS 0.0067645 0.0004570 0 ********** THE CORRELATION COEFFICIENTS MULTIPLIED BY 1000 (0 MEANS A CORRELATION SMALLER THAN 0.05 %) A 1000 B 1 1000 D-J -46 236 1000 D-JK 105 18 -572 1000 D-K -38 -28 0 5 1000 RHO 68 -202 -82 143 144 1000 V3 65 -219 -79 137 143 995 1000 DJM -63 478 50 -63 -113 -821 -817 1000 DKM 984 -13 -17 54 -146 61 54 -63 1000 DSJ -58 34 19 -85 -40 -354 -344 291 -77 1000 F3J -59 -503 84 -72 -87 -613 -593 355 -44 253 1000 F3K 979 -12 -16 55 -153 65 57 -66 1000 -84 -46 1000 F6J -54 608 32 -59 -104 -761 -761 980 -57 260 168 -60 1000 F3JJ(Hz) 24 -77 -654 426 4 15 11 61 8 47 -40 9 73 1000 F3KK(Hz) -39 -32 -13 6 959 161 160 -126 -145 -46 -98 -152 -117 6 1000 F3JK(Hz) -90 1 314 -617 1 -76 -71 -59 -75 72 -47 -77 -37 -591 5 1000 HJJJ(Hz) -23 138 584 -409 0 -22 -22 13 4 1 15 4 9 -151 1 55 1000 HJJK(Hz) 45 -17 -351 609 12 232 226 -178 28 -521 -153 31 -161 55 29 -127 -478 1000 HJKK(Hz) 37 32 126 0 4 -38 -38 34 40 24 27 40 31 -27 -57 46 -165 -44 1000 HJJM(Hz) -28 88 710 -452 4 -18 -14 -58 10 -40 46 10 -71 -995 7 576 175 -73 36 1000 HJKM(Hz) -26 2 -348 666 21 89 85 45 -51 -66 31 -50 26 598 26 -987 -67 145 -64 -589 1000 HJMM(Hz) -30 805 11 -31 -70 -519 -525 835 -40 162 -216 -41 925 72 -79 -20 8 -102 20 -73 15 1000 EP (Hz) 4 1 -55 104 9 6 6 3 1 1 2 0 3 2 3 0 -167 148 88 3 1 3 1000 EPJ(Hz) 4 1 55 -105 9 5 5 3 0 1 2 0 3 2 3 0 171 -155 -86 3 1 3 -993 1000 DEL A5 190 -19 63 -162 -31 -193 -162 147 89 224 155 63 125 -96 -34 141 14 -150 20 94 -148 73 2 2 1000 DEL B5 -51 -24 41 -75 -18 -127 -112 123 -26 28 195 -22 82 -149 -21 88 3 -33 12 134 -92 30 1 1 91 1000 DEL D-J -40 -17 -28 18 3 27 28 -35 -15 -39 40 9 -51 -75 3 2 -13 25 3 58 1 -47 2 2 -15 888 1000 DEL D-JK 23 -15 274 -577 -16 -73 -71 -35 42 55 -26 41 -20 -477 -21 804 59 -158 56 469 -816 -11 -10 10 243 86 -24 1000 DEL D-K 21 6 2 8 3 9 9 7 6 21 5 3 7 3 3 5 4 2 3 2 6 5 8 8 365 5 69 -86 1000 V35 -86 264 57 -93 -118 -837 -887 687 -59 254 422 -56 661 8 -132 40 16 -170 30 5 -52 479 5 4 -17 33 -24 43 2 1000 F3J5 -39 635 18 -39 -95 -697 -700 934 -49 241 75 -52 971 108 -106 -57 7 -146 26 -103 47 928 3 3 103 -151 -252 -35 5 620 1000 F3JJ5(Hz) -48 43 430 -272 1 17 20 -71 -18 -57 58 -14 -91 -684 0 364 104 -26 22 675 -371 -88 2 2 56 762 761 283 20 -28 -266 1000 HJJK5(Hz) -11 -20 -11 -67 1 -41 -38 32 -17 95 26 -20 30 5 2 25 2 -106 3 6 -24 19 8 9 195 27 81 497 30 21 31 0 1000 ANU0 5 55 -194 -83 145 145 999 989 -820 50 -357 -620 54 -758 16 161 -77 -22 233 -38 -20 91 -515 6 5 -212 -132 28 -76 -11 -810 -693 16 -42 1000 FER3 83 -262 -61 100 122 865 910 -710 58 -269 -446 56 -681 6 137 -46 -17 179 -31 2 58 -490 5 5 -11 -38 28 -50 6 -998 -638 30 -26 841 1000 CDS 164 18 -66 164 -31 169 134 -127 282 -248 -125 309 -111 78 -28 -162 -14 143 0 -80 119 -67 1 1 -835 118 191 -117 -104 45 -136 93 -86 185 -17 1000 P-BRANCH OF THE NU5 COLD BAND Each transition frequency is an weighted average over the three sigma components. N6' = 0 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR cm-1 cm-1 cm-1 cm-1 1 599.475734 599.475821 0.000087 0.00030 10 9**** 0 9 9**** 2 599.130083 599.130207 0.000124 0.00030 11 9**** 0 10 9**** 3 598.784461 598.784624 0.000163 0.00030 12 9**** 0 11 9**** 4 598.438871 598.438995 0.000124 0.00030 13 9**** 0 12 9**** 5 598.093312 598.093462 0.000150 0.00030 14 9**** 0 13 9**** 6 597.402295 597.402405 0.000110 0.00030 16 9**** 0 15 9**** 7 597.056837 597.056940 0.000103 0.00030 17 9**** 0 16 9**** 8 596.711415 596.711556 0.000141 0.00030 18 9**** 0 17 9**** 9 596.366028 596.366160 0.000132 0.00030 19 9**** 0 18 9**** 10 596.020679 596.020796 0.000117 0.00030 20 9**** 0 19 9**** 11 595.675367 595.675459 0.000092 0.00030 21 9**** 0 20 9**** 12 595.330093 595.330244 0.000151 0.00030 22 9**** 0 21 9**** 13 594.984859 594.984995 0.000136 0.00030 23 9**** 0 22 9**** 14 594.639664 594.639753 0.000089 0.00030 24 9**** 0 23 9**** 15 593.949396 593.949491 0.000095 0.00030 26 9**** 0 25 9**** 16 593.604325 593.604460 0.000135 0.00030 27 9**** 0 26 9**** 17 593.259296 593.259371 0.000075 0.00030 28 9**** 0 27 9**** 18 592.914310 592.914313 0.000003 0.00030 29 9**** 0 28 9**** 19 592.569369 592.569476 0.000107 0.00030 30 9**** 0 29 9**** 20 591.534813 591.534904 0.000091 0.00030 33 9**** 0 32 9**** 21 591.190053 591.190111 0.000058 0.00030 34 9**** 0 33 9**** 22 590.845340 590.845399 0.000059 0.00030 35 9**** 0 34 9**** 23 598.434463 598.434336 -0.000127 0.00030 13 12**** 0 12 12**** 24 598.088915 598.088888 -0.000027 0.00030 14 12**** 0 13 12**** 25 597.743401 597.743404 0.000003 0.00030 15 12**** 0 14 12**** 26 597.397920 597.397915 -0.000005 0.00030 16 12**** 0 15 12**** 27 597.052474 597.052455 -0.000019 0.00030 17 12**** 0 16 12**** 28 596.707064 596.707054 -0.000010 0.00030 18 12**** 0 17 12**** 29 596.361690 596.361705 0.000015 0.00030 19 12**** 0 18 12**** 30 596.016352 596.016345 -0.000007 0.00030 20 12**** 0 19 12**** 31 595.671053 595.671040 -0.000013 0.00030 21 12**** 0 20 12**** 32 595.325791 595.325801 0.000010 0.00030 22 12**** 0 21 12**** 33 594.980570 594.980554 -0.000016 0.00030 23 12**** 0 22 12**** 34 594.635387 594.635374 -0.000013 0.00030 24 12**** 0 23 12**** 35 594.290246 594.290211 -0.000035 0.00030 25 12**** 0 24 12**** 36 593.945146 593.945121 -0.000025 0.00030 26 12**** 0 25 12**** 37 593.600088 593.600076 -0.000012 0.00030 27 12**** 0 26 12**** 38 593.255073 593.255035 -0.000038 0.00030 28 12**** 0 27 12**** 39 592.910101 592.910093 -0.000008 0.00030 29 12**** 0 28 12**** 40 592.565173 592.565175 0.000002 0.00030 30 12**** 0 29 12**** 41 592.220289 592.220230 -0.000059 0.00030 31 12**** 0 30 12**** 42 591.875451 591.875381 -0.000070 0.00030 32 12**** 0 31 12**** 43 591.530659 591.530627 -0.000032 0.00030 33 12**** 0 32 12**** 44 591.185913 591.185940 0.000027 0.00030 34 12**** 0 33 12**** 45 590.841215 590.841225 0.000010 0.00030 35 12**** 0 34 12**** 46 590.496564 590.496543 -0.000021 0.00030 36 12**** 0 35 12**** 47 590.151961 590.151936 -0.000025 0.00030 37 12**** 0 36 12**** 48 589.807408 589.807400 -0.000008 0.00030 38 12**** 0 37 12**** 49 589.462904 589.462926 0.000022 0.00030 39 12**** 0 38 12**** 50 589.118450 589.118439 -0.000011 0.00030 40 12**** 0 39 12**** 51 588.774046 588.774010 -0.000036 0.00030 41 12**** 0 40 12**** 52 588.429694 588.429677 -0.000017 0.00030 42 12**** 0 41 12**** 53 588.085393 588.085412 0.000019 0.00030 43 12**** 0 42 12**** 54 587.741145 587.741152 0.000007 0.00030 44 12**** 0 43 12**** 55 587.396949 587.396985 0.000036 0.00030 45 12**** 0 44 12**** 56 587.052806 587.052880 0.000074 0.00030 46 12**** 0 45 12**** 57 586.708718 586.708753 0.000035 0.00030 47 12**** 0 46 12**** 58 586.364684 586.364686 0.000002 0.00030 48 12**** 0 47 12**** 59 586.020704 586.020756 0.000052 0.00030 49 12**** 0 48 12**** 60 585.676780 585.676748 -0.000032 0.00030 50 12**** 0 49 12**** 61 585.332912 585.332930 0.000018 0.00030 51 12**** 0 50 12**** 62 584.989100 584.989146 0.000046 0.00030 52 12**** 0 51 12**** 63 584.645345 584.645432 0.000087 0.00030 53 12**** 0 52 12**** 64 584.301648 584.301703 0.000055 0.00030 54 12**** 0 53 12**** 65 583.614428 583.614479 0.000051 0.00030 56 12**** 0 55 12**** 66 583.270905 583.271008 0.000103 0.00030 57 12**** 0 56 12**** 67 582.927443 582.927518 0.000075 0.00030 58 12**** 0 57 12**** 68 582.584040 582.584069 0.000029 0.00030 59 12**** 0 58 12**** 69 582.240698 582.240733 0.000035 0.00030 60 12**** 0 59 12**** 70 581.897417 581.897478 0.000061 0.00030 61 12**** 0 60 12**** 71 581.554197 581.554278 0.000081 0.00030 62 12**** 0 61 12**** 72 581.211039 581.211092 0.000053 0.00030 63 12**** 0 62 12**** 73 580.867944 580.867923 -0.000021 0.00030 64 12**** 0 63 12**** 74 580.524912 580.524919 0.000007 0.00030 65 12**** 0 64 12**** 75 580.181943 580.181945 0.000002 0.00030 66 12**** 0 65 12**** 76 579.839039 579.838953 -0.000086 0.00030 67 12**** 0 66 12**** 77 579.496200 579.496118 -0.000082 0.00030 68 12**** 0 67 12**** 78 579.153425 579.153327 -0.000098 0.00030 69 12**** 0 68 12**** 79 578.810717 578.810604 -0.000113 0.00030 70 12**** 0 69 12**** 80 598.087180 598.087314 0.000134 0.00030 14 13**** 0 13 13**** 81 597.741670 597.741712 0.000042 0.00030 15 13**** 0 14 13**** 82 597.396194 597.396201 0.000007 0.00030 16 13**** 0 15 13**** 83 597.050752 597.050795 0.000043 0.00030 17 13**** 0 16 13**** 84 596.705347 596.705367 0.000020 0.00030 18 13**** 0 17 13**** 85 596.359977 596.359990 0.000013 0.00030 19 13**** 0 18 13**** 86 596.014645 596.014651 0.000006 0.00030 20 13**** 0 19 13**** 87 595.669350 595.669343 -0.000007 0.00030 21 13**** 0 20 13**** 88 595.324094 595.324123 0.000029 0.00030 22 13**** 0 21 13**** 89 594.978877 594.978872 -0.000005 0.00030 23 13**** 0 22 13**** 90 594.633700 594.633699 -0.000001 0.00030 24 13**** 0 23 13**** 91 594.288564 594.288580 0.000016 0.00030 25 13**** 0 24 13**** 92 593.943469 593.943429 -0.000040 0.00030 26 13**** 0 25 13**** 93 593.598417 593.598413 -0.000004 0.00030 27 13**** 0 26 13**** 94 593.253407 593.253392 -0.000015 0.00030 28 13**** 0 27 13**** 95 592.908440 592.908416 -0.000024 0.00030 29 13**** 0 28 13**** 96 592.563518 592.563515 -0.000003 0.00030 30 13**** 0 29 13**** 97 592.218640 592.218678 0.000038 0.00030 31 13**** 0 30 13**** 98 591.873808 591.873804 -0.000004 0.00030 32 13**** 0 31 13**** 99 591.529021 591.528999 -0.000022 0.00030 33 13**** 0 32 13**** 100 591.184282 591.184255 -0.000027 0.00030 34 13**** 0 33 13**** 101 590.839589 590.839546 -0.000043 0.00030 35 13**** 0 34 13**** 102 590.494944 590.494942 -0.000002 0.00030 36 13**** 0 35 13**** 103 590.150348 590.150329 -0.000019 0.00030 37 13**** 0 36 13**** 104 589.805800 589.805754 -0.000046 0.00030 38 13**** 0 37 13**** 105 589.461302 589.461252 -0.000050 0.00030 39 13**** 0 38 13**** 106 589.116854 589.116836 -0.000018 0.00030 40 13**** 0 39 13**** 107 588.772457 588.772471 0.000014 0.00030 41 13**** 0 40 13**** 108 588.428111 588.428057 -0.000054 0.00030 42 13**** 0 41 13**** 109 588.083816 588.083782 -0.000034 0.00030 43 13**** 0 42 13**** 110 587.739574 587.739566 -0.000008 0.00030 44 13**** 0 43 13**** 111 587.395385 587.395370 -0.000015 0.00030 45 13**** 0 44 13**** 112 587.051249 587.051196 -0.000053 0.00030 46 13**** 0 45 13**** 113 586.707166 586.707080 -0.000086 0.00030 47 13**** 0 46 13**** 114 586.363139 586.363117 -0.000022 0.00030 48 13**** 0 47 13**** 115 586.019166 586.019201 0.000035 0.00030 49 13**** 0 48 13**** 116 585.675248 585.675186 -0.000062 0.00030 50 13**** 0 49 13**** 117 585.331387 585.331325 -0.000062 0.00030 51 13**** 0 50 13**** 118 584.987581 584.987569 -0.000012 0.00030 52 13**** 0 51 13**** 119 584.643833 584.643896 0.000063 0.00030 53 13**** 0 52 13**** 120 584.300142 584.300128 -0.000014 0.00030 54 13**** 0 53 13**** 121 583.956509 583.956517 0.000008 0.00030 55 13**** 0 54 13**** 122 583.269419 583.269375 -0.000044 0.00030 57 13**** 0 56 13**** 123 582.925963 582.925980 0.000017 0.00030 58 13**** 0 57 13**** 124 582.582567 582.582529 -0.000038 0.00030 59 13**** 0 58 13**** 125 582.239232 582.239182 -0.000050 0.00030 60 13**** 0 59 13**** 126 581.895957 581.895943 -0.000014 0.00030 61 13**** 0 60 13**** 127 581.552744 581.552745 0.000001 0.00030 62 13**** 0 61 13**** 128 581.209593 581.209497 -0.000096 0.00030 63 13**** 0 62 13**** 129 580.866504 580.866402 -0.000102 0.00030 64 13**** 0 63 13**** 130 580.523479 580.523344 -0.000135 0.00030 65 13**** 0 64 13**** 131 580.180517 580.180457 -0.000060 0.00030 66 13**** 0 65 13**** 132 579.837619 579.837523 -0.000096 0.00030 67 13**** 0 66 13**** 133 579.494786 579.494703 -0.000083 0.00030 68 13**** 0 67 13**** 134 578.809317 578.809102 -0.000215 0.00030 70 13**** 0 69 13**** 135 597.739859 597.740069 0.000210 0.00030 15 14**** 0 14 14**** 136 597.394388 597.394364 -0.000024 0.00030 16 14**** 0 15 14**** 137 597.048951 597.048921 -0.000030 0.00030 17 14**** 0 16 14**** 138 596.703551 596.703611 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583.872623 583.872646 0.000023 0.00030 55 39**** 0 54 39**** 1172 583.529433 583.529482 0.000049 0.00030 56 39**** 0 55 39**** 1173 583.186304 583.186355 0.000051 0.00030 57 39**** 0 56 39**** 1174 582.843234 582.843323 0.000089 0.00030 58 39**** 0 57 39**** 1175 582.500225 582.500243 0.000018 0.00030 59 39**** 0 58 39**** 1176 