Supplementary material in electronic form for the paper WATER SPECTRA IN THE 4200-6250 cm-1 REGION: EXTENDED ANALYSIS OF n1+n2, n2+n3, AND 3n2 BANDS AND CONFIRMATION OF HIGHLY EXCITED STATES FROM FLAME SPECTRA AND FROM ATMOSPHERIC LONG-PATH OBSERVATIONS by (1) S.N. MIKHAILENKO, (2) VL.G. TYUTEREV, (1) V.I. STARIKOV, (3) K.K. ALBERT, (3,#) B.P. WINNEWISSER, (3,#) M. WINNEWISSER, (3) G. MELLAU, (4) C. CAMY-PEYRET, (4) R. LANQUETIN, (5) J.-M. FLAUD and (6) J.W. BRAULT (1) Institute of Atmospheric Optics, Russian Academy of Sciences, 1, av.Akademicheskii, 634055 Tomsk, Russia (2) Groupe de Spectrometrie Moleculaire et Atmospherique, UMR CNRS 6089, Universite de Reims, Faculte des Sciences, Moulin de la Housse, BP 1039, 51687 Reims Cedex 2, France (3) Justus-Liebig-Universitaet Giessen, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany (4)Laboratoire de Physique Moleculaire et Applications, Universite Pierre et Marie Curie, Tour 13, Bte 76, 4 place Jussieu, 75252 Paris Cedex 05, France (5)Laboratoire de Photophysique Moleculaire, Universite Paris-Sud, Bat. 350, 91405 Orsay, France (6)Laboratory for Atmospheric and Space Physics, Campus Box 590, Univ. of Colorado, Boulder, CO 80309-0590 (#) Present address: Department of Physics, The Ohio State University, Columbus, Ohio, USA 43210 submitted to Journal of Molecular Spectroscopy. ---------------------------------------------- Appendix 2. Ground State H2(16)O energy levels consistent with observed line positions and second triad rovibrational levels of Table 5. E/hc = experimental term values [in cm-1], dE = standard error of energy level determination [in 10-3 cm-1] Nup = number of obs. transition (included in RITZ-calculations: see Section 2) in which a given level appears as upper state levels. Nlow = number of obs. transition (included in RITZ-calculations: see Section 2) in which a given level appear as lower state levels. v1v2v3 J Ka Kc E/hc dE Nup Nlow 000 0 0 0 .00000 .05 0 30 000 1 0 1 23.79435 .05 0 87 000 1 1 1 37.13720 .04 1 82 000 1 1 0 42.37166 .05 1 73 000 2 0 2 70.09084 .04 1 110 000 2 1 2 79.49635 .04 1 137 000 2 1 1 95.17588 .04 1 90 000 2 2 1 134.90155 .04 2 120 000 2 2 0 136.16386 .04 2 100 000 3 0 3 136.76166 .04 1 153 000 3 1 3 142.27847 .03 2 144 000 3 1 2 173.36566 .04 2 148 000 3 2 2 206.30154 .03 2 133 000 3 2 1 212.15631 .04 2 153 000 3 3 1 285.21947 .03 3 108 000 3 3 0 285.41867 .04 3 119 000 4 0 4 222.05275 .03 1 152 000 4 1 4 224.83828 .04 2 173 000 4 1 3 275.49702 .03 2 135 000 4 2 3 300.36229 .04 3 182 000 4 2 2 315.77956 .03 3 156 000 4 3 2 382.51698 .04 4 161 000 4 3 1 383.84276 .03 3 135 000 4 4 1 488.10793 .04 4 118 