582.157276 582.157175 -0.000101 0.00030 60 39**** 0 59 39**** 1177 581.814388 581.814372 -0.000016 0.00030 61 39**** 0 60 39**** 1178 581.471561 581.471606 0.000045 0.00030 62 39**** 0 61 39**** 1179 581.128796 581.128721 -0.000075 0.00030 63 39**** 0 62 39**** 1180 580.786092 580.785966 -0.000126 0.00030 64 39**** 0 63 39**** 1181 580.443451 580.443249 -0.000202 0.00030 65 39**** 0 64 39**** 1182 580.100872 580.100824 -0.000048 0.00030 66 39**** 0 65 39**** 1183 579.758356 579.758363 0.000007 0.00030 67 39**** 0 66 39**** 1184 579.415903 579.416175 0.000272 0.00030 68 39**** 0 67 39**** 1185 587.646136 587.646378 0.000242 0.00030 44 40**** 0 43 40**** 1186 587.302338 587.302459 0.000121 0.00030 45 40**** 0 44 40**** 1187 586.958595 586.958903 0.000308 0.00030 46 40**** 0 45 40**** 1188 586.614909 586.614964 0.000055 0.00030 47 40**** 0 46 40**** 1189 586.271279 586.271385 0.000106 0.00030 48 40**** 0 47 40**** 1190 585.927706 585.927745 0.000039 0.00030 49 40**** 0 48 40**** 1191 585.584191 585.584127 -0.000064 0.00030 50 40**** 0 49 40**** 1192 585.240733 585.240564 -0.000169 0.00030 51 40**** 0 50 40**** 1193 584.897333 584.897392 0.000059 0.00030 52 40**** 0 51 40**** 1194 584.553992 584.554081 0.000089 0.00030 53 40**** 0 52 40**** 1195 584.210709 584.210964 0.000255 0.00030 54 40**** 0 53 40**** 1196 583.867485 583.867481 -0.000004 0.00030 55 40**** 0 54 40**** 1197 583.524321 583.524086 -0.000235 0.00030 56 40**** 0 55 40**** 1198 583.181216 583.181165 -0.000051 0.00030 57 40**** 0 56 40**** 1199 582.838171 582.838247 0.000076 0.00030 58 40**** 0 57 40**** 1200 582.495187 582.495136 -0.000051 0.00030 59 40**** 0 58 40**** 1201 582.152263 582.152148 -0.000115 0.00030 60 40**** 0 59 40**** 1202 581.809400 581.809078 -0.000322 0.00030 61 40**** 0 60 40**** 1203 581.466598 581.466427 -0.000171 0.00030 62 40**** 0 61 40**** 1204 581.123858 581.124169 0.000311 0.00030 63 40**** 0 62 40**** 1205 580.781179 580.781091 -0.000088 0.00030 64 40**** 0 63 40**** 1206 580.096009 580.095871 -0.000138 0.00030 66 40**** 0 65 40**** 1207 585.922384 585.922490 0.000106 0.00030 49 41**** 0 48 41**** 1208 585.578894 585.579020 0.000126 0.00030 50 41**** 0 49 41**** 1209 585.235462 585.235485 0.000023 0.00030 51 41**** 0 50 41**** 1210 584.892088 584.892004 -0.000084 0.00030 52 41**** 0 51 41**** 1211 584.548773 584.548687 -0.000086 0.00030 53 41**** 0 52 41**** 1212 584.205516 584.205398 -0.000118 0.00030 54 41**** 0 53 41**** 1213 583.862319 583.862303 -0.000016 0.00030 55 41**** 0 54 41**** 1214 583.519181 583.519000 -0.000181 0.00030 56 41**** 0 55 41**** 1215 583.176103 583.176198 0.000095 0.00030 57 41**** 0 56 41**** 1216 582.833085 582.832931 -0.000154 0.00030 58 41**** 0 57 41**** 1217 582.490128 582.490268 0.000140 0.00030 59 41**** 0 58 41**** 1218 582.147231 582.147352 0.000121 0.00030 60 41**** 0 59 41**** 1219 581.804395 581.804310 -0.000085 0.00030 61 41**** 0 60 41**** 1220 581.461620 581.461531 -0.000089 0.00030 62 41**** 0 61 41**** 1221 581.118907 581.118905 -0.000002 0.00030 63 41**** 0 62 41**** 1222 580.776256 580.776160 -0.000096 0.00030 64 41**** 0 63 41**** 1223 586.604122 586.604335 0.000213 0.00030 47 42**** 0 46 42**** 1224 586.260543 586.260608 0.000065 0.00030 48 42**** 0 47 42**** 1225 585.917022 585.917000 -0.000022 0.00030 49 42**** 0 48 42**** 1226 585.573558 585.573511 -0.000047 0.00030 50 42**** 0 49 42**** 1227 585.230152 585.230229 0.000077 0.00030 51 42**** 0 50 42**** 1228 584.886804 584.886891 0.000087 0.00030 52 42**** 0 51 42**** 1229 584.543515 584.543694 0.000179 0.00030 53 42**** 0 52 42**** 1230 584.200285 584.200384 0.000099 0.00030 54 42**** 0 53 42**** 1231 583.857115 583.857090 -0.000025 0.00030 55 42**** 0 54 42**** 1232 583.514004 583.514074 0.000070 0.00030 56 42**** 0 55 42**** 1233 583.170953 583.170925 -0.000028 0.00030 57 42**** 0 56 42**** 1234 582.827962 582.828048 0.000086 0.00030 58 42**** 0 57 42**** 1235 582.485031 582.484899 -0.000132 0.00030 59 42**** 0 58 42**** 1236 582.142161 582.142091 -0.000070 0.00030 60 42**** 0 59 42**** 1237 581.799353 581.799631 0.000278 0.00030 61 42**** 0 60 42**** 1238 581.456606 581.456566 -0.000040 0.00030 62 42**** 0 61 42**** 1239 581.113920 581.113838 -0.000082 0.00030 63 42**** 0 62 42**** 1240 580.771296 580.771205 -0.000091 0.00030 64 42**** 0 63 42**** 1241 580.086236 580.086019 -0.000217 0.00030 66 42**** 0 65 42**** 1242 587.285625 587.286242 0.000617 0.00030 45 43**** 0 44 43**** 1243 586.941958 586.942539 0.000581 0.00030 46 43**** 0 45 43**** 1244 586.598348 586.598363 0.000015 0.00030 47 43**** 0 46 43**** 1245 586.254795 586.254939 0.000144 0.00030 48 43**** 0 47 43**** 1246 585.911300 585.911440 0.000140 0.00030 49 43**** 0 48 43**** 1247 585.567863 585.567872 0.000009 0.00030 50 43**** 0 49 43**** 1248 585.224483 585.224640 0.000157 0.00030 51 43**** 0 50 43**** 1249 584.881163 584.881292 0.000129 0.00030 52 43**** 0 51 43**** 1250 584.537901 584.538149 0.000248 0.00030 53 43**** 0 52 43**** 1251 584.194698 584.194730 0.000032 0.00030 54 43**** 0 53 43**** 1252 583.851555 583.851391 -0.000164 0.00030 55 43**** 0 54 43**** 1253 583.508471 583.508660 0.000189 0.00030 56 43**** 0 55 43**** 1254 583.165447 583.165488 0.000041 0.00030 57 43**** 0 56 43**** 1255 582.822484 582.822407 -0.000077 0.00030 58 43**** 0 57 43**** 1256 582.479581 582.479685 0.000104 0.00030 59 43**** 0 58 43**** 1257 582.136739 582.136701 -0.000038 0.00030 60 43**** 0 59 43**** 1258 581.793958 581.794073 0.000115 0.00030 61 43**** 0 60 43**** 1259 581.451239 581.451090 -0.000149 0.00030 62 43**** 0 61 43**** 1260 581.108581 581.108485 -0.000096 0.00030 63 43**** 0 62 43**** 1261 580.765985 580.765944 -0.000041 0.00030 64 43**** 0 63 43**** 1262 585.218746 585.218975 0.000229 0.00030 51 44**** 0 50 44**** 1263 584.875454 584.875613 0.000159 0.00030 52 44**** 0 51 44**** 1264 584.532221 584.532192 -0.000029 0.00030 53 44**** 0 52 44**** 1265 584.189047 584.188994 -0.000053 0.00030 54 44**** 0 53 44**** 1266 583.845933 583.845985 0.000052 0.00030 55 44**** 0 54 44**** 1267 583.502879 583.502943 0.000064 0.00030 56 44**** 0 55 44**** 1268 583.159884 583.159870 -0.000014 0.00030 57 44**** 0 56 44**** 1269 582.816951 582.816885 -0.000066 0.00030 58 44**** 0 57 44**** 1270 582.131266 582.131110 -0.000156 0.00030 60 44**** 0 59 44**** 1271 581.445826 581.446003 0.000177 0.00030 62 44**** 0 61 44**** 1272 581.103199 581.103255 0.000056 0.00030 63 44**** 0 62 44**** 1273 584.869725 584.869732 0.000007 0.00030 52 45**** 0 51 45**** 1274 584.526521 584.526609 0.000088 0.00030 53 45**** 0 52 45**** 1275 584.183377 584.183549 0.000172 0.00030 54 45**** 0 53 45**** 1276 583.840293 583.840261 -0.000032 0.00030 55 45**** 0 54 45**** 1277 583.497268 583.497167 -0.000101 0.00030 56 45**** 0 55 45**** 1278 583.154304 583.154232 -0.000072 0.00030 57 45**** 0 56 45**** 1279 582.811401 582.811458 0.000057 0.00030 58 45**** 0 57 45**** 1280 582.468558 582.468504 -0.000054 0.00030 59 45**** 0 58 45**** 1281 582.125776 582.125691 -0.000085 0.00030 60 45**** 0 59 45**** 1282 581.783056 581.783024 -0.000032 0.00030 61 45**** 0 60 45**** 1283 581.440398 581.440519 0.000121 0.00030 62 45**** 0 61 45**** 1284 585.206876 585.207126 0.000250 0.00030 51 46**** 0 50 46**** 1285 584.863643 584.863770 0.000127 0.00030 52 46**** 0 51 46**** 1286 584.520469 584.520622 0.000153 0.00030 53 46**** 0 52 46**** 1287 584.177355 584.177517 0.000162 0.00030 54 46**** 0 53 46**** 1288 583.491307 583.491127 -0.000180 0.00030 56 46**** 0 55 46**** 1289 582.462688 582.462652 -0.000036 0.00030 59 46**** 0 58 46**** R-BRANCH OF THE NU5 COLD BAND Each transition frequency is an weighted average over the three sigma components. N6' = 0 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR cm-1 cm-1 cm-1 cm-1 1290 606.739744 606.739789 0.000045 0.00030 10 9**** 0 11 9**** 1291 607.085816 607.085754 -0.000062 0.00030 11 9**** 0 12 9**** 1292 607.431895 607.431991 0.000096 0.00030 12 9**** 0 13 9**** 1293 607.777979 607.778030 0.000051 0.00030 13 9**** 0 14 9**** 1294 608.124067 608.124137 0.000070 0.00030 14 9**** 0 15 9**** 1295 608.470159 608.470256 0.000097 0.00030 15 9**** 0 16 9**** 1296 608.816252 608.816312 0.000060 0.00030 16 9**** 0 17 9**** 1297 609.162346 609.162446 0.000100 0.00030 17 9**** 0 18 9**** 1298 609.508440 609.508605 0.000165 0.00030 18 9**** 0 19 9**** 1299 609.854531 609.854585 0.000054 0.00030 19 9**** 0 20 9**** 1300 610.200619 610.200689 0.000070 0.00030 20 9**** 0 21 9**** 1301 610.546703 610.546851 0.000148 0.00030 21 9**** 0 22 9**** 1302 610.892781 610.892818 0.000037 0.00030 22 9**** 0 23 9**** 1303 611.238852 611.238933 0.000081 0.00030 23 9**** 0 24 9**** 1304 611.584915 611.585013 0.000098 0.00030 24 9**** 0 25 9**** 1305 611.930967 611.931039 0.000072 0.00030 25 9**** 0 26 9**** 1306 612.277009 612.277100 0.000091 0.00030 26 9**** 0 27 9**** 1307 612.623038 612.623155 0.000117 0.00030 27 9**** 0 28 9**** 1308 612.969054 612.969192 0.000138 0.00030 28 9**** 0 29 9**** 1309 613.315054 613.315140 0.000086 0.00030 29 9**** 0 30 9**** 1310 613.661037 613.660994 -0.000043 0.00030 30 9**** 0 31 9**** 1311 614.007003 614.007070 0.000067 0.00030 31 9**** 0 32 9**** 1312 614.352950 614.353003 0.000053 0.00030 32 9**** 0 33 9**** 1313 614.698875 614.698975 0.000100 0.00030 33 9**** 0 34 9**** 1314 615.044778 615.044898 0.000120 0.00030 34 9**** 0 35 9**** 1315 615.390658 615.390714 0.000056 0.00030 35 9**** 0 36 9**** 1316 615.736513 615.736686 0.000173 0.00030 36 9**** 0 37 9**** 1317 616.082341 616.082438 0.000097 0.00030 37 9**** 0 38 9**** 1318 616.428141 616.428194 0.000053 0.00030 38 9**** 0 39 9**** 1319 616.773912 616.774103 0.000191 0.00030 39 9**** 0 40 9**** 1320 617.119652 617.119658 0.000006 0.00030 40 9**** 0 41 9**** 1321 617.465360 617.465449 0.000089 0.00030 41 9**** 0 42 9**** 1322 617.811034 617.811073 0.000039 0.00030 42 9**** 0 43 9**** 1323 618.156672 618.156815 0.000143 0.00030 43 9**** 0 44 9**** 1324 618.502274 618.502537 0.000263 0.00030 44 9**** 0 45 9**** 1325 618.847838 618.847779 -0.000059 0.00030 45 9**** 0 46 9**** 1326 619.193362 619.193192 -0.000170 0.00030 46 9**** 0 47 9**** 1327 619.538845 619.538812 -0.000033 0.00030 47 9**** 0 48 9**** 1328 619.884285 619.884529 0.000244 0.00030 48 9**** 0 49 9**** 1329 620.229680 620.229829 0.000149 0.00030 49 9**** 0 50 9**** 1330 620.575030 620.575144 0.000114 0.00030 50 9**** 0 51 9**** 1331 620.920333 620.920322 -0.000011 0.00030 51 9**** 0 52 9**** 1332 621.265588 621.265638 0.000050 0.00030 52 9**** 0 53 9**** 1333 621.610792 621.611070 0.000278 0.00030 53 9**** 0 54 9**** 1334 621.955944 621.956082 0.000138 0.00030 54 9**** 0 55 9**** 1335 622.301043 622.300970 -0.000073 0.00030 55 9**** 0 56 9**** 1336 622.646087 622.646167 0.000080 0.00030 56 9**** 0 57 9**** 1337 622.991076 622.991051 -0.000025 0.00030 57 9**** 0 58 9**** 1338 623.336006 623.336249 0.000243 0.00030 58 9**** 0 59 9**** 1339 623.680878 623.680965 0.000087 0.00030 59 9**** 0 60 9**** 1340 624.025688 624.025565 -0.000123 0.00030 60 9**** 0 61 9**** 1341 624.715122 624.715028 -0.000094 0.00030 62 9**** 0 63 9**** 1342 625.059742 625.059519 -0.000223 0.00030 63 9**** 0 64 9**** 1343 625.404295 625.404211 -0.000084 0.00030 64 9**** 0 65 9**** 1344 625.748781 625.748580 -0.000201 0.00030 65 9**** 0 66 9**** 1345 626.093197 626.093081 -0.000116 0.00030 66 9**** 0 67 9**** 1346 626.437542 626.437513 -0.000029 0.00030 67 9**** 0 68 9**** 1347 626.781815 626.781578 -0.000237 0.00030 68 9**** 0 69 9**** 1348 627.126014 627.125848 -0.000166 0.00030 69 9**** 0 70 9**** 1349 627.470138 627.469923 -0.000215 0.00030 70 9**** 0 71 9**** 1350 608.122708 608.122881 0.000173 0.00030 14 10**** 0 15 10**** 1351 608.468798 608.468866 0.000068 0.00030 15 10**** 0 16 10**** 1352 608.814890 608.814983 0.000093 0.00030 16 10**** 0 17 10**** 1353 609.160983 609.161070 0.000087 0.00030 17 10**** 0 18 10**** 1354 609.507075 609.507205 0.000130 0.00030 18 10**** 0 19 10**** 1355 609.853165 609.853339 0.000174 0.00030 19 10**** 0 20 10**** 1356 610.199252 610.199385 0.000133 0.00030 20 10**** 0 21 10**** 1357 610.545335 610.545409 0.000074 0.00030 21 10**** 0 22 10**** 1358 610.891412 610.891629 0.000217 0.00030 22 10**** 0 23 10**** 1359 611.237482 611.237579 0.000097 0.00030 23 10**** 0 24 10**** 1360 611.583543 611.583478 -0.000065 0.00030 24 10**** 0 25 10**** 1361 611.929595 611.929793 0.000198 0.00030 25 10**** 0 26 10**** 1362 612.275636 612.275727 0.000091 0.00030 26 10**** 0 27 10**** 1363 612.621664 612.621723 0.000059 0.00030 27 10**** 0 28 10**** 1364 612.967679 612.967774 0.000095 0.00030 28 10**** 0 29 10**** 1365 613.313678 613.313761 0.000083 0.00030 29 10**** 0 30 10**** 1366 613.659661 613.659891 0.000230 0.00030 30 10**** 0 31 10**** 1367 614.005626 614.005608 -0.000018 0.00030 31 10**** 0 32 10**** 1368 614.351572 614.351492 -0.000080 0.00030 32 10**** 0 33 10**** 1369 614.697497 614.697646 0.000149 0.00030 33 10**** 0 34 10**** 1370 615.043400 615.043476 0.000076 0.00030 34 10**** 0 35 10**** 1371 615.735133 615.735185 0.000052 0.00030 36 10**** 0 37 10**** 1372 616.080961 616.080854 -0.000107 0.00030 37 10**** 0 38 10**** 1373 616.426761 616.426958 0.000197 0.00030 38 10**** 0 39 10**** 1374 616.772531 616.772573 0.000042 0.00030 39 10**** 0 40 10**** 1375 617.463979 617.464105 0.000126 0.00030 41 10**** 0 42 10**** 1376 617.809652 617.809602 -0.000050 0.00030 42 10**** 0 43 10**** 1377 618.155291 618.155530 0.000239 0.00030 43 10**** 0 44 10**** 1378 618.500892 618.501002 0.000110 0.00030 44 10**** 0 45 10**** 1379 619.191980 619.192192 0.000212 0.00030 46 10**** 0 47 10**** 1380 619.882902 619.882989 0.000087 0.00030 48 10**** 0 49 10**** 1381 620.228298 620.228010 -0.000288 0.00030 49 10**** 0 50 10**** 1382 620.918951 620.919072 0.000121 0.00030 51 10**** 0 52 10**** 1383 621.264205 621.264240 0.000035 0.00030 52 10**** 0 53 10**** 1384 621.609409 621.609285 -0.000124 0.00030 53 10**** 0 54 10**** 1385 621.954562 621.954659 0.000097 0.00030 54 10**** 0 55 10**** 1386 622.644705 622.644711 0.000006 0.00030 56 10**** 0 57 10**** 1387 622.989694 622.989516 -0.000178 0.00030 57 10**** 0 58 10**** 1388 623.334624 623.334591 -0.000033 0.00030 58 10**** 0 59 10**** 1389 624.369055 624.369065 0.000010 0.00030 61 10**** 0 62 10**** 1390 607.429061 607.429078 0.000017 0.00030 12 11**** 0 13 11**** 1391 607.775142 607.775190 0.000048 0.00030 13 11**** 0 14 11**** 1392 608.121227 608.121253 0.000026 0.00030 14 11**** 0 15 11**** 1393 608.467315 608.467363 0.000048 0.00030 15 11**** 0 16 11**** 1394 608.813406 608.813416 0.000010 0.00030 16 11**** 0 17 11**** 1395 609.159497 609.159491 -0.000006 0.00030 17 11**** 0 18 11**** 1396 609.505587 609.505608 0.000021 0.00030 18 11**** 0 19 11**** 1397 609.851676 609.851706 0.000030 0.00030 19 11**** 0 20 11**** 1398 610.197761 610.197791 0.000030 0.00030 20 11**** 0 21 11**** 1399 610.543843 610.543832 -0.000011 0.00030 21 11**** 0 22 11**** 1400 610.889918 610.889954 0.000036 0.00030 22 11**** 0 23 11**** 1401 611.235987 611.236015 0.000028 0.00030 23 11**** 0 24 11**** 1402 611.582047 611.582124 0.000077 0.00030 24 11**** 0 25 11**** 1403 611.928098 611.928141 0.000043 0.00030 25 11**** 0 26 11**** 1404 612.274138 612.274108 -0.000030 0.00030 26 11**** 0 27 11**** 1405 612.620165 612.620237 0.000072 0.00030 27 11**** 0 28 11**** 1406 612.966179 612.966234 0.000055 0.00030 28 11**** 0 29 11**** 1407 613.312177 613.312123 -0.000054 0.00030 29 11**** 0 30 11**** 1408 613.658160 613.658233 0.000073 0.00030 30 11**** 0 31 11**** 1409 614.004124 614.004196 0.000072 0.00030 31 11**** 0 32 11**** 1410 614.350069 614.350183 0.000114 0.00030 32 11**** 0 33 11**** 1411 614.695993 614.695949 -0.000044 0.00030 33 11**** 0 34 11**** 1412 615.041895 615.041843 -0.000052 0.00030 34 11**** 0 35 11**** 1413 615.387774 615.387845 0.000071 0.00030 35 11**** 0 36 11**** 1414 615.733628 615.733645 0.000017 0.00030 36 11**** 0 37 11**** 1415 616.079455 616.079598 0.000143 0.00030 37 11**** 0 38 11**** 1416 616.425255 616.425315 0.000060 0.00030 38 11**** 0 39 11**** 1417 616.771025 616.770925 -0.000100 0.00030 39 11**** 0 40 11**** 1418 617.116764 617.116804 0.000040 0.00030 40 11**** 0 41 11**** 1419 617.462471 617.462492 0.000021 0.00030 41 11**** 0 42 11**** 1420 617.808144 617.808307 0.000163 0.00030 42 11**** 0 43 11**** 1421 618.153783 618.153789 0.000006 0.00030 43 11**** 0 44 11**** 1422 618.499384 618.499276 -0.000108 0.00030 44 11**** 0 45 11**** 1423 618.844947 618.845047 0.000100 0.00030 45 11**** 0 46 11**** 1424 619.190471 619.190451 -0.000020 0.00030 46 11**** 0 47 11**** 1425 619.881393 619.881478 0.000085 0.00030 48 11**** 0 49 11**** 1426 620.226789 620.226779 -0.000010 0.00030 49 11**** 0 50 11**** 1427 620.572139 620.572079 -0.000060 0.00030 50 11**** 0 51 11**** 1428 620.917441 620.917478 0.000037 0.00030 51 11**** 0 52 11**** 1429 621.262696 621.262857 0.000161 0.00030 52 11**** 0 53 11**** 1430 621.607899 621.607971 0.000072 0.00030 53 11**** 0 54 11**** 1431 621.953052 621.953080 0.000028 0.00030 54 11**** 0 55 11**** 1432 622.298151 622.298091 -0.000060 0.00030 55 11**** 0 56 11**** 1433 622.643195 622.643235 0.000040 0.00030 56 11**** 0 57 11**** 1434 623.333114 623.333095 -0.000019 0.00030 58 11**** 0 59 11**** 1435 623.677985 623.678003 0.000018 0.00030 59 11**** 0 60 11**** 1436 624.022796 624.022740 -0.000056 0.00030 60 11**** 0 61 11**** 1437 624.712229 624.712384 0.000155 0.00030 62 11**** 0 63 11**** 1438 625.056849 625.056763 -0.000086 0.00030 63 11**** 0 64 11**** 1439 625.401402 625.401254 -0.000148 0.00030 64 11**** 0 65 11**** 1440 625.745887 625.745946 0.000059 0.00030 65 11**** 0 66 11**** 1441 626.090303 626.089927 -0.000376 0.00030 66 11**** 0 67 11**** 1442 626.434648 626.434306 -0.000342 0.00030 67 11**** 0 68 11**** 1443 626.778920 626.778581 -0.000339 0.00030 68 11**** 0 69 11**** 1444 607.427271 607.427344 0.000073 0.00030 12 12**** 0 13 12**** 1445 607.773349 607.773326 -0.000023 0.00030 13 12**** 0 14 12**** 1446 608.119432 608.119448 0.000016 0.00030 14 12**** 0 15 12**** 1447 608.465519 608.465484 -0.000035 0.00030 15 12**** 0 16 12**** 1448 608.811607 608.811599 -0.000008 0.00030 16 12**** 0 17 12**** 1449 609.157696 609.157686 -0.000010 0.00030 17 12**** 0 18 12**** 1450 609.503785 609.503772 -0.000013 0.00030 18 12**** 0 19 12**** 1451 609.849872 609.849862 -0.000010 0.00030 19 12**** 0 20 12**** 1452 610.195956 610.195954 -0.000002 0.00030 20 12**** 0 21 12**** 1453 610.542036 610.542044 0.000008 0.00030 21 12**** 0 22 12**** 1454 610.888110 610.888105 -0.000005 0.00030 22 12**** 0 23 12**** 1455 611.234177 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1710 621.252437 621.252415 -0.000022 0.00030 52 16**** 0 53 16**** 1711 621.597640 621.597461 -0.000179 0.00030 53 16**** 0 54 16**** 1712 621.942792 621.942825 0.000033 0.00030 54 16**** 0 55 16**** 1713 622.287891 622.288032 0.000141 0.00030 55 16**** 0 56 16**** 1714 622.632934 622.632877 -0.000057 0.00030 56 16**** 0 57 16**** 1715 622.977922 622.977809 -0.000113 0.00030 57 16**** 0 58 16**** 1716 623.322852 623.322845 -0.000007 0.00030 58 16**** 0 59 16**** 1717 623.667723 623.667861 0.000138 0.00030 59 16**** 0 60 16**** 1718 624.012532 624.012519 -0.000013 0.00030 60 16**** 0 61 16**** 1719 624.357280 624.357192 -0.000088 0.00030 61 16**** 0 62 16**** 1720 624.701964 624.701806 -0.000158 0.00030 62 16**** 0 63 16**** 1721 625.046583 625.046542 -0.000041 0.00030 63 16**** 0 64 16**** 1722 625.391135 625.391210 0.000075 0.00030 64 16**** 0 65 16**** 1723 625.735619 625.735544 -0.000075 0.00030 65 16**** 0 66 16**** 1724 626.080033 626.080040 0.000007 0.00030 66 16**** 0 67 16**** 1725 626.424376 626.424090 -0.000286 0.00030 67 16**** 0 68 16**** 1726 626.768646 626.768503 -0.000143 0.00030 68 16**** 0 69 16**** 1727 627.112842 627.112508 -0.000334 0.00030 69 16**** 0 70 16**** 1728 627.456963 627.456706 -0.000257 0.00030 70 16**** 0 71 16**** 1729 609.147017 609.146892 -0.000125 0.00030 17 17**** 0 18 17**** 1730 609.493096 609.493051 -0.000045 0.00030 18 17**** 0 19 17**** 1731 609.839173 609.839168 -0.000005 0.00030 19 17**** 0 20 17**** 1732 610.185247 610.185241 -0.000006 0.00030 20 17**** 0 21 17**** 1733 610.531318 610.531326 0.000008 0.00030 21 17**** 0 22 17**** 1734 610.877384 610.877372 -0.000012 0.00030 22 17**** 0 23 17**** 1735 611.223443 611.223440 -0.000003 0.00030 23 17**** 0 24 17**** 1736 611.569494 611.569471 -0.000023 0.00030 24 17**** 0 25 17**** 1737 611.915536 611.915556 0.000020 0.00030 25 17**** 0 26 17**** 1738 612.261568 612.261587 0.000019 0.00030 26 17**** 0 27 17**** 1739 612.607587 612.607638 0.000051 0.00030 27 17**** 0 28 17**** 1740 612.953594 612.953591 -0.000003 0.00030 28 17**** 0 29 17**** 1741 613.299585 613.299558 -0.000027 0.00030 29 17**** 0 30 17**** 1742 613.645561 613.645570 0.000009 0.00030 30 17**** 0 31 17**** 1743 613.991519 613.991503 -0.000016 0.00030 31 17**** 0 32 17**** 1744 614.337459 614.337475 0.000016 0.00030 32 17**** 0 33 17**** 1745 614.683378 614.683428 0.000050 0.00030 33 17**** 0 34 17**** 1746 615.029275 615.029204 -0.000071 0.00030 34 17**** 0 35 17**** 1747 615.375149 615.375260 0.000111 0.00030 35 17**** 0 36 17**** 1748 615.720999 615.720997 -0.000002 0.00030 36 17**** 0 37 17**** 1749 616.066822 616.066749 -0.000073 0.00030 37 17**** 0 38 17**** 1750 616.412618 616.412593 -0.000025 0.00030 38 17**** 0 39 17**** 1751 616.758385 616.758375 -0.000010 0.00030 39 17**** 0 40 17**** 1752 617.104122 617.104234 0.000112 0.00030 40 17**** 0 41 17**** 1753 617.449826 617.449917 0.000091 0.00030 41 17**** 0 42 17**** 1754 617.795497 617.795458 -0.000039 0.00030 42 17**** 0 43 17**** 1755 618.141133 618.141087 -0.000046 0.00030 43 17**** 0 44 17**** 1756 618.486733 618.486740 0.000007 0.00030 44 17**** 0 45 17**** 1757 618.832294 618.832321 0.000027 0.00030 45 17**** 0 46 17**** 1758 619.177816 619.177842 0.000026 0.00030 46 17**** 0 47 17**** 1759 619.523298 619.523500 0.000202 0.00030 47 17**** 0 48 17**** 1760 619.868736 619.868698 -0.000038 0.00030 48 17**** 0 49 17**** 1761 620.214131 620.214037 -0.000094 0.00030 49 17**** 0 50 17**** 1762 620.559480 620.559578 0.000098 0.00030 50 17**** 0 51 17**** 1763 620.904782 620.904790 0.000008 0.00030 51 17**** 0 52 17**** 1764 621.250036 621.250203 0.000167 0.00030 52 17**** 0 53 17**** 1765 621.595239 621.595283 0.000044 0.00030 53 17**** 0 54 17**** 1766 621.940391 621.940358 -0.000033 0.00030 54 17**** 0 55 17**** 1767 622.285489 622.285526 0.000037 0.00030 55 17**** 0 56 17**** 1768 622.630533 622.630351 -0.000182 0.00030 56 17**** 0 57 17**** 1769 622.975521 622.975666 0.000145 0.00030 57 17**** 0 58 17**** 1770 623.320451 623.320564 0.000113 0.00030 58 17**** 0 59 17**** 1771 623.665322 623.665296 -0.000026 0.00030 59 17**** 0 60 17**** 1772 624.010132 624.010032 -0.000100 0.00030 60 17**** 0 61 17**** 1773 624.354879 624.354877 -0.000002 0.00030 61 17**** 0 62 17**** 1774 624.699563 624.699657 0.000094 0.00030 62 17**** 0 63 17**** 1775 625.044182 625.044144 -0.000038 0.00030 63 17**** 0 64 17**** 1776 625.388734 625.388713 -0.000021 0.00030 64 17**** 0 65 17**** 1777 625.733218 625.733210 -0.000008 0.00030 65 17**** 0 66 17**** 1778 626.077632 626.077603 -0.000029 0.00030 66 17**** 0 67 17**** 1779 626.421974 626.421903 -0.000071 0.00030 67 17**** 0 68 17**** 1780 626.766244 626.766418 0.000174 0.00030 68 17**** 0 69 17**** 1781 609.490423 609.490471 0.000048 0.00030 18 18**** 0 19 18**** 1782 609.836498 609.836441 -0.000057 0.00030 19 18**** 0 20 18**** 1783 610.182570 610.182494 -0.000076 0.00030 20 18**** 0 21 18**** 1784 610.528639 610.528626 -0.000013 0.00030 21 18**** 0 22 18**** 1785 610.874702 610.874694 -0.000008 0.00030 22 18**** 0 23 18**** 1786 611.220759 611.220767 0.000008 0.00030 23 18**** 0 24 18**** 1787 611.566809 611.566778 -0.000031 0.00030 24 18**** 0 25 18**** 1788 611.912849 611.912844 -0.000005 0.00030 25 18**** 0 26 18**** 1789 612.258878 612.258865 -0.000013 0.00030 26 18**** 0 27 18**** 1790 612.604896 612.604902 0.000006 0.00030 27 18**** 0 28 18**** 1791 612.950901 612.950884 -0.000017 0.00030 28 18**** 0 29 18**** 1792 613.296891 613.296890 -0.000001 0.00030 29 18**** 0 30 18**** 1793 613.642866 613.642804 -0.000062 0.00030 30 18**** 0 31 18**** 1794 613.988822 613.988835 0.000013 0.00030 31 18**** 0 32 18**** 1795 614.334761 614.334758 -0.000003 0.00030 32 18**** 0 33 18**** 1796 614.680678 614.680682 