000 4 4 0 488.13450 .03 3 111 000 5 0 5 325.34795 .03 1 177 000 5 1 5 326.62561 .03 2 156 000 5 1 4 399.45751 .03 2 173 000 5 2 4 416.20893 .03 3 154 000 5 2 3 446.51062 .03 3 181 000 5 3 3 503.96823 .03 4 161 000 5 3 2 508.81215 .03 4 183 000 5 4 2 610.11475 .03 4 127 000 5 4 1 610.34137 .03 4 152 000 5 5 1 742.07327 .03 4 71 000 5 5 0 742.07644 .04 5 95 000 6 0 6 446.69654 .03 1 139 000 6 1 6 447.25237 .03 2 175 000 6 1 5 542.90582 .03 2 152 000 6 2 5 552.91141 .03 3 185 000 6 2 4 602.77352 .03 4 159 000 6 3 4 648.97873 .03 4 187 000 6 3 3 661.54904 .03 4 156 000 6 4 3 756.72500 .03 5 167 000 6 4 2 757.78041 .03 5 153 000 6 5 2 888.59901 .03 5 131 000 6 5 1 888.63280 .03 5 113 000 6 6 1 1045.05840 .04 4 76 000 6 6 0 1045.05863 .03 4 57 000 7 0 7 586.24359 .03 1 155 000 7 1 7 586.47928 .02 1 130 000 7 1 6 704.21406 .03 2 168 000 7 2 6 709.60825 .02 3 145 000 7 2 5 782.40983 .03 3 176 000 7 3 5 816.69448 .02 4 147 000 7 3 4 842.35674 .03 4 168 000 7 4 4 927.74415 .02 4 126 000 7 4 3 931.23730 .03 6 161 000 7 5 3 1059.64700 .03 6 105 000 7 5 2 1059.83570 .03 6 136 000 7 6 2 1216.19022 .03 4 70 000 7 6 1 1216.19466 .03 4 97 000 7 7 1 1394.81466 .04 4 45 000 7 7 0 1394.81464 .03 4 65 000 8 0 8 744.06400 .02 1 119 000 8 1 8 744.16278 .03 1 151 000 8 1 7 882.89051 .02 2 124 000 8 2 7 885.60030 .03 3 154 000 8 2 6 982.91187 .02 3 127 000 8 3 6 1006.11606 .03 4 168 000 8 3 5 1050.15785 .02 4 120 000 8 4 5 1122.70862 .03 5 142 000 8 4 4 1131.77585 .02 4 114 000 8 5 4 1255.16700 .03 5 135 000 8 5 3 1255.91187 .02 4 95 000 8 6 3 1411.61178 .03 6 104 000 8 6 2 1411.64232 .03 5 83 000 8 7 2 1590.69045 .03 4 72 000 8 7 1 1590.69095 .03 3 44 000 8 8 1 1789.04333 .04 3 27 000 8 8 0 1789.04385 .08 1 11 000 9 0 9 920.16862 .03 1 124 000 9 1 9 920.21035 .02 1 99 000 9 1 8 1079.07960 .03 2 127 000 9 2 8 1080.38563 .02 2 110 000 9 2 7 1201.92155 .03 3 139 000 9 3 7 1216.23152 .02 4 111 000 9 3 6 1282.91919 .03 4 117 000 9 4 6 1340.88516 .02 4 93 000 9 4 5 1360.23549 .03 5 125 000 9 5 5 1474.98109 .02 5 82 000 9 5 4 1477.29755 .03 4 105 000 9 6 4 1631.24600 .03 5 60 000 9 6 3 1631.38340 .03 5 84 000 9 7 3 1810.58394 .03 3 41 000 9 7 2 1810.58798 .03 4 65 000 9 8 2 2009.80659 .08 2 13 000 9 8 1 2009.80544 .03 4 40 000 9 9 1 2225.47024 .08 3 2 000 9 9 0 2225.46954 .04 2 19 000 10 0 10 1114.53252 .03 1 76 000 10 1 10 1114.54999 .03 1 100 000 10 1 9 1293.01854 .02 2 85 000 10 2 9 1293.63423 .03 3 121 000 10 2 8 1437.96888 .02 3 85 000 10 3 8 1446.12840 .03 5 113 000 10 3 7 1538.14976 .02 5 75 000 10 4 7 1581.33630 .03 5 99 000 10 4 6 1616.45334 .02 4 61 000 10 5 6 1718.71909 .03 5 91 000 10 5 5 1724.70581 .02 4 61 000 10 6 