0.000004 0.00030 33 18**** 0 34 18**** 1797 615.026575 615.026526 -0.000049 0.00030 34 18**** 0 35 18**** 1798 615.372448 615.372440 -0.000008 0.00030 35 18**** 0 36 18**** 1799 615.718296 615.718344 0.000048 0.00030 36 18**** 0 37 18**** 1800 616.064119 616.064086 -0.000033 0.00030 37 18**** 0 38 18**** 1801 616.409914 616.409925 0.000011 0.00030 38 18**** 0 39 18**** 1802 616.755680 616.755716 0.000036 0.00030 39 18**** 0 40 18**** 1803 617.101416 617.101390 -0.000026 0.00030 40 18**** 0 41 18**** 1804 617.447119 617.447166 0.000047 0.00030 41 18**** 0 42 18**** 1805 617.792790 617.792810 0.000020 0.00030 42 18**** 0 43 18**** 1806 618.138425 618.138488 0.000063 0.00030 43 18**** 0 44 18**** 1807 618.484024 618.484068 0.000044 0.00030 44 18**** 0 45 18**** 1808 618.829585 618.829535 -0.000050 0.00030 45 18**** 0 46 18**** 1809 619.175107 619.175022 -0.000085 0.00030 46 18**** 0 47 18**** 1810 619.520588 619.520631 0.000043 0.00030 47 18**** 0 48 18**** 1811 619.866026 619.866049 0.000023 0.00030 48 18**** 0 49 18**** 1812 620.211420 620.211404 -0.000016 0.00030 49 18**** 0 50 18**** 1813 620.556769 620.556959 0.000190 0.00030 50 18**** 0 51 18**** 1814 620.902070 620.902078 0.000008 0.00030 51 18**** 0 52 18**** 1815 621.247323 621.247158 -0.000165 0.00030 52 18**** 0 53 18**** 1816 621.592526 621.592610 0.000084 0.00030 53 18**** 0 54 18**** 1817 621.937678 621.937729 0.000051 0.00030 54 18**** 0 55 18**** 1818 622.282776 622.282893 0.000117 0.00030 55 18**** 0 56 18**** 1819 622.627819 622.627914 0.000095 0.00030 56 18**** 0 57 18**** 1820 622.972806 622.972846 0.000040 0.00030 57 18**** 0 58 18**** 1821 623.317736 623.317808 0.000072 0.00030 58 18**** 0 59 18**** 1822 623.662606 623.662496 -0.000110 0.00030 59 18**** 0 60 18**** 1823 624.007415 624.007477 0.000062 0.00030 60 18**** 0 61 18**** 1824 624.352162 624.352292 0.000130 0.00030 61 18**** 0 62 18**** 1825 624.696846 624.696936 0.000090 0.00030 62 18**** 0 63 18**** 1826 625.041464 625.041348 -0.000116 0.00030 63 18**** 0 64 18**** 1827 625.386015 625.386065 0.000050 0.00030 64 18**** 0 65 18**** 1828 625.730497 625.730640 0.000143 0.00030 65 18**** 0 66 18**** 1829 626.074910 626.074886 -0.000024 0.00030 66 18**** 0 67 18**** 1830 626.419252 626.419348 0.000096 0.00030 67 18**** 0 68 18**** 1831 626.763521 626.763442 -0.000079 0.00030 68 18**** 0 69 18**** 1832 627.107715 627.107648 -0.000067 0.00030 69 18**** 0 70 18**** 1833 627.451834 627.451688 -0.000146 0.00030 70 18**** 0 71 18**** 1834 609.833698 609.833601 -0.000097 0.00030 19 19**** 0 20 19**** 1835 610.179768 610.179726 -0.000042 0.00030 20 19**** 0 21 19**** 1836 610.525835 610.525799 -0.000036 0.00030 21 19**** 0 22 19**** 1837 610.871896 610.871827 -0.000069 0.00030 22 19**** 0 23 19**** 1838 611.217951 611.217888 -0.000063 0.00030 23 19**** 0 24 19**** 1839 611.563998 611.563954 -0.000044 0.00030 24 19**** 0 25 19**** 1840 611.910037 611.910000 -0.000037 0.00030 25 19**** 0 26 19**** 1841 612.256065 612.256021 -0.000044 0.00030 26 19**** 0 27 19**** 1842 612.602081 612.602018 -0.000063 0.00030 27 19**** 0 28 19**** 1843 612.948085 612.948073 -0.000012 0.00030 28 19**** 0 29 19**** 1844 613.294074 613.294021 -0.000053 0.00030 29 19**** 0 30 19**** 1845 613.640047 613.640107 0.000060 0.00030 30 19**** 0 31 19**** 1846 613.986003 613.985942 -0.000061 0.00030 31 19**** 0 32 19**** 1847 614.331940 614.331943 0.000003 0.00030 32 19**** 0 33 19**** 1848 614.677857 614.677793 -0.000064 0.00030 33 19**** 0 34 19**** 1849 615.023752 615.023672 -0.000080 0.00030 34 19**** 0 35 19**** 1850 615.369624 615.369605 -0.000019 0.00030 35 19**** 0 36 19**** 1851 615.715472 615.715489 0.000017 0.00030 36 19**** 0 37 19**** 1852 616.061294 616.061270 -0.000024 0.00030 37 19**** 0 38 19**** 1853 616.407089 616.406983 -0.000106 0.00030 38 19**** 0 39 19**** 1854 616.752855 616.752838 -0.000017 0.00030 39 19**** 0 40 19**** 1855 617.098590 617.098574 -0.000016 0.00030 40 19**** 0 41 19**** 1856 617.444294 617.444243 -0.000051 0.00030 41 19**** 0 42 19**** 1857 617.789964 617.790014 0.000050 0.00030 42 19**** 0 43 19**** 1858 618.135599 618.135540 -0.000059 0.00030 43 19**** 0 44 19**** 1859 618.481198 618.481179 -0.000019 0.00030 44 19**** 0 45 19**** 1860 618.826759 618.826690 -0.000069 0.00030 45 19**** 0 46 19**** 1861 619.172281 619.172270 -0.000011 0.00030 46 19**** 0 47 19**** 1862 619.517762 619.517831 0.000069 0.00030 47 19**** 0 48 19**** 1863 619.863200 619.863185 -0.000015 0.00030 48 19**** 0 49 19**** 1864 620.208595 620.208491 -0.000104 0.00030 49 19**** 0 50 19**** 1865 620.553944 620.553717 -0.000227 0.00030 50 19**** 0 51 19**** 1866 620.899246 620.899302 0.000056 0.00030 51 19**** 0 52 19**** 1867 621.244499 621.244495 -0.000004 0.00030 52 19**** 0 53 19**** 1868 621.589703 621.589687 -0.000016 0.00030 53 19**** 0 54 19**** 1869 621.934855 621.934851 -0.000004 0.00030 54 19**** 0 55 19**** 1870 622.279953 622.279808 -0.000145 0.00030 55 19**** 0 56 19**** 1871 622.624997 622.625005 0.000008 0.00030 56 19**** 0 57 19**** 1872 622.969985 622.970016 0.000031 0.00030 57 19**** 0 58 19**** 1873 623.314915 623.314831 -0.000084 0.00030 58 19**** 0 59 19**** 1874 623.659786 623.659842 0.000056 0.00030 59 19**** 0 60 19**** 1875 624.004596 624.004589 -0.000007 0.00030 60 19**** 0 61 19**** 1876 624.349344 624.349340 -0.000004 0.00030 61 19**** 0 62 19**** 1877 624.694028 624.693929 -0.000099 0.00030 62 19**** 0 63 19**** 1878 625.038646 625.038528 -0.000118 0.00030 63 19**** 0 64 19**** 1879 625.383198 625.383137 -0.000061 0.00030 64 19**** 0 65 19**** 1880 625.727682 625.727781 0.000099 0.00030 65 19**** 0 66 19**** 1881 626.072095 626.072076 -0.000019 0.00030 66 19**** 0 67 19**** 1882 626.416437 626.416160 -0.000277 0.00030 67 19**** 0 68 19**** 1883 626.760707 626.760940 0.000233 0.00030 68 19**** 0 69 19**** 1884 627.104902 627.104789 -0.000113 0.00030 69 19**** 0 70 19**** 1885 627.449022 627.449109 0.000087 0.00030 70 19**** 0 71 19**** 1886 610.176933 610.176813 -0.000120 0.00030 20 20**** 0 21 20**** 1887 610.522997 610.522986 -0.000011 0.00030 21 20**** 0 22 20**** 1888 610.869057 610.868985 -0.000072 0.00030 22 20**** 0 23 20**** 1889 611.215110 611.215078 -0.000032 0.00030 23 20**** 0 24 20**** 1890 611.561155 611.561089 -0.000066 0.00030 24 20**** 0 25 20**** 1891 611.907192 611.907135 -0.000057 0.00030 25 20**** 0 26 20**** 1892 612.253218 612.253206 -0.000012 0.00030 26 20**** 0 27 20**** 1893 612.599233 612.599178 -0.000055 0.00030 27 20**** 0 28 20**** 1894 612.945235 612.945205 -0.000030 0.00030 28 20**** 0 29 20**** 1895 613.291223 613.291236 0.000013 0.00030 29 20**** 0 30 20**** 1896 613.637194 613.637134 -0.000060 0.00030 30 20**** 0 31 20**** 1897 613.983149 613.983161 0.000012 0.00030 31 20**** 0 32 20**** 1898 614.329085 614.329006 -0.000079 0.00030 32 20**** 0 33 20**** 1899 614.675001 614.674973 -0.000028 0.00030 33 20**** 0 34 20**** 1900 615.020896 615.020877 -0.000019 0.00030 34 20**** 0 35 20**** 1901 615.366767 615.366722 -0.000045 0.00030 35 20**** 0 36 20**** 1902 615.712614 615.712620 0.000006 0.00030 36 20**** 0 37 20**** 1903 616.058436 616.058357 -0.000079 0.00030 37 20**** 0 38 20**** 1904 616.404230 616.404310 0.000080 0.00030 38 20**** 0 39 20**** 1905 616.749995 616.749983 -0.000012 0.00030 39 20**** 0 40 20**** 1906 617.095730 617.095720 -0.000010 0.00030 40 20**** 0 41 20**** 1907 617.441434 617.441334 -0.000100 0.00030 41 20**** 0 42 20**** 1908 617.787104 617.787091 -0.000013 0.00030 42 20**** 0 43 20**** 1909 618.132739 618.132755 0.000016 0.00030 43 20**** 0 44 20**** 1910 618.478338 618.478315 -0.000023 0.00030 44 20**** 0 45 20**** 1911 618.823899 618.823949 0.000050 0.00030 45 20**** 0 46 20**** 1912 619.169421 619.169436 0.000015 0.00030 46 20**** 0 47 20**** 1913 619.514902 619.514824 -0.000078 0.00030 47 20**** 0 48 20**** 1914 619.860340 619.860306 -0.000034 0.00030 48 20**** 0 49 20**** 1915 620.205735 620.205788 0.000053 0.00030 49 20**** 0 50 20**** 1916 620.551084 620.551099 0.000015 0.00030 50 20**** 0 51 20**** 1917 620.896386 620.896350 -0.000036 0.00030 51 20**** 0 52 20**** 1918 621.241640 621.241739 0.000099 0.00030 52 20**** 0 53 20**** 1919 621.586844 621.586755 -0.000089 0.00030 53 20**** 0 54 20**** 1920 621.931996 621.931967 -0.000029 0.00030 54 20**** 0 55 20**** 1921 622.277095 622.277120 0.000025 0.00030 55 20**** 0 56 20**** 1922 622.622139 622.622195 0.000056 0.00030 56 20**** 0 57 20**** 1923 622.967128 622.967270 0.000142 0.00030 57 20**** 0 58 20**** 1924 623.312058 623.312026 -0.000032 0.00030 58 20**** 0 59 20**** 1925 623.656929 623.656905 -0.000024 0.00030 59 20**** 0 60 20**** 1926 624.001739 624.001754 0.000015 0.00030 60 20**** 0 61 20**** 1927 624.346488 624.346515 0.000027 0.00030 61 20**** 0 62 20**** 1928 624.691172 624.691139 -0.000033 0.00030 62 20**** 0 63 20**** 1929 625.035791 625.035748 -0.000043 0.00030 63 20**** 0 64 20**** 1930 625.380343 625.380396 0.000053 0.00030 64 20**** 0 65 20**** 1931 625.724826 625.724902 0.000076 0.00030 65 20**** 0 66 20**** 1932 626.069240 626.069202 -0.000038 0.00030 66 20**** 0 67 20**** 1933 626.413582 626.413472 -0.000110 0.00030 67 20**** 0 68 20**** 1934 626.757852 626.757875 0.000023 0.00030 68 20**** 0 69 20**** 1935 627.102047 627.102141 0.000094 0.00030 69 20**** 0 70 20**** 1936 627.446166 627.445911 -0.000255 0.00030 70 20**** 0 71 20**** 1937 610.519881 610.519967 0.000086 0.00030 21 21**** 0 22 21**** 1938 610.865937 610.865947 0.000010 0.00030 22 21**** 0 23 21**** 1939 611.211988 611.211915 -0.000073 0.00030 23 21**** 0 24 21**** 1940 611.558031 611.557946 -0.000085 0.00030 24 21**** 0 25 21**** 1941 611.904066 611.904026 -0.000040 0.00030 25 21**** 0 26 21**** 1942 612.250091 612.250082 -0.000009 0.00030 26 21**** 0 27 21**** 1943 612.596104 612.596084 -0.000020 0.00030 27 21**** 0 28 21**** 1944 612.942104 612.942129 0.000025 0.00030 28 21**** 0 29 21**** 1945 613.288090 613.288062 -0.000028 0.00030 29 21**** 0 30 21**** 1946 613.634060 613.634079 0.000019 0.00030 30 21**** 0 31 21**** 1947 613.980013 613.980027 0.000014 0.00030 31 21**** 0 32 21**** 1948 614.325948 614.325960 0.000012 0.00030 32 21**** 0 33 21**** 1949 614.671862 614.671923 0.000061 0.00030 33 21**** 0 34 21**** 1950 615.017756 615.017713 -0.000043 0.00030 34 21**** 0 35 21**** 1951 615.363626 615.363647 0.000021 0.00030 35 21**** 0 36 21**** 1952 615.709473 615.709433 -0.000040 0.00030 36 21**** 0 37 21**** 1953 616.055293 616.055341 0.000048 0.00030 37 21**** 0 38 21**** 1954 616.401086 616.401054 -0.000032 0.00030 38 21**** 0 39 21**** 1955 616.746851 616.746869 0.000018 0.00030 39 21**** 0 40 21**** 1956 617.092585 617.092528 -0.000057 0.00030 40 21**** 0 41 21**** 1957 617.438288 617.438264 -0.000024 0.00030 41 21**** 0 42 21**** 1958 617.783957 617.783996 0.000039 0.00030 42 21**** 0 43 21**** 1959 618.129592 618.129665 0.000073 0.00030 43 21**** 0 44 21**** 1960 618.475190 618.475220 0.000030 0.00030 44 21**** 0 45 21**** 1961 618.820751 618.820737 -0.000014 0.00030 45 21**** 0 46 21**** 1962 619.166272 619.166336 0.000064 0.00030 46 21**** 0 47 21**** 1963 619.511753 619.511612 -0.000141 0.00030 47 21**** 0 48 21**** 1964 619.857191 619.857241 0.000050 0.00030 48 21**** 0 49 21**** 1965 620.202586 620.202635 0.000049 0.00030 49 21**** 0 50 21**** 1966 620.547935 620.548028 0.000093 0.00030 50 21**** 0 51 21**** 1967 620.893237 620.893250 0.000013 0.00030 51 21**** 0 52 21**** 1968 621.238490 621.238517 0.000027 0.00030 52 21**** 0 53 21**** 1969 621.583694 621.583797 0.000103 0.00030 53 21**** 0 54 21**** 1970 621.928845 621.928867 0.000022 0.00030 54 21**** 0 55 21**** 1971 622.273944 622.274045 0.000101 0.00030 55 21**** 0 56 21**** 1972 622.618988 622.619037 0.000049 0.00030 56 21**** 0 57 21**** 1973 622.963976 622.963768 -0.000208 0.00030 57 21**** 0 58 21**** 1974 623.308906 623.309024 0.000118 0.00030 58 21**** 0 59 21**** 1975 623.653777 623.653839 0.000062 0.00030 59 21**** 0 60 21**** 1976 623.998587 623.998708 0.000121 0.00030 60 21**** 0 61 21**** 1977 624.343334 624.343450 0.000116 0.00030 61 21**** 0 62 21**** 1978 624.688018 624.688019 0.000001 0.00030 62 21**** 0 63 21**** 1979 625.032636 625.032736 0.000100 0.00030 63 21**** 0 64 21**** 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613.630752 613.630700 -0.000052 0.00030 30 22**** 0 31 22**** 1996 613.976704 613.976643 -0.000061 0.00030 31 22**** 0 32 22**** 1997 614.322638 614.322625 -0.000013 0.00030 32 22**** 0 33 22**** 1998 614.668552 614.668543 -0.000009 0.00030 33 22**** 0 34 22**** 1999 615.014444 615.014427 -0.000017 0.00030 34 22**** 0 35 22**** 2000 615.360314 615.360258 -0.000056 0.00030 35 22**** 0 36 22**** 2001 615.706160 615.706068 -0.000092 0.00030 36 22**** 0 37 22**** 2002 616.051980 616.052011 0.000031 0.00030 37 22**** 0 38 22**** 2003 616.397773 616.397679 -0.000094 0.00030 38 22**** 0 39 22**** 2004 616.743537 616.743554 0.000017 0.00030 39 22**** 0 40 22**** 2005 617.089271 617.089222 -0.000049 0.00030 40 22**** 0 41 22**** 2006 617.434974 617.434983 0.000009 0.00030 41 22**** 0 42 22**** 2007 617.780643 617.780603 -0.000040 0.00030 42 22**** 0 43 22**** 2008 618.126278 618.126438 0.000160 0.00030 43 22**** 0 44 22**** 2009 618.471876 618.471856 -0.000020 0.00030 44 22**** 0 45 22**** 2010 618.817437 618.817313 -0.000124 0.00030 45 22**** 0 46 22**** 2011 619.162959 619.163016 0.000057 0.00030 46 22**** 0 47 22**** 2012 619.508440 619.508576 0.000136 0.00030 47 22**** 0 48 22**** 2013 619.853879 619.853838 -0.000041 0.00030 48 22**** 0 49 22**** 2014 620.199274 620.199187 -0.000087 0.00030 49 22**** 0 50 22**** 2015 620.544623 620.544615 -0.000008 0.00030 50 22**** 0 51 22**** 2016 620.889926 620.889866 -0.000060 0.00030 51 22**** 0 52 22**** 2017 621.235180 621.235226 0.000046 0.00030 52 22**** 0 53 22**** 2018 621.580384 621.580433 0.000049 0.00030 53 22**** 0 54 22**** 2019 621.925537 621.925670 0.000133 0.00030 54 22**** 0 55 22**** 2020 622.270636 622.270597 -0.000039 0.00030 55 22**** 0 56 22**** 2021 622.615681 622.615574 -0.000107 0.00030 56 22**** 0 57 22**** 2022 622.960670 622.960742 0.000072 0.00030 57 22**** 0 58 22**** 2023 623.305601 623.305577 -0.000024 0.00030 58 22**** 0 59 22**** 2024 623.650473 623.650725 0.000252 0.00030 59 22**** 0 60 22**** 2025 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620.093699 620.093807 0.000108 0.00030 49 43**** 0 50 43**** 2761 620.439096 620.438936 -0.000160 0.00030 50 43**** 0 51 43**** 2762 620.784448 620.784604 0.000156 0.00030 51 43**** 0 52 43**** 2763 621.129754 621.129709 -0.000045 0.00030 52 43**** 0 53 43**** 2764 621.475012 621.474494 -0.000518 0.00030 53 43**** 0 54 43**** 2765 621.820219 621.820319 0.000100 0.00030 54 43**** 0 55 43**** 2766 622.165375 622.165404 0.000029 0.00030 55 43**** 0 56 43**** 2767 622.510478 622.510592 0.000114 0.00030 56 43**** 0 57 43**** 2768 622.855526 622.855485 -0.000041 0.00030 57 43**** 0 58 43**** 2769 623.200517 623.200619 0.000102 0.00030 58 43**** 0 59 43**** 2770 623.545450 623.545394 -0.000056 0.00030 59 43**** 0 60 43**** 2771 623.890322 623.890043 -0.000279 0.00030 60 43**** 0 61 43**** 2772 624.235133 624.235142 0.000009 0.00030 61 43**** 0 62 43**** 2773 624.579880 624.579834 -0.000046 0.00030 62 43**** 0 63 43**** 2774 624.924562 624.924448 -0.000114 0.00030 63 43**** 0 64 43**** 2775 625.269176 625.269028 -0.000148 0.00030 64 43**** 0 65 43**** 2776 625.613722 625.613838 0.000116 0.00030 65 43**** 0 66 43**** 2777 625.958197 625.958157 -0.000040 0.00030 66 43**** 0 67 43**** 2778 626.646929 626.646958 0.000029 0.00030 68 43**** 0 69 43**** 2779 619.395862 619.396169 0.000307 0.00030 47 44**** 0 48 44**** 2780 619.741349 619.741391 0.000042 0.00030 48 44**** 0 49 44**** 2781 620.086795 620.087034 0.000239 0.00030 49 44**** 0 50 44**** 2782 620.432198 620.432398 0.000200 0.00030 50 44**** 0 51 44**** 2783 620.777556 620.777317 -0.000239 0.00030 51 44**** 0 52 44**** 2784 621.122868 621.122999 0.000131 0.00030 52 44**** 0 53 44**** 2785 621.468133 621.468128 -0.000005 0.00030 53 44**** 0 54 44**** 2786 621.813347 621.813208 -0.000139 0.00030 54 44**** 0 55 44**** 2787 622.158510 622.158509 -0.000001 0.00030 55 44**** 0 56 44**** 2788 622.503621 622.503853 0.000232 0.00030 56 44**** 0 57 44**** 2789 622.848676 622.848486 -0.000190 0.00030 57 44**** 0 58 44**** 2790 623.193674 623.193630 -0.000044 0.00030 58 44**** 0 59 44**** 2791 623.538615 623.538690 0.000075 0.00030 59 44**** 0 60 44**** 2792 623.883495 623.883510 0.000015 0.00030 60 44**** 0 61 44**** 2793 624.228314 624.228276 -0.000038 0.00030 61 44**** 0 62 44**** 2794 624.573069 624.573052 -0.000017 0.00030 62 44**** 0 63 44**** 2795 624.917759 624.917719 -0.000040 0.00030 63 44**** 0 64 44**** 2796 625.262382 625.262206 -0.000176 0.00030 64 44**** 0 65 44**** 2797 625.606936 625.606707 -0.000229 0.00030 65 44**** 0 66 44**** 2798 625.951420 625.951384 -0.000036 0.00030 66 44**** 0 67 44**** 2799 620.425252 620.425292 0.000040 0.00030 50 45**** 0 51 45**** 2800 620.770617 620.770563 -0.000054 0.00030 51 45**** 0 52 45**** 2801 621.115936 621.115824 -0.000112 0.00030 52 45**** 0 53 45**** 2802 621.461206 621.461262 0.000056 0.00030 53 45**** 0 54 45**** 2803 621.806428 621.806386 -0.000042 0.00030 54 45**** 0 55 45**** 2804 622.151598 622.151584 -0.000014 0.00030 55 45**** 0 56 45**** 2805 622.496715 622.496609 -0.000106 0.00030 56 45**** 0 57 45**** 2806 622.841778 622.841714 -0.000064 0.00030 57 45**** 0 58 45**** 2807 623.186784 623.186735 -0.000049 0.00030 58 45**** 0 59 45**** 2808 623.531732 623.531628 -0.000104 0.00030 59 45**** 0 60 45**** 2809 623.876620 623.876561 -0.000059 0.00030 60 45**** 0 61 45**** 2810 624.221446 624.221160 -0.000286 0.00030 61 45**** 0 62 45**** 2811 624.566209 624.566117 -0.000092 0.00030 62 45**** 0 63 45**** 2812 624.910906 624.910848 -0.000058 0.00030 63 45**** 0 64 45**** 2813 625.255537 625.255467 -0.000070 0.00030 64 45**** 0 65 45**** 2814 625.600099 625.599934 -0.000165 0.00030 65 45**** 0 66 45**** 2815 625.944591 625.944484 -0.000107 0.00030 66 45**** 0 67 45**** 2816 626.289011 626.288745 -0.000266 0.00030 67 45**** 0 68 45**** R-BRANCH OF THE NU5 HOT BAND FOR SIGMA = 0 N6' = 1 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 2890 607.489166 607.488958 -0.000208 0.00030 7 6 0 1 8 6 0 2891 607.834576 607.834422 -0.000154 0.00030 8 6 0 1 9 6 0 2892 608.179985 608.179988 0.000003 0.00030 9 6 0 1 10 6 0 2893 608.525392 608.525082 -0.000310 0.00030 10 6 0 1 11 6 0 2894 608.870796 608.870755 -0.000041 0.00030 11 6 0 1 12 6 0 2895 609.216195 609.216247 0.000052 0.00030 12 6 0 1 13 6 0 2896 609.561589 609.561542 -0.000047 0.00030 13 6 0 1 14 6 0 2897 609.906977 609.906946 -0.000031 0.00030 14 6 0 1 15 6 0 2898 610.252357 610.252445 0.000088 0.00030 15 6 0 1 16 6 0 2899 610.597727 610.597780 0.000053 0.00030 16 6 0 1 17 6 0 2900 610.943088 610.943017 -0.000071 0.00030 17 6 0 1 18 6 0 2901 611.288438 611.288530 0.000092 0.00030 18 6 0 1 19 6 0 2902 611.633775 611.633689 -0.000086 0.00030 19 6 0 1 20 6 0 2903 611.979098 611.979273 0.000175 0.00030 20 6 0 1 21 6 0 2904 612.324407 612.324486 0.000079 0.00030 21 6 0 1 22 6 0 2905 612.669699 612.669664 -0.000035 0.00030 22 6 0 1 23 6 0 2906 613.014974 613.015057 0.000083 0.00030 23 6 0 1 24 6 0 2907 613.360230 613.360225 -0.000005 0.00030 24 6 0 1 25 6 0 2908 613.705467 613.705374 -0.000093 0.00030 25 6 0 1 26 6 0 2909 614.050682 614.050625 -0.000057 0.00030 26 6 0 1 27 6 0 2910 614.395875 614.395896 0.000021 0.00030 27 6 0 1 28 6 0 2911 615.431308 615.431297 -0.000011 0.00030 30 6 0 1 31 6 0 2912 615.776398 615.776470 0.000072 0.00030 31 6 0 1 32 6 0 2913 616.121461 616.121437 -0.000024 0.00030 32 6 0 1 33 6 0 2914 616.466493 616.466438 -0.000055 0.00030 33 6 0 1 34 6 0 2915 616.811493 616.811440 -0.000053 0.00030 34 6 0 1 35 6 0 2916 617.156461 617.156593 0.000132 0.00030 35 6 0 1 36 6 0 2917 617.501395 617.501418 0.000023 0.00030 36 6 0 1 37 6 0 2918 617.846294 617.846203 -0.000091 0.00030 37 6 0 1 38 6 0 2919 618.191156 618.191258 0.000102 0.00030 38 6 0 1 39 6 0 2920 618.535980 618.536171 0.000191 0.00030 39 6 0 1 40 6 0 2921 618.880765 618.880883 0.000118 0.00030 40 6 0 1 41 6 0 2922 619.225509 619.225620 0.000111 0.00030 41 6 0 1 42 6 0 2923 619.570212 619.570126 -0.000086 0.00030 42 6 0 1 43 6 0 2924 619.914871 619.914911 0.000040 0.00030 43 6 0 1 44 6 0 2925 620.259485 620.259613 0.000128 0.00030 44 6 0 1 45 6 0 2926 620.604054 620.604271 0.000217 0.00030 45 6 0 1 46 6 0 2927 620.948575 620.948606 0.000031 0.00030 46 6 0 1 47 6 0 2928 621.293048 621.293170 0.000122 0.00030 47 6 0 1 48 6 0 2929 621.637470 621.637686 0.000216 0.00030 48 6 0 1 49 6 0 2930 621.981842 621.981986 0.000144 0.00030 49 6 0 1 50 6 0 2931 622.326161 622.326178 0.000017 0.00030 50 6 0 1 51 6 0 2932 622.670426 622.670625 0.000199 0.00030 51 6 0 1 52 6 0 2933 623.014635 623.014783 0.000148 0.00030 52 6 0 1 53 6 0 2934 623.358788 623.358892 0.000104 0.00030 53 6 0 1 54 6 0 2935 623.702884 623.702858 -0.000026 0.00030 54 6 0 1 55 6 0 2936 624.046920 624.046751 -0.000169 0.00030 55 6 0 1 56 6 0 2937 624.390895 624.391149 0.000254 0.00030 56 6 0 1 57 6 0 2938 624.734809 624.734890 0.000081 0.00030 57 6 0 1 58 6 0 2939 625.078659 625.078611 -0.000048 0.00030 58 6 0 1 59 6 0 2940 625.766166 625.766289 0.000123 0.00030 60 6 0 1 61 6 0 2941 626.109820 626.109770 -0.000050 0.00030 61 6 0 1 62 6 0 2942 626.453405 626.453487 0.000082 0.00030 62 6 0 1 63 6 0 2943 627.140367 627.140218 -0.000149 0.00030 64 6 0 1 65 6 0 2944 609.214703 609.214776 0.000073 0.00030 12 7 0 1 13 7 0 2945 609.560096 609.559949 -0.000147 0.00030 13 7 0 1 14 7 0 2946 609.905482 609.905239 -0.000243 0.00030 14 7 0 1 15 7 0 2947 610.250861 610.250988 0.000127 0.00030 15 7 0 1 16 7 0 2948 610.596230 610.596098 -0.000132 0.00030 16 7 0 1 17 7 0 2949 610.941590 610.941513 -0.000077 0.00030 17 7 0 1 18 7 0 2950 611.632275 611.632198 -0.000077 0.00030 19 7 0 1 20 7 0 2951 612.322905 612.322887 -0.000018 0.00030 21 7 0 1 22 7 0 2952 612.668196 612.668398 0.000202 0.00030 22 7 0 1 23 7 0 2953 613.013470 613.013365 -0.000105 0.00030 23 7 0 1 24 7 0 2954 613.358726 613.358754 0.000028 0.00030 24 7 0 1 25 7 0 2955 613.703962 613.704000 0.000038 0.00030 25 7 0 1 26 7 0 2956 616.464982 616.465080 0.000098 0.00030 33 7 0 1 34 7 0 2957 616.809982 616.809704 -0.000278 0.00030 34 7 0 1 35 7 0 2958 617.154950 617.154945 -0.000005 0.00030 35 7 0 1 36 7 0 2959 617.499883 617.500054 0.000171 0.00030 36 7 0 1 37 7 0 2960 617.844781 617.844663 -0.000118 0.00030 37 7 0 1 38 7 0 2961 618.879251 618.879378 0.000127 0.00030 40 7 0 1 41 7 0 2962 619.223995 619.224134 0.000139 0.00030 41 7 0 1 42 7 0 2963 620.947059 620.947262 0.000203 0.00030 46 7 0 1 47 7 0 2964 621.635953 621.635882 -0.000071 0.00030 48 7 0 1 49 7 0 2965 621.980324 621.980437 0.000113 0.00030 49 7 0 1 50 7 0 2966 623.013117 623.013125 0.000008 0.00030 52 7 0 1 53 7 0 2967 623.357269 623.357264 -0.000005 0.00030 53 7 0 1 54 7 0 2968 608.522184 608.522211 0.000027 0.00030 10 8 0 1 11 8 0 2969 608.867585 608.867727 0.000142 0.00030 11 8 0 1 12 8 0 2970 609.212982 609.212993 0.000011 0.00030 12 8 0 1 13 8 0 2971 609.558374 609.558325 -0.000049 0.00030 13 8 0 1 14 8 0 2972 609.903759 609.903692 -0.000067 0.00030 14 8 0 1 15 8 0 2973 610.249136 610.249407 0.000271 0.00030 15 8 0 1 16 8 0 2974 610.594505 610.594477 -0.000028 0.00030 16 8 0 1 17 8 0 2975 610.939863 610.939831 -0.000032 0.00030 17 8 0 1 18 8 0 2976 611.285211 611.285303 0.000092 0.00030 18 8 0 1 19 8 0 2977 611.630546 611.630427 -0.000119 0.00030 19 8 0 1 20 8 0 2978 611.975867 611.975992 0.000125 0.00030 20 8 0 1 21 8 0 2979 612.321173 612.321013 -0.000160 0.00030 21 8 0 1 22 8 0 2980 612.666464 612.666515 0.000051 0.00030 22 8 0 1 23 8 0 2981 613.011737 613.011761 0.000024 0.00030 23 8 0 1 24 8 0 2982 613.356992 613.356944 -0.000048 0.00030 24 8 0 1 25 8 0 2983 613.702226 613.702078 -0.000148 0.00030 25 8 0 1 26 8 0 2984 614.047440 614.047442 0.000002 0.00030 26 8 0 1 27 8 0 2985 614.392632 614.392698 0.000066 0.00030 27 8 0 1 28 8 0 2986 614.737800 614.737719 -0.000081 0.00030 28 8 0 1 29 8 0 2987 615.082943 615.083132 0.000189 0.00030 29 8 0 1 30 8 0 2988 616.118210 616.118318 0.000108 0.00030 32 8 0 1 33 8 0 2989 617.153207 617.153028 -0.000179 0.00030 35 8 0 1 36 8 0 2990 617.843038 617.843241 0.000203 0.00030 37 8 0 1 38 8 0 2991 619.222249 619.222123 -0.000126 0.00030 41 8 0 1 42 8 0 2992 619.911609 619.911674 