5 1874.97335 .03 5 67 000 10 6 4 1875.46240 .03 5 46 000 10 7 4 2054.34563 .03 4 51 000 10 7 3 2054.36918 .03 4 35 000 10 8 3 2254.28440 .03 4 36 000 10 8 2 2254.28488 .05 3 10 000 10 9 2 2471.25535 .03 3 25 000 10 9 1 2471.25592 .08 2 3 000 10 10 1 2701.88880 .04 1 14 000 10 10 0 2701.88883 .15 0 1 000 11 0 11 1327.11026 .03 1 85 000 11 1 11 1327.11804 .03 1 52 000 11 1 10 1524.84804 .03 2 87 000 11 2 10 1525.13639 .02 2 57 000 11 2 9 1690.66454 .02 3 85 000 11 3 9 1695.06905 .03 3 58 000 11 3 8 1813.22360 .02 4 72 000 11 4 8 1843.03004 .02 5 51 000 11 4 7 1899.00836 .02 5 61 000 11 5 7 1985.78541 .02 4 45 000 11 5 6 1998.99553 .02 4 59 000 11 6 6 2142.59818 .03 3 32 000 11 6 5 2144.04674 .02 4 56 000 11 7 5 2321.81361 .03 3 23 000 11 7 4 2321.90623 .03 4 41 000 11 8 4 2522.26123 .05 2 13 000 11 8 3 2522.26521 .03 4 33 000 11 9 3 2740.42172 .06 2 2 000 11 9 2 2740.42129 .03 4 21 000 11 10 1 2972.82770 .04 3 14 000 11 11 0 3216.19356 .06 1 8 000 12 0 12 1557.84499 .04 1 45 000 12 1 12 1557.84795 .03 1 62 000 12 1 11 1774.61674 .03 2 55 000 12 2 11 1774.75133 .03 2 62 000 12 2 10 1960.20770 .03 3 45 000 12 3 10 1962.50706 .03 3 58 000 12 3 9 2105.86825 .03 3 40 000 12 4 9 2124.95178 .02 5 59 000 12 4 8 2205.65340 .03 3 37 000 12 5 8 2275.37307 .02 4 47 000 12 5 7 2300.68537 .03 2 30 000 12 6 7 2433.80087 .03 4 39 000 12 6 6 2437.50232 .03 2 29 000 12 7 6 2612.80010 .03 5 31 000 12 7 5 2613.10515 .03 3 22 000 12 8 5 2813.51237 .03 5 23 000 12 8 4 2813.52915 .04 3 15 000 12 9 4 3032.69047 .03 3 20 000 12 9 3 3032.69046 .07 3 1 000 12 10 3 3266.76477 .04 2 12 000 12 11 2 3512.40502 .05 1 9 000 12 12 1 3766.38756 .08 1 5 000 13 0 13 1806.67026 .03 1 47 000 13 1 13 1806.67182 .05 1 34 000 13 1 12 2042.31081 .03 2 52 000 13 2 12 2042.37455 .04 2 39 000 13 2 11 2246.88510 .03 3 50 000 13 3 11 2248.06477 .04 3 33 000 13 3 10 2414.72353 .03 3 39 000 13 4 10 2426.19695 .04 3 26 000 13 4 9 2533.79344 .03 5 28 000 13 5 9 2586.53020 .04 4 24 000 13 5 8 2629.33470 .03 2 31 000 13 6 8 2748.09989 .04 4 21 000 13 6 7 2756.41551 .03 3 28 000 13 7 7 2927.07592 .04 4 17 000 13 7 6 2927.94179 .03 4 21 000 13 8 6 3127.80350 .05 4 14 000 13 8 5 3127.86192 .03 3 18 000 13 9 5 3347.78086 .06 2 4 000 13 9 4 3347.78264 .04 3 12 000 13 10 3 3583.37464 .05 3 10 000 13 11 2 3831.17906 .05 2 9 000 13 12 1 4087.98056 .07 1 6 000 13 13 0 4350.59168 .12 1 5 000 14 0 14 2073.51521 .06 1 29 000 14 1 14 2073.51588 .04 1 38 000 14 1 13 2327.88382 .05 2 29 000 14 2 13 2327.91426 .04 2 37 000 14 2 12 2550.88275 .05 3 31 000 14 3 12 2551.48374 .03 3 31 000 14 3 11 2739.42860 .05 1 18 000 14 4 11 2746.02376 .03 2 32 000 14 4 10 2880.83439 .05 