0.000065 0.00030 43 8 0 1 44 8 0 2993 620.256223 620.255989 -0.000234 0.00030 44 8 0 1 45 8 0 2994 621.634204 621.634243 0.000039 0.00030 48 8 0 1 49 8 0 2995 621.978575 621.978416 -0.000159 0.00030 49 8 0 1 50 8 0 2996 623.011366 623.011438 0.000072 0.00030 52 8 0 1 53 8 0 2997 623.355519 623.355709 0.000190 0.00030 53 8 0 1 54 8 0 2998 624.043648 624.043578 -0.000070 0.00030 55 8 0 1 56 8 0 2999 624.387623 624.387633 0.000010 0.00030 56 8 0 1 57 8 0 3000 608.520240 608.520119 -0.000121 0.00030 10 9 0 1 11 9 0 3001 608.865639 608.865559 -0.000080 0.00030 11 9 0 1 12 9 0 3002 609.211034 609.211002 -0.000032 0.00030 12 9 0 1 13 9 0 3003 609.556425 609.556256 -0.000169 0.00030 13 9 0 1 14 9 0 3004 609.901808 609.901811 0.000003 0.00030 14 9 0 1 15 9 0 3005 610.247184 610.247357 0.000173 0.00030 15 9 0 1 16 9 0 3006 610.592551 610.592601 0.000050 0.00030 16 9 0 1 17 9 0 3007 610.937908 610.937717 -0.000191 0.00030 17 9 0 1 18 9 0 3008 611.283254 611.283317 0.000063 0.00030 18 9 0 1 19 9 0 3009 611.628588 611.628534 -0.000054 0.00030 19 9 0 1 20 9 0 3010 611.973908 611.973903 -0.000005 0.00030 20 9 0 1 21 9 0 3011 612.319214 612.319233 0.000019 0.00030 21 9 0 1 22 9 0 3012 612.664503 612.664558 0.000055 0.00030 22 9 0 1 23 9 0 3013 613.009775 613.009726 -0.000049 0.00030 23 9 0 1 24 9 0 3014 613.355029 613.355076 0.000047 0.00030 24 9 0 1 25 9 0 3015 613.700262 613.700062 -0.000200 0.00030 25 9 0 1 26 9 0 3016 614.045475 614.045515 0.000040 0.00030 26 9 0 1 27 9 0 3017 614.390666 614.390580 -0.000086 0.00030 27 9 0 1 28 9 0 3018 614.735833 614.735816 -0.000017 0.00030 28 9 0 1 29 9 0 3019 615.080975 615.080886 -0.000089 0.00030 29 9 0 1 30 9 0 3020 615.426091 615.426123 0.000032 0.00030 30 9 0 1 31 9 0 3021 615.771180 615.771271 0.000091 0.00030 31 9 0 1 32 9 0 3022 616.461270 616.461259 -0.000011 0.00030 33 9 0 1 34 9 0 3023 616.806269 616.806344 0.000075 0.00030 34 9 0 1 35 9 0 3024 617.151235 617.151183 -0.000052 0.00030 35 9 0 1 36 9 0 3025 617.496167 617.496244 0.000077 0.00030 36 9 0 1 37 9 0 3026 617.841064 617.840955 -0.000109 0.00030 37 9 0 1 38 9 0 3027 618.185925 618.185918 -0.000007 0.00030 38 9 0 1 39 9 0 3028 618.530747 618.530615 -0.000132 0.00030 39 9 0 1 40 9 0 3029 618.875531 618.875459 -0.000072 0.00030 40 9 0 1 41 9 0 3030 619.220273 619.220196 -0.000077 0.00030 41 9 0 1 42 9 0 3031 619.564974 619.564844 -0.000130 0.00030 42 9 0 1 43 9 0 3032 619.909632 619.909600 -0.000032 0.00030 43 9 0 1 44 9 0 3033 620.254245 620.254228 -0.000017 0.00030 44 9 0 1 45 9 0 3034 620.598812 620.598671 -0.000141 0.00030 45 9 0 1 46 9 0 3035 620.943332 620.943191 -0.000141 0.00030 46 9 0 1 47 9 0 3036 621.287804 621.287756 -0.000048 0.00030 47 9 0 1 48 9 0 3037 621.632225 621.632321 0.000096 0.00030 48 9 0 1 49 9 0 3038 621.976595 621.976714 0.000119 0.00030 49 9 0 1 50 9 0 3039 622.665177 622.665241 0.000064 0.00030 51 9 0 1 52 9 0 3040 623.009385 623.009428 0.000043 0.00030 52 9 0 1 53 9 0 3041 623.353537 623.353571 0.000034 0.00030 53 9 0 1 54 9 0 3042 623.697631 623.697679 0.000048 0.00030 54 9 0 1 55 9 0 3043 624.041666 624.041862 0.000196 0.00030 55 9 0 1 56 9 0 3044 624.385640 624.385779 0.000139 0.00030 56 9 0 1 57 9 0 3045 624.729553 624.729638 0.000085 0.00030 57 9 0 1 58 9 0 3046 626.104558 626.104557 -0.000001 0.00030 61 9 0 1 62 9 0 3047 627.135100 627.134789 -0.000311 0.00030 64 9 0 1 65 9 0 3048 608.518069 608.518069 0.000000 0.00030 10 10 0 1 11 10 0 3049 608.863467 608.863624 0.000157 0.00030 11 10 0 1 12 10 0 3050 609.208861 609.208890 0.000029 0.00030 12 10 0 1 13 10 0 3051 609.554249 609.554301 0.000052 0.00030 13 10 0 1 14 10 0 3052 609.899631 609.899582 -0.000049 0.00030 14 10 0 1 15 10 0 3053 610.245005 610.245363 0.000358 0.00030 15 10 0 1 16 10 0 3054 610.590371 610.590558 0.000187 0.00030 16 10 0 1 17 10 0 3055 610.935727 610.935640 -0.000087 0.00030 17 10 0 1 18 10 0 3056 611.626403 611.626577 0.000174 0.00030 19 10 0 1 20 10 0 3057 611.971722 611.971554 -0.000168 0.00030 20 10 0 1 21 10 0 3058 612.317026 612.317227 0.000201 0.00030 21 10 0 1 22 10 0 3059 612.662314 612.662204 -0.000110 0.00030 22 10 0 1 23 10 0 3060 613.007585 613.007799 0.000214 0.00030 23 10 0 1 24 10 0 3061 613.352837 613.352692 -0.000145 0.00030 24 10 0 1 25 10 0 3062 614.733638 614.733556 -0.000082 0.00030 28 10 0 1 29 10 0 3063 615.078779 615.078684 -0.000095 0.00030 29 10 0 1 30 10 0 3064 615.423894 615.423955 0.000061 0.00030 30 10 0 1 31 10 0 3065 615.768982 615.768760 -0.000222 0.00030 31 10 0 1 32 10 0 3066 616.114041 616.113968 -0.000073 0.00030 32 10 0 1 33 10 0 3067 617.149034 617.149011 -0.000023 0.00030 35 10 0 1 36 10 0 3068 617.838862 617.838856 -0.000006 0.00030 37 10 0 1 38 10 0 3069 618.183722 618.183789 0.000067 0.00030 38 10 0 1 39 10 0 3070 618.528543 618.528511 -0.000032 0.00030 39 10 0 1 40 10 0 3071 618.873326 618.872983 -0.000343 0.00030 40 10 0 1 41 10 0 3072 619.907426 619.907256 -0.000170 0.00030 43 10 0 1 44 10 0 3073 620.941125 620.941151 0.000026 0.00030 46 10 0 1 47 10 0 3074 621.630017 621.629987 -0.000030 0.00030 48 10 0 1 49 10 0 3075 623.007175 623.006985 -0.000190 0.00030 52 10 0 1 53 10 0 3076 623.351326 623.351521 0.000195 0.00030 53 10 0 1 54 10 0 3077 624.727340 624.727617 0.000277 0.00030 57 10 0 1 58 10 0 3078 609.897228 609.897181 -0.000047 0.00030 14 11 0 1 15 11 0 3079 610.242601 610.242332 -0.000269 0.00030 15 11 0 1 16 11 0 3080 610.587965 610.588197 0.000232 0.00030 16 11 0 1 17 11 0 3081 610.933319 610.933360 0.000041 0.00030 17 11 0 1 18 11 0 3082 611.278662 611.278516 -0.000146 0.00030 18 11 0 1 19 11 0 3083 611.623993 611.624052 0.000059 0.00030 19 11 0 1 20 11 0 3084 611.969310 611.969303 -0.000007 0.00030 20 11 0 1 21 11 0 3085 612.314612 612.314451 -0.000161 0.00030 21 11 0 1 22 11 0 3086 612.659899 612.660056 0.000157 0.00030 22 11 0 1 23 11 0 3087 613.005169 613.004998 -0.000171 0.00030 23 11 0 1 24 11 0 3088 613.350420 613.350475 0.000055 0.00030 24 11 0 1 25 11 0 3089 613.695651 613.696001 0.000350 0.00030 25 11 0 1 26 11 0 3090 614.040862 614.040586 -0.000276 0.00030 26 11 0 1 27 11 0 3091 614.386050 614.386033 -0.000017 0.00030 27 11 0 1 28 11 0 3092 614.731215 614.731138 -0.000077 0.00030 28 11 0 1 29 11 0 3093 615.076355 615.076394 0.000039 0.00030 29 11 0 1 30 11 0 3094 615.421470 615.421204 -0.000266 0.00030 30 11 0 1 31 11 0 3095 615.766557 615.766451 -0.000106 0.00030 31 11 0 1 32 11 0 3096 616.111615 616.111584 -0.000031 0.00030 32 11 0 1 33 11 0 3097 616.456643 616.456934 0.000291 0.00030 33 11 0 1 34 11 0 3098 617.836432 617.836203 -0.000229 0.00030 37 11 0 1 38 11 0 3099 618.526112 618.526220 0.000108 0.00030 39 11 0 1 40 11 0 3100 618.870894 618.870795 -0.000099 0.00030 40 11 0 1 41 11 0 3101 619.215636 619.215728 0.000092 0.00030 41 11 0 1 42 11 0 3102 620.249604 620.249471 -0.000133 0.00030 44 11 0 1 45 11 0 3103 620.938689 620.938478 -0.000211 0.00030 46 11 0 1 47 11 0 3104 623.348887 623.348916 0.000029 0.00030 53 11 0 1 54 11 0 3105 623.692980 623.692947 -0.000033 0.00030 54 11 0 1 55 11 0 3106 609.203839 609.204006 0.000167 0.00030 12 12 0 1 13 12 0 3107 609.549224 609.549517 0.000293 0.00030 13 12 0 1 14 12 0 3108 609.894602 609.894607 0.000005 0.00030 14 12 0 1 15 12 0 3109 610.239972 610.240017 0.000045 0.00030 15 12 0 1 16 12 0 3110 610.585335 610.585359 0.000024 0.00030 16 12 0 1 17 12 0 3111 610.930687 610.930795 0.000108 0.00030 17 12 0 1 18 12 0 3112 611.276028 611.276049 0.000021 0.00030 18 12 0 1 19 12 0 3113 611.621357 611.621349 -0.000008 0.00030 19 12 0 1 20 12 0 3114 611.966673 611.966875 0.000202 0.00030 20 12 0 1 21 12 0 3115 612.311974 612.311970 -0.000004 0.00030 21 12 0 1 22 12 0 3116 612.657259 612.657353 0.000094 0.00030 22 12 0 1 23 12 0 3117 613.002527 613.002571 0.000044 0.00030 23 12 0 1 24 12 0 3118 613.347777 613.347945 0.000168 0.00030 24 12 0 1 25 12 0 3119 613.693007 613.693020 0.000013 0.00030 25 12 0 1 26 12 0 3120 614.038216 614.038398 0.000182 0.00030 26 12 0 1 27 12 0 3121 614.383404 614.383223 -0.000181 0.00030 27 12 0 1 28 12 0 3122 614.728567 614.728396 -0.000171 0.00030 28 12 0 1 29 12 0 3123 615.073706 615.073731 0.000025 0.00030 29 12 0 1 30 12 0 3124 615.418820 615.418703 -0.000117 0.00030 30 12 0 1 31 12 0 3125 615.763906 615.763989 0.000083 0.00030 31 12 0 1 32 12 0 3126 616.108963 616.109029 0.000066 0.00030 32 12 0 1 33 12 0 3127 616.453990 616.453962 -0.000028 0.00030 33 12 0 1 34 12 0 3128 616.798987 616.798875 -0.000112 0.00030 34 12 0 1 35 12 0 3129 617.143950 617.143964 0.000014 0.00030 35 12 0 1 36 12 0 3130 617.833775 617.833668 -0.000107 0.00030 37 12 0 1 38 12 0 3131 618.178634 618.178448 -0.000186 0.00030 38 12 0 1 39 12 0 3132 618.523454 618.523386 -0.000068 0.00030 39 12 0 1 40 12 0 3133 618.868236 618.868162 -0.000074 0.00030 40 12 0 1 41 12 0 3134 619.212977 619.212839 -0.000138 0.00030 41 12 0 1 42 12 0 3135 619.902332 619.902258 -0.000074 0.00030 43 12 0 1 44 12 0 3136 620.246943 620.246754 -0.000189 0.00030 44 12 0 1 45 12 0 3137 620.591509 620.591388 -0.000121 0.00030 45 12 0 1 46 12 0 3138 620.936027 620.936021 -0.000006 0.00030 46 12 0 1 47 12 0 3139 621.280497 621.280488 -0.000009 0.00030 47 12 0 1 48 12 0 3140 621.624917 621.624935 0.000018 0.00030 48 12 0 1 49 12 0 3141 621.969286 621.969225 -0.000061 0.00030 49 12 0 1 50 12 0 3142 622.313602 622.313559 -0.000043 0.00030 50 12 0 1 51 12 0 3143 622.657864 622.657796 -0.000068 0.00030 51 12 0 1 52 12 0 3144 623.346222 623.346057 -0.000165 0.00030 53 12 0 1 54 12 0 3145 623.690314 623.690102 -0.000212 0.00030 54 12 0 1 55 12 0 3146 624.034348 624.034201 -0.000147 0.00030 55 12 0 1 56 12 0 3147 610.582482 610.582454 -0.000028 0.00030 16 13 0 1 17 13 0 3148 610.927832 610.927791 -0.000041 0.00030 17 13 0 1 18 13 0 3149 611.273172 611.273366 0.000194 0.00030 18 13 0 1 19 13 0 3150 611.618499 611.618372 -0.000127 0.00030 19 13 0 1 20 13 0 3151 611.963813 611.963545 -0.000268 0.00030 20 13 0 1 21 13 0 3152 612.309112 612.309243 0.000131 0.00030 21 13 0 1 22 13 0 3153 612.654396 612.654254 -0.000142 0.00030 22 13 0 1 23 13 0 3154 612.999662 612.999653 -0.000009 0.00030 23 13 0 1 24 13 0 3155 613.344911 613.344958 0.000047 0.00030 24 13 0 1 25 13 0 3156 613.690139 613.690322 0.000183 0.00030 25 13 0 1 26 13 0 3157 614.035347 614.035191 -0.000156 0.00030 26 13 0 1 27 13 0 3158 614.380533 614.380599 0.000066 0.00030 27 13 0 1 28 13 0 3159 614.725696 614.725395 -0.000301 0.00030 28 13 0 1 29 13 0 3160 615.070834 615.070656 -0.000178 0.00030 29 13 0 1 30 13 0 3161 615.415946 615.415888 -0.000058 0.00030 30 13 0 1 31 13 0 3162 615.761031 615.761252 0.000221 0.00030 31 13 0 1 32 13 0 3163 616.106087 616.105974 -0.000113 0.00030 32 13 0 1 33 13 0 3164 616.451114 616.450975 -0.000139 0.00030 33 13 0 1 34 13 0 3165 616.796109 616.795971 -0.000138 0.00030 34 13 0 1 35 13 0 3166 617.141072 617.140992 -0.000080 0.00030 35 13 0 1 36 13 0 3167 617.486001 617.486263 0.000262 0.00030 36 13 0 1 37 13 0 3168 618.865353 618.865185 -0.000168 0.00030 40 13 0 1 41 13 0 3169 619.554792 619.554864 0.000072 0.00030 42 13 0 1 43 13 0 3170 619.899447 619.899159 -0.000288 0.00030 43 13 0 1 44 13 0 3171 620.933141 620.933363 0.000222 0.00030 46 13 0 1 47 13 0 3172 621.277610 621.277359 -0.000251 0.00030 47 13 0 1 48 13 0 3173 621.966398 621.966449 0.000051 0.00030 49 13 0 1 50 13 0 P-BRANCH OF THE NU5 HOT BAND FOR SIGMA = 0 N6' = 1 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3174 600.582392 600.582276 -0.000116 0.00030 12 6 0 1 11 6 0 3175 600.237201 600.236983 -0.000218 0.00030 13 6 0 1 12 6 0 3176 599.892031 599.891864 -0.000167 0.00030 14 6 0 1 13 6 0 3177 599.546882 599.546765 -0.000117 0.00030 15 6 0 1 14 6 0 3178 599.201756 599.201761 0.000005 0.00030 16 6 0 1 15 6 0 3179 597.476494 597.476426 -0.000068 0.00030 21 6 0 1 20 6 0 3180 597.131521 597.131476 -0.000045 0.00030 22 6 0 1 21 6 0 3181 596.786577 596.786563 -0.000014 0.00030 23 6 0 1 22 6 0 3182 596.441661 596.441653 -0.000008 0.00030 24 6 0 1 23 6 0 3183 596.096776 596.096774 -0.000002 0.00030 25 6 0 1 24 6 0 3184 595.751921 595.751947 0.000026 0.00030 26 6 0 1 25 6 0 3185 595.407098 595.407186 0.000088 0.00030 27 6 0 1 26 6 0 3186 595.062306 595.062410 0.000104 0.00030 28 6 0 1 27 6 0 3187 594.717548 594.717487 -0.000061 0.00030 29 6 0 1 28 6 0 3188 594.372823 594.372672 -0.000151 0.00030 30 6 0 1 29 6 0 3189 594.028133 594.028164 0.000031 0.00030 31 6 0 1 30 6 0 3190 592.994277 592.994318 0.000041 0.00030 34 6 0 1 33 6 0 3191 592.649731 592.649843 0.000112 0.00030 35 6 0 1 34 6 0 3192 592.305224 592.305239 0.000015 0.00030 36 6 0 1 35 6 0 3193 591.960755 591.960751 -0.000004 0.00030 37 6 0 1 36 6 0 3194 591.616326 591.616397 0.000071 0.00030 38 6 0 1 37 6 0 3195 591.271937 591.272168 0.000231 0.00030 39 6 0 1 38 6 0 3196 590.927589 590.927640 0.000051 0.00030 40 6 0 1 39 6 0 3197 590.583282 590.583565 0.000283 0.00030 41 6 0 1 40 6 0 3198 590.239017 590.239126 0.000109 0.00030 42 6 0 1 41 6 0 3199 589.894795 589.894870 0.000075 0.00030 43 6 0 1 42 6 0 3200 589.550616 589.550683 0.000067 0.00030 44 6 0 1 43 6 0 3201 589.206482 589.206686 0.000204 0.00030 45 6 0 1 44 6 0 3202 588.862393 588.862410 0.000017 0.00030 46 6 0 1 45 6 0 3203 588.518349 588.518514 0.000165 0.00030 47 6 0 1 46 6 0 3204 588.174351 588.174438 0.000087 0.00030 48 6 0 1 47 6 0 3205 587.830400 587.830492 0.000092 0.00030 49 6 0 1 48 6 0 3206 587.486496 587.486587 0.000091 0.00030 50 6 0 1 49 6 0 3207 587.142641 587.142705 0.000064 0.00030 51 6 0 1 50 6 0 3208 599.545438 599.545387 -0.000051 0.00030 15 7 0 1 14 7 0 3209 599.200314 599.200243 -0.000071 0.00030 16 7 0 1 15 7 0 3210 598.855214 598.855058 -0.000156 0.00030 17 7 0 1 16 7 0 3211 597.130094 597.130194 0.000100 0.00030 22 7 0 1 21 7 0 3212 596.785152 596.785151 -0.000001 0.00030 23 7 0 1 22 7 0 3213 596.440239 596.440331 0.000092 0.00030 24 7 0 1 23 7 0 3214 596.095356 596.095408 0.000052 0.00030 25 7 0 1 24 7 0 3215 600.579269 600.579103 -0.000166 0.00030 12 8 0 1 11 8 0 3216 600.234082 600.234082 0.000000 0.00030 13 8 0 1 12 8 0 3217 599.888917 599.888961 0.000044 0.00030 14 8 0 1 13 8 0 3218 599.543773 599.543741 -0.000032 0.00030 15 8 0 1 14 8 0 3219 599.198652 599.198561 -0.000091 0.00030 16 8 0 1 15 8 0 3220 598.853554 598.853516 -0.000038 0.00030 17 8 0 1 16 8 0 3221 598.508481 598.508598 0.000117 0.00030 18 8 0 1 17 8 0 3222 596.783509 596.783486 -0.000023 0.00030 23 8 0 1 22 8 0 3223 596.438598 596.438605 0.000007 0.00030 24 8 0 1 23 8 0 3224 596.093718 596.093613 -0.000105 0.00030 25 8 0 1 24 8 0 3225 595.748869 595.748828 -0.000041 0.00030 26 8 0 1 25 8 0 3226 595.404051 595.404001 -0.000050 0.00030 27 8 0 1 26 8 0 3227 595.059266 595.059267 0.000001 0.00030 28 8 0 1 27 8 0 3228 594.714513 594.714471 -0.000042 0.00030 29 8 0 1 28 8 0 3229 594.025110 594.025153 0.000043 0.00030 31 8 0 1 30 8 0 3230 593.680461 593.680497 0.000036 0.00030 32 8 0 1 31 8 0 3231 593.335847 593.335851 0.000004 0.00030 33 8 0 1 32 8 0 3232 592.991271 592.991282 0.000011 0.00030 34 8 0 1 33 8 0 3233 591.613345 591.613309 -0.000036 0.00030 38 8 0 1 37 8 0 3234 591.268962 591.268921 -0.000041 0.00030 39 8 0 1 38 8 0 3235 590.236060 590.235953 -0.000107 0.00030 42 8 0 1 41 8 0 3236 589.547672 589.547632 -0.000040 0.00030 44 8 0 1 43 8 0 3237 589.203544 589.203471 -0.000073 0.00030 45 8 0 1 44 8 0 3238 600.577376 600.577264 -0.000112 0.00030 12 9 0 1 11 9 0 3239 600.232192 600.232258 0.000066 0.00030 13 9 0 1 12 9 0 3240 599.887029 599.886999 -0.000030 0.00030 14 9 0 1 13 9 0 3241 599.541888 599.541910 0.000022 0.00030 15 9 0 1 14 9 0 3242 599.196770 599.196749 -0.000021 0.00030 16 9 0 1 15 9 0 3243 598.851675 598.851650 -0.000025 0.00030 17 9 0 1 16 9 0 3244 598.506605 598.506575 -0.000030 0.00030 18 9 0 1 17 9 0 3245 598.161560 598.161627 0.000067 0.00030 19 9 0 1 18 9 0 3246 597.816541 597.816604 0.000063 0.00030 20 9 0 1 19 9 0 3247 596.091865 596.091877 0.000012 0.00030 25 9 0 1 24 9 0 3248 595.747019 595.747060 0.000041 0.00030 26 9 0 1 25 9 0 3249 595.402205 595.402203 -0.000002 0.00030 27 9 0 1 26 9 0 3250 595.057423 595.057405 -0.000018 0.00030 28 9 0 1 27 9 0 3251 594.712674 594.712625 -0.000049 0.00030 29 9 0 1 28 9 0 3252 594.367958 594.367915 -0.000043 0.00030 30 9 0 1 29 9 0 3253 594.023277 594.023260 -0.000017 0.00030 31 9 0 1 30 9 0 3254 593.678632 593.678621 -0.000011 0.00030 32 9 0 1 31 9 0 3255 593.334022 593.333946 -0.000076 0.00030 33 9 0 1 32 9 0 3256 592.989449 592.989403 -0.000046 0.00030 34 9 0 1 33 9 0 3257 592.644914 592.644853 -0.000061 0.00030 35 9 0 1 34 9 0 3258 592.300416 592.300571 0.000155 0.00030 36 9 0 1 35 9 0 3259 591.955957 591.955834 -0.000123 0.00030 37 9 0 1 36 9 0 3260 591.611538 591.611583 0.000045 0.00030 38 9 0 1 37 9 0 3261 590.234269 590.234380 0.000111 0.00030 42 9 0 1 41 9 0 3262 589.890057 589.890006 -0.000051 0.00030 43 9 0 1 42 9 0 3263 589.545888 589.545921 0.000033 0.00030 44 9 0 1 43 9 0 3264 589.201764 589.201775 0.000011 0.00030 45 9 0 1 44 9 0 3265 588.857685 588.857648 -0.000037 0.00030 46 9 0 1 45 9 0 3266 588.513651 588.513646 -0.000005 0.00030 47 9 0 1 46 9 0 3267 588.169664 588.169682 0.000018 0.00030 48 9 0 1 47 9 0 3268 587.825723 587.825728 0.000005 0.00030 49 9 0 1 48 9 0 3269 598.504512 598.504417 -0.000095 0.00030 18 10 0 1 17 10 0 3270 598.159470 598.159469 -0.000001 0.00030 19 10 0 1 18 10 0 3271 597.814455 597.814505 0.000050 0.00030 20 10 0 1 19 10 0 3272 595.744955 595.744892 -0.000063 0.00030 26 10 0 1 25 10 0 3273 595.400144 595.400099 -0.000045 0.00030 27 10 0 1 26 10 0 3274 595.055366 595.055262 -0.000104 0.00030 28 10 0 1 27 10 0 3275 594.710621 594.710592 -0.000029 0.00030 29 10 0 1 28 10 0 3276 594.365909 594.365873 -0.000036 0.00030 30 10 0 1 29 10 0 3277 594.021233 594.021305 0.000072 0.00030 31 10 0 1 30 10 0 3278 593.676591 593.676738 0.000147 0.00030 32 10 0 1 31 10 0 3279 593.331985 593.332114 0.000129 0.00030 33 10 0 1 32 10 0 3280 592.987416 592.987491 0.000075 0.00030 34 10 0 1 33 10 0 3281 592.642885 592.642987 0.000102 0.00030 35 10 0 1 34 10 0 3282 592.298392 592.298386 -0.000006 0.00030 36 10 0 1 35 10 0 3283 591.953937 591.953995 0.000058 0.00030 37 10 0 1 36 10 0 3284 591.265147 591.265081 -0.000066 0.00030 39 10 0 1 38 10 0 3285 590.920813 590.920600 -0.000213 0.00030 40 10 0 1 39 10 0 3286 599.192352 599.192259 -0.000093 0.00030 16 11 0 1 15 11 0 3287 598.847265 598.847299 0.000034 0.00030 17 11 0 1 16 11 0 3288 598.502202 598.502261 0.000059 0.00030 18 11 0 1 17 11 0 3289 598.157164 598.157233 0.000069 0.00030 19 11 0 1 18 11 0 3290 597.812153 597.812023 -0.000130 0.00030 20 11 0 1 19 11 0 3291 597.467168 597.467240 0.000072 0.00030 21 11 0 1 20 11 0 3292 597.122211 597.122455 0.000244 0.00030 22 11 0 1 21 11 0 3293 595.053097 595.053045 -0.000052 0.00030 28 11 0 1 27 11 0 3294 594.708356 594.708785 0.000429 0.00030 29 11 0 1 28 11 0 3295 594.363649 594.363734 0.000085 0.00030 30 11 0 1 29 11 0 3296 594.018976 594.018897 -0.000079 0.00030 31 11 0 1 30 11 0 3297 593.674339 593.674325 -0.000014 0.00030 32 11 0 1 31 11 0 3298 593.329738 593.329738 0.000000 0.00030 33 11 0 1 32 11 0 3299 592.985174 592.985085 -0.000089 0.00030 34 11 0 1 33 11 0 3300 592.640647 592.640616 -0.000031 0.00030 35 11 0 1 34 11 0 3301 592.296158 592.296201 0.000043 0.00030 36 11 0 1 35 11 0 3302 591.951708 591.951754 0.000046 0.00030 37 11 0 1 36 11 0 3303 591.607298 591.607201 -0.000097 0.00030 38 11 0 1 37 11 0 3304 591.262927 591.263134 0.000207 0.00030 39 11 0 1 38 11 0 3305 590.918598 590.918385 -0.000213 0.00030 40 11 0 1 39 11 0 3306 589.885861 589.886116 0.000255 0.00030 43 11 0 1 42 11 0 3307 599.534927 599.535014 0.000087 0.00030 15 12 0 1 14 12 0 3308 599.189819 599.190084 0.000265 0.00030 16 12 0 1 15 12 0 3309 598.844736 598.844874 0.000138 0.00030 17 12 0 1 16 12 0 3310 598.499677 598.499736 0.000059 0.00030 18 12 0 1 17 12 0 3311 598.154644 598.154575 -0.000069 0.00030 19 12 0 1 18 12 0 3312 597.809636 597.809635 -0.000001 0.00030 20 12 0 1 19 12 0 3313 597.464656 597.464693 0.000037 0.00030 21 12 0 1 20 12 0 3314 597.119703 597.119779 0.000076 0.00030 22 12 0 1 21 12 0 3315 596.774780 596.774852 0.000072 0.00030 23 12 0 1 22 12 0 3316 596.429885 596.430064 0.000179 0.00030 24 12 0 1 23 12 0 3317 596.085021 596.085114 0.000093 0.00030 25 12 0 1 24 12 0 3318 594.705880 594.705886 0.000006 0.00030 29 12 0 1 28 12 0 3319 594.361178 594.361177 -0.000001 0.00030 30 12 0 1 29 12 0 3320 594.016511 594.016575 0.000064 0.00030 31 12 0 1 30 12 0 3321 593.671878 593.671868 -0.000010 0.00030 32 12 0 1 31 12 0 3322 593.327282 593.327308 0.000026 0.00030 33 12 0 1 32 12 0 3323 592.982723 592.982817 0.000094 0.00030 34 12 0 1 33 12 0 3324 592.638201 592.638191 -0.000010 0.00030 35 12 0 1 34 12 0 3325 592.293717 592.293719 0.000002 0.00030 36 12 0 1 35 12 0 3326 591.949272 591.949243 -0.000029 0.00030 37 12 0 1 36 12 0 3327 591.604867 591.604891 0.000024 0.00030 38 12 0 1 37 12 0 3328 591.260502 591.260503 0.000001 0.00030 39 12 0 1 38 12 0 3329 590.916178 590.916127 -0.000051 0.00030 40 12 0 1 39 12 0 3330 590.571895 590.571918 0.000023 0.00030 41 12 0 1 40 12 0 3331 590.227654 590.227544 -0.000110 0.00030 42 12 0 1 41 12 0 3332 589.883457 589.883395 -0.000062 0.00030 43 12 0 1 42 12 0 3333 589.539303 589.539300 -0.000003 0.00030 44 12 0 1 43 12 0 3334 589.195193 589.195136 -0.000057 0.00030 45 12 0 1 44 12 0 3335 588.851128 588.851178 0.000050 0.00030 46 12 0 1 45 12 0 3336 588.507109 588.507189 0.000080 0.00030 47 12 0 1 46 12 0 3337 588.163136 588.163262 0.000126 0.00030 48 12 0 1 47 12 0 3338 587.819210 587.819252 0.000042 0.00030 49 12 0 1 48 12 0 3339 587.475331 587.475174 -0.000157 0.00030 50 12 0 1 49 12 0 3340 597.461932 597.462162 0.000230 0.00030 21 13 0 1 20 13 0 3341 597.116984 597.117040 0.000056 0.00030 22 13 0 1 21 13 0 3342 596.772065 596.771836 -0.000229 0.00030 23 13 0 1 22 13 0 3343 596.427176 596.427104 -0.000072 0.00030 24 13 0 1 23 13 0 3344 596.082316 596.082510 0.000194 0.00030 25 13 0 1 24 13 0 3345 595.737488 595.737557 0.000069 0.00030 26 13 0 1 25 13 0 3346 595.392691 595.392801 0.000110 0.00030 27 13 0 1 26 13 0 3347 594.013837 594.013699 -0.000138 0.00030 31 13 0 1 30 13 0 3348 593.669210 593.669291 0.000081 0.00030 32 13 0 1 31 13 0 3349 593.324619 593.324611 -0.000008 0.00030 33 13 0 1 32 13 0 3350 592.980066 592.980120 0.000054 0.00030 34 13 0 1 33 13 0 3351 592.635549 592.635672 0.000123 0.00030 35 13 0 1 34 13 0 3352 592.291071 592.291115 0.000044 0.00030 36 13 0 1 35 13 0 3353 591.946632 591.946550 -0.000082 0.00030 37 13 0 1 36 13 0 3354 590.913554 590.913523 -0.000031 0.00030 40 13 0 1 39 13 0 3355 589.880850 589.880737 -0.000113 0.00030 43 13 0 1 42 13 0 3356 589.536702 589.536607 -0.000095 0.00030 44 13 0 1 43 13 0 3357 588.160558 588.160544 -0.000014 0.00030 48 13 0 1 47 13 0 R-BRANCH OF THE NU5 HOT BAND FOR SIGMA = +1 N6' = 1 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3358 607.807728 607.807505 -0.000223 0.00050 8 1 1 1 9 1 1 3359 608.153127 608.153114 -0.000013 0.00050 9 1 1 1 10 1 1 3360 608.498523 608.498422 -0.000101 0.00050 10 1 1 1 11 1 1 3361 608.843914 608.843860 -0.000054 0.00050 11 1 1 1 12 1 1 3362 609.189299 609.189219 -0.000080 0.00050 12 1 1 1 13 1 1 3363 609.534677 609.534549 -0.000128 0.00050 13 1 1 1 14 1 1 3364 609.880047 609.880050 0.000003 0.00050 14 1 1 1 15 1 1 3365 610.225408 610.225339 -0.000069 0.00050 15 1 1 1 16 1 1 3366 610.570758 610.570666 -0.000092 0.00050 16 1 1 1 17 1 1 3367 610.916097 610.916030 -0.000067 0.00050 17 1 1 1 18 1 1 3368 611.261423 611.261365 -0.000058 0.00050 18 1 1 1 19 1 1 3369 611.606735 611.606729 -0.000006 0.00050 19 1 1 1 20 1 1 3370 611.952032 611.952010 -0.000022 0.00050 20 1 1 1 21 1 1 3371 612.297312 612.297227 -0.000085 0.00050 21 1 1 1 22 1 1 3372 612.642575 612.642493 -0.000082 0.00050 22 1 1 1 23 1 1 3373 612.987819 612.987681 -0.000138 0.00050 23 1 1 1 24 1 1 3374 613.333043 613.332957 -0.000086 0.00050 24 1 1 1 25 1 1 3375 613.678245 613.678037 -0.000208 0.00050 25 1 1 1 26 1 1 3376 614.023425 614.023401 -0.000024 0.00050 26 1 1 1 27 1 1 3377 614.368581 614.368358 -0.000223 0.00050 27 1 1 1 28 1 1 3378 614.713712 614.713752 0.000040 0.00050 28 1 1 1 29 1 1 3379 615.058816 615.058645 -0.000171 0.00050 29 1 1 1 30 1 1 3380 615.403892 615.403867 -0.000025 0.00050 30 1 1 1 31 1 1 3381 615.748940 615.749060 0.000120 0.00050 31 1 1 1 32 1 1 3382 608.157375 608.157352 -0.000023 0.00050 9 4 1 1 10 4 1 3383 608.502772 608.502738 -0.000034 0.00050 10 4 1 1 11 4 1 3384 608.848165 608.848242 0.000077 0.00050 11 4 1 1 12 4 1 3385 609.193552 