3 16 000 14 5 10 2918.24558 .03 4 24 000 14 5 9 2983.39665 .05 3 15 000 14 6 9 3084.83592 .03 5 23 000 14 6 8 3101.44124 .06 2 13 000 14 7 8 3264.33786 .03 4 19 000 14 7 7 3266.51470 .06 3 8 000 14 8 7 3464.88764 .04 4 14 000 14 8 6 3465.07004 .05 2 11 000 14 9 6 3685.40822 .04 3 10 000 14 9 5 3685.41939 .06 3 5 000 14 10 5 3922.33047 .05 3 9 000 14 10 4 3922.33627 .11 1 0 000 14 11 4 4172.15244 .05 3 9 000 14 12 3 4431.63731 .07 1 5 000 14 13 2 4697.66155 .09 1 4 000 14 14 1 4967.04235 .16 1 3 000 15 0 15 2358.30193 .04 1 31 000 15 1 15 2358.30198 .07 1 22 000 15 1 14 2631.26934 .04 2 30 000 15 2 14 2631.28344 .07 2 18 000 15 2 13 2872.27456 .04 2 25 000 15 3 13 2872.58070 .06 2 16 000 15 3 12 3080.17891 .04 3 20 000 15 4 12 3083.86536 .06 2 16 000 15 4 11 3244.60101 .04 3 16 000 15 5 11 3269.54004 .06 3 13 000 15 5 10 3360.60040 .04 3 16 000 15 6 10 3443.19222 .06 4 12 000 15 6 9 3472.88176 .04 3 15 000 15 7 9 3624.18145 .06 4 8 000 15 7 8 3629.09638 .04 3 14 000 15 8 8 3824.49873 .06 4 8 000 15 8 7 3824.99837 .04 3 11 000 15 9 7 4045.28601 .06 3 6 000 15 9 6 4045.32192 .04 3 9 000 16 0 16 2660.94699 .10 1 10 000 16 1 16 2660.94593 .05 1 22 000 16 1 15 2952.38649 .08 0 10 000 16 2 15 2952.39386 .05 1 18 000 16 2 14 3211.05581 .07 1 12 000 16 3 14 3211.21318 .05 2 13 000 16 3 13 3437.27730 .07 1 11 000 16 4 13 3439.30730 .05 2 15 000 16 4 12 3623.76528 .08 1 9 000 16 5 12 3639.53844 .05 4 15 000 16 5 11 3758.39746 .07 3 8 000 16 6 11 3822.24634 .05 4 12 000 16 6 10 3870.20209 .07 3 7 000 16 7 10 4006.07359 .05 4 10 000 16 7 9 4016.13486 .07 2 6 000 16 8 9 4206.33167 .05 4 9 000 16 8 8 4207.56258 .07 3 7 000 17 0 17 2981.35970 .07 1 13 000 17 1 17 2981.36076 .11 1 2 000 17 1 16 3291.14829 .06 1 12 000 17 2 16 3291.15252 .12 0 8 000 17 2 15 3567.17379 .06 1 12 000 17 3 15 3567.25535 .09 1 8 000 17 3 14 3810.93699 .06 2 12 000 17 4 14 3812.04776 .09 2 10 000 17 4 13 4017.90854 .06 3 11 000 17 5 13 4027.50625 .08 3 9 000 17 5 12 4174.28761 .06 3 9 000 18 0 18 3319.44785 .16 0 2 000 18 1 18 3319.44826 .08 0 11 000 18 1 17 3647.46050 .13 0 5 000 18 2 17 3647.46088 .08 0 10 000 18 2 16 3940.54607 .11 1 9 000 18 3 16 3940.58742 .07 1 9 000 18 3 15 4201.25195 .11 2 5 000 19 0 19 3675.11293 .10 0 8 000 19 1 19 3675.11326 .16 0 2 000 19 1 18 4021.21788 .10 0 9 000 19 2 18 4021.22252 .16 1 6 000 19 2 17 4331.06685 .08 2 8 000 20 1 20 4048.24900 .11 0 7 000 20 1 19 4412.31670 .18 1 5 000 20 2 19 4412.31677 .11 1 8 000 20 2 18 4738.62190 .16 2 4 000 21 0 21 4438.74811 .12 1 8 000 21 1 20 4820.64265 .12 2 8 000 21 2 20 4820.64466 .23 1 2 000 21 2 19 5163.08119 .12 2 8 ----------------------------------------------