609.193307 -0.000245 0.00050 12 4 1 1 13 4 1 3386 609.538933 609.538879 -0.000054 0.00050 13 4 1 1 14 4 1 3387 609.884306 609.884281 -0.000025 0.00050 14 4 1 1 15 4 1 3388 610.229670 610.229615 -0.000055 0.00050 15 4 1 1 16 4 1 3389 610.575024 610.575055 0.000031 0.00050 16 4 1 1 17 4 1 3390 610.920367 610.920422 0.000055 0.00050 17 4 1 1 18 4 1 3391 611.611014 611.611001 -0.000013 0.00050 19 4 1 1 20 4 1 3392 611.956316 611.956336 0.000020 0.00050 20 4 1 1 21 4 1 R-BRANCH OF THE NU5 HOT BAND FOR SIGMA = +1 N6' = 1 Each line is a weighted average over the five K components which have the highest frequencies. CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3393 609.542953 609.542886 -0.000067 0.00050 13 * 1 1 14 * 1 3394 609.888304 609.888398 0.000094 0.00050 14 * 1 1 15 * 1 3395 610.233658 610.233620 -0.000038 0.00050 15 * 1 1 16 * 1 3396 610.579007 610.579146 0.000139 0.00050 16 * 1 1 17 * 1 3397 610.924348 610.924446 0.000098 0.00050 17 * 1 1 18 * 1 3398 611.269681 611.269732 0.000051 0.00050 18 * 1 1 19 * 1 3399 611.615001 611.615135 0.000134 0.00050 19 * 1 1 20 * 1 3400 611.960309 611.960411 0.000102 0.00050 20 * 1 1 21 * 1 3401 612.305602 612.305663 0.000061 0.00050 21 * 1 1 22 * 1 3402 612.650879 612.651027 0.000148 0.00050 22 * 1 1 23 * 1 3403 612.996139 612.996210 0.000071 0.00050 23 * 1 1 24 * 1 3404 613.341381 613.341515 0.000134 0.00050 24 * 1 1 25 * 1 3405 613.686603 613.686673 0.000070 0.00050 25 * 1 1 26 * 1 3406 614.031803 614.031920 0.000117 0.00050 26 * 1 1 27 * 1 3407 614.376982 614.377000 0.000018 0.00050 27 * 1 1 28 * 1 3408 614.722137 614.722246 0.000109 0.00050 28 * 1 1 29 * 1 3409 615.067266 615.067340 0.000074 0.00050 29 * 1 1 30 * 1 3410 615.412370 615.412381 0.000011 0.00050 30 * 1 1 31 * 1 3411 615.757446 615.757490 0.000044 0.00050 31 * 1 1 32 * 1 3412 616.102493 616.102570 0.000077 0.00050 32 * 1 1 33 * 1 3413 616.447510 616.447660 0.000150 0.00050 33 * 1 1 34 * 1 3414 616.792495 616.792435 -0.000060 0.00050 34 * 1 1 35 * 1 3415 617.137448 617.137476 0.000028 0.00050 35 * 1 1 36 * 1 3416 617.482366 617.482203 -0.000163 0.00050 36 * 1 1 37 * 1 3417 617.827249 617.827248 -0.000001 0.00050 37 * 1 1 38 * 1 3418 618.861671 618.861663 -0.000008 0.00050 40 * 1 1 41 * 1 3419 619.206398 619.206287 -0.000111 0.00050 41 * 1 1 42 * 1 3420 619.551084 619.550930 -0.000154 0.00050 42 * 1 1 43 * 1 3421 619.895725 619.895505 -0.000220 0.00050 43 * 1 1 44 * 1 3422 620.240322 620.240305 -0.000017 0.00050 44 * 1 1 45 * 1 3423 620.584873 620.584664 -0.000209 0.00050 45 * 1 1 46 * 1 3424 620.929376 620.929248 -0.000128 0.00050 46 * 1 1 47 * 1 P-BRANCH OF THE NU5 HOT BAND FOR SIGMA = +1 N6' = 1 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3425 600.210205 600.210257 0.000052 0.00050 13 1 1 1 12 1 1 3426 599.865011 599.865001 -0.000010 0.00050 14 1 1 1 13 1 1 3427 599.519837 599.519759 -0.000078 0.00050 15 1 1 1 14 1 1 3428 599.174685 599.174711 0.000026 0.00050 16 1 1 1 15 1 1 3429 598.829554 598.829526 -0.000028 0.00050 17 1 1 1 16 1 1 3430 598.484446 598.484270 -0.000176 0.00050 18 1 1 1 17 1 1 3431 598.139362 598.139295 -0.000067 0.00050 19 1 1 1 18 1 1 3432 597.794302 597.794235 -0.000067 0.00050 20 1 1 1 19 1 1 3433 597.449268 597.449170 -0.000098 0.00050 21 1 1 1 20 1 1 3434 597.104259 597.104193 -0.000066 0.00050 22 1 1 1 21 1 1 3435 596.759277 596.759266 -0.000011 0.00050 23 1 1 1 22 1 1 3436 596.414323 596.414375 0.000052 0.00050 24 1 1 1 23 1 1 3437 596.069398 596.069386 -0.000012 0.00050 25 1 1 1 24 1 1 3438 595.724501 595.724593 0.000092 0.00050 26 1 1 1 25 1 1 3439 595.379635 595.379768 0.000133 0.00050 27 1 1 1 26 1 1 3440 595.034799 595.034983 0.000184 0.00050 28 1 1 1 27 1 1 3441 599.869318 599.869557 0.000239 0.00050 14 4 1 1 13 4 1 3442 599.524151 599.524072 -0.000079 0.00050 15 4 1 1 14 4 1 3443 599.179005 599.179137 0.000132 0.00050 16 4 1 1 15 4 1 3444 598.833881 598.833820 -0.000061 0.00050 17 4 1 1 16 4 1 3445 598.488781 598.488733 -0.000048 0.00050 18 4 1 1 17 4 1 3446 598.143705 598.143687 -0.000018 0.00050 19 4 1 1 18 4 1 3447 597.798653 597.798914 0.000261 0.00050 20 4 1 1 19 4 1 P-BRANCH OF THE NU5 HOT BAND FOR SIGMA = +1 N6' = 1 Each line is a weighted average over the five K components which have the highest frequencies. CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCUALTED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3448 599.528498 599.528678 0.000180 0.00050 15 * 1 1 14 * 1 3449 599.183383 599.183443 0.000060 0.00050 16 * 1 1 15 * 1 3450 598.838291 598.838437 0.000146 0.00050 17 * 1 1 16 * 1 3451 598.493224 598.493404 0.000180 0.00050 18 * 1 1 17 * 1 3452 598.148181 598.148263 0.000082 0.00050 19 * 1 1 18 * 1 3453 597.803165 597.803240 0.000075 0.00050 20 * 1 1 19 * 1 3454 597.458176 597.458336 0.000160 0.00050 21 * 1 1 20 * 1 3455 597.113214 597.113237 0.000023 0.00050 22 * 1 1 21 * 1 3456 596.768280 596.768388 0.000108 0.00050 23 * 1 1 22 * 1 3457 596.423402 596.423460 0.000058 0.00050 24 * 1 1 23 * 1 3458 596.078529 596.078552 0.000023 0.00050 25 * 1 1 24 * 1 3459 595.733688 595.733820 0.000132 0.00050 26 * 1 1 25 * 1 3460 595.388878 595.388844 -0.000034 0.00050 27 * 1 1 26 * 1 3461 595.044101 595.044115 0.000014 0.00050 28 * 1 1 27 * 1 3462 594.699357 594.699341 -0.000016 0.00050 29 * 1 1 28 * 1 3463 594.354647 594.354740 0.000093 0.00050 30 * 1 1 29 * 1 3464 592.976159 592.976022 -0.000137 0.00050 34 * 1 1 33 * 1 3465 592.631629 592.631545 -0.000084 0.00050 35 * 1 1 34 * 1 3466 592.287137 592.286998 -0.000139 0.00050 36 * 1 1 35 * 1 3467 591.942683 591.942477 -0.000206 0.00050 37 * 1 1 36 * 1 3468 591.598269 591.597991 -0.000278 0.00050 38 * 1 1 37 * 1 3469 591.253894 591.253649 -0.000245 0.00050 39 * 1 1 38 * 1 3470 590.909561 590.909391 -0.000170 0.00050 40 * 1 1 39 * 1 3471 590.565269 590.565081 -0.000188 0.00050 41 * 1 1 40 * 1 3472 590.221018 590.220700 -0.000318 0.00050 42 * 1 1 41 * 1 3473 589.876811 589.876607 -0.000204 0.00050 43 * 1 1 42 * 1 3474 589.532647 589.532329 -0.000318 0.00050 44 * 1 1 43 * 1 3475 589.188453 589.188370 -0.000083 0.00050 45 * 1 1 44 * 1 3476 588.844389 588.843966 -0.000423 0.00050 46 * 1 1 45 * 1 3477 588.500371 588.500086 -0.000285 0.00050 47 * 1 1 46 * 1 3478 588.156399 588.156074 -0.000325 0.00050 48 * 1 1 47 * 1 3479 587.812474 587.812124 -0.000350 0.00050 49 * 1 1 48 * 1 R-BRANCH OF THE NU5 HOT BAND FOR SIGMA = -1 N6' = 1 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3480 608.147853 608.148193 0.000340 0.00050 9 2 -1 1 10 2 -1 3481 608.493246 608.493218 -0.000028 0.00050 10 2 -1 1 11 2 -1 3482 608.838633 608.838629 -0.000004 0.00050 11 2 -1 1 12 2 -1 3483 609.184015 609.183952 -0.000063 0.00050 12 2 -1 1 13 2 -1 3484 609.529389 609.529284 -0.000105 0.00050 13 2 -1 1 14 2 -1 3485 609.874756 609.874727 -0.000029 0.00050 14 2 -1 1 15 2 -1 3486 610.220112 610.220086 -0.000026 0.00050 15 2 -1 1 16 2 -1 3487 610.565458 610.565445 -0.000013 0.00050 16 2 -1 1 17 2 -1 3488 610.910792 610.910743 -0.000049 0.00050 17 2 -1 1 18 2 -1 3489 611.256114 611.255897 -0.000217 0.00050 18 2 -1 1 19 2 -1 3490 611.601421 611.601389 -0.000032 0.00050 19 2 -1 1 20 2 -1 3491 611.946712 611.946630 -0.000082 0.00050 20 2 -1 1 21 2 -1 3492 612.291987 612.291921 -0.000066 0.00050 21 2 -1 1 22 2 -1 3493 612.637244 612.637182 -0.000062 0.00050 22 2 -1 1 23 2 -1 3494 612.982482 612.982453 -0.000029 0.00050 23 2 -1 1 24 2 -1 3495 613.327699 613.327646 -0.000053 0.00050 24 2 -1 1 25 2 -1 3496 613.672895 613.672804 -0.000091 0.00050 25 2 -1 1 26 2 -1 3497 614.018068 614.018139 0.000071 0.00050 26 2 -1 1 27 2 -1 3498 614.363217 614.363022 -0.000195 0.00050 27 2 -1 1 28 2 -1 3499 608.145926 608.145848 -0.000078 0.00050 9 3 -1 1 10 3 -1 3500 608.491317 608.491269 -0.000048 0.00050 10 3 -1 1 11 3 -1 3501 608.836704 608.836491 -0.000213 0.00050 11 3 -1 1 12 3 -1 3502 609.182084 609.181666 -0.000418 0.00050 12 3 -1 1 13 3 -1 3503 609.527457 609.527313 -0.000144 0.00050 13 3 -1 1 14 3 -1 3504 609.872822 609.872753 -0.000069 0.00050 14 3 -1 1 15 3 -1 3505 610.218177 610.218222 0.000045 0.00050 15 3 -1 1 16 3 -1 3506 610.563521 610.563390 -0.000131 0.00050 16 3 -1 1 17 3 -1 3507 610.908854 610.908730 -0.000124 0.00050 17 3 -1 1 18 3 -1 3508 611.254173 611.254097 -0.000076 0.00050 18 3 -1 1 19 3 -1 3509 611.599479 611.599270 -0.000209 0.00050 19 3 -1 1 20 3 -1 3510 611.944768 611.944467 -0.000301 0.00050 20 3 -1 1 21 3 -1 3511 612.290041 612.289777 -0.000264 0.00050 21 3 -1 1 22 3 -1 3512 612.635296 612.635009 -0.000287 0.00050 22 3 -1 1 23 3 -1 3513 612.980532 612.980491 -0.000041 0.00050 23 3 -1 1 24 3 -1 3514 608.832669 608.832636 -0.000033 0.00050 11 5 -1 1 12 5 -1 3515 609.178047 609.178263 0.000216 0.00050 12 5 -1 1 13 5 -1 3516 609.523417 609.523583 0.000166 0.00050 13 5 -1 1 14 5 -1 3517 609.868778 609.868677 -0.000101 0.00050 14 5 -1 1 15 5 -1 3518 610.214130 610.214230 0.000100 0.00050 15 5 -1 1 16 5 -1 3519 610.559472 610.559580 0.000108 0.00050 16 5 -1 1 17 5 -1 3520 610.904801 610.904878 0.000077 0.00050 17 5 -1 1 18 5 -1 3521 611.250117 611.250159 0.000042 0.00050 18 5 -1 1 19 5 -1 3522 611.595419 611.595420 0.000001 0.00050 19 5 -1 1 20 5 -1 3523 611.940705 611.940671 -0.000034 0.00050 20 5 -1 1 21 5 -1 3524 612.285974 612.285977 0.000003 0.00050 21 5 -1 1 22 5 -1 3525 612.631226 612.631238 0.000012 0.00050 22 5 -1 1 23 5 -1 P-BRANCH OF THE NU5 HOT BAND FOR SIGMA = -1 N6' = 1 CALCULATED OBSERVED OBSERVED EXPERIMENTAL J" K" NU6" J' K' VALUE VALUE -CALCULATED ERROR sigma" sigma' cm-1 cm-1 cm-1 cm-1 3526 600.204935 600.204904 -0.000031 0.00050 13 2 -1 1 12 2 -1 3527 599.859738 599.859675 -0.000063 0.00050 14 2 -1 1 13 2 -1 3528 599.514561 599.514590 0.000029 0.00050 15 2 -1 1 14 2 -1 3529 599.169406 599.169383 -0.000023 0.00050 16 2 -1 1 15 2 -1 3530 598.824272 598.824232 -0.000040 0.00050 17 2 -1 1 16 2 -1 3531 598.479160 598.479012 -0.000148 0.00050 18 2 -1 1 17 2 -1 3532 598.134072 598.134180 0.000108 0.00050 19 2 -1 1 18 2 -1 3533 597.789008 597.789113 0.000105 0.00050 20 2 -1 1 19 2 -1 3534 597.443970 597.443910 -0.000060 0.00050 21 2 -1 1 20 2 -1 3535 597.098956 597.098850 -0.000106 0.00050 22 2 -1 1 21 2 -1 3536 596.753970 596.754001 0.000031 0.00050 23 2 -1 1 22 2 -1 3537 596.409011 596.408978 -0.000033 0.00050 24 2 -1 1 23 2 -1 3538 596.064080 596.064023 -0.000057 0.00050 25 2 -1 1 24 2 -1 3539 595.719178 595.719171 -0.000007 0.00050 26 2 -1 1 25 2 -1 3540 595.374305 595.374261 -0.000044 0.00050 27 2 -1 1 26 2 -1 3541 595.029464 595.029448 -0.000016 0.00050 28 2 -1 1 27 2 -1 3542 594.684653 594.684572 -0.000081 0.00050 29 2 -1 1 28 2 -1 3543 594.339874 594.339828 -0.000046 0.00050 30 2 -1 1 29 2 -1 3544 593.995127 593.995111 -0.000016 0.00050 31 2 -1 1 30 2 -1 3545 593.650414 593.650534 0.000120 0.00050 32 2 -1 1 31 2 -1 3546 593.305735 593.305776 0.000041 0.00050 33 2 -1 1 32 2 -1 3547 599.512648 599.512435 -0.000213 0.00050 15 3 -1 1 14 3 -1 3548 599.167492 599.167288 -0.000204 0.00050 16 3 -1 1 15 3 -1 3549 598.822358 598.822552 0.000194 0.00050 17 3 -1 1 16 3 -1 3550 598.477246 598.477436 0.000190 0.00050 18 3 -1 1 17 3 -1 3551 598.132158 598.132307 0.000149 0.00050 19 3 -1 1 18 3 -1 3552 597.787094 597.787158 0.000064 0.00050 20 3 -1 1 19 3 -1 3553 597.442054 597.441946 -0.000108 0.00050 21 3 -1 1 20 3 -1 3554 597.097041 597.097099 0.000058 0.00050 22 3 -1 1 21 3 -1 3555 596.752054 596.752233 0.000179 0.00050 23 3 -1 1 22 3 -1 3556 596.407094 596.406986 -0.000108 0.00050 24 3 -1 1 23 3 -1 3557 596.062162 596.062076 -0.000086 0.00050 25 3 -1 1 24 3 -1 3558 595.717260 595.717359 0.000099 0.00050 26 3 -1 1 25 3 -1 3559 595.372387 595.372492 0.000105 0.00050 27 3 -1 1 26 3 -1 3560 595.027544 595.027653 0.000109 0.00050 28 3 -1 1 27 3 -1 3561 594.682732 594.682946 0.000214 0.00050 29 3 -1 1 28 3 -1 3562 594.337952 594.338205 0.000253 0.00050 30 3 -1 1 29 3 -1 3563 593.993205 593.993304 0.000099 0.00050 31 3 -1 1 30 3 -1 3564 593.648491 593.648555 0.000064 0.00050 32 3 -1 1 31 3 -1 3565 593.303811 593.303931 0.000120 0.00050 33 3 -1 1 32 3 -1 3566 592.959165 592.959465 0.000300 0.00050 34 3 -1 1 33 3 -1 3567 592.614556 592.614613 0.000057 0.00050 35 3 -1 1 34 3 -1 3568 600.544254 600.544290 0.000036 0.00050 12 5 -1 1 11 5 -1 3569 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