SUPPLEMENTARY MATERIAL for the article: Centrifugal Distortion Analysis of the Millimetre-Wave Spectrum of 1,1,1,2-Tetrafluoroethane by L. Bizzocchi, C. Degli Esposti, and L. Dore Dipartimento di Chimica "G. Ciamician", Università di Bologna, Via F. Selmi 2, 40126 Bologna, Italy The supplementary material consists of 2 tables, which contain the list of rotational transition frequencies analysed for 1,1,1,2-Tetrafluoroethane (HFC 134a) in the ground (Table I) and in the first excited torsional state (Table II). All the reported millimetre-wave measurements are original, while the centimetre-wave transition frequencies were taken from the following previous works: 1. L.-H. Xu, A.M. Andrews, R.R. Cavanagh, G.T. Fraser, K.K. Irikura, F.J. Lovas, J.-U. Grabow, W. Stahl, M.K. Crawford, and R.J. Smalley. J. Phys. Chem. A 101, 2288-2297 (1997). 2. T. Ogata, and Y. Miki J. Mol. Struct. 140, 49-56 (1986). Table I Analysed transition frequencies (MHz) of HFC 134a in the Ground State MWFT measurements from Ref. (1) J’ K’a K’c J Ka Kc observed calculated o - c 6 2 4 6 1 5 7346.429 7346.430 -.001 5 2 3 5 1 4 7448.167 7448.167 .000 4 2 2 4 1 3 7537.529 7537.528 .001 3 2 1 3 1 2 7612.019 7612.018 .001 2 2 0 2 1 1 7669.641 7669.635 .006 2 2 1 2 1 2 7788.520 7788.517 .003 3 2 2 3 1 3 7848.394 7848.396 -.002 4 2 3 4 1 4 7928.411 7928.408 .003 5 2 4 5 1 5 8028.690 8028.688 .002 1 1 1 0 0 0 8115.043 8115.048 -.005 6 2 5 6 1 6 8149.399 8149.397 .002 7 2 6 7 1 7 8290.709 8290.710 -.001 8 2 7 8 1 8 8452.810 8452.804 .006 2 0 2 1 1 1 8560.437 8560.436 .001 9 2 8 9 1 9 8635.855 8635.856 -.001 3 1 3 2 2 0 8826.950 8826.947 .003 10 2 9 10 1 10 8840.026 8840.025 .001 11 2 10 11 1 11 9065.441 9065.443 -.002 4 2 3 3 3 0 9352.282 9352.285 -.003 4 2 2 3 3 1 9359.190 9359.192 -.002 13 2 12 13 1 13 9580.355 9580.355 .000 5 3 3 4 4 0 9760.987 9760.989 -.002 5 3 2 4 4 1 9761.079 9761.082 -.003 6 4 2 5 5 1 10166.464 10166.466 -.002 15 2 14 15 1 15 10180.694 10180.694 .000 7 5 2 6 6 1 10571.592 10571.594 -.002 2 1 2 1 1 1 11077.495 11077.494 .001 2 0 2 1 0 1 11116.833 11116.832 .001 2 1 1 1 1 0 11157.057 11157.056 .001 9 3 6 9 2 7 12774.564 12774.566 -.002 8 3 5 8 2 6 12812.316 12812.318 -.002 7 3 4 7 2 5 12839.261 12839.263 -.002 6 3 3 6 2 4 12857.533 12857.536 -.003 5 3 2 5 2 3 12869.143 12869.149 -.006 4 3 1 4 2 2 12875.915 12875.917 -.002 3 3 0 3 2 1 12879.406 12879.403 .003 3 3 1 3 2 2 12881.708 12881.702 .006 4 3 2 4 2 3 12882.797 12882.798 -.001 5 3 3 5 2 4 12885.146 12885.152 -.006 Table I - continued (1) J’ K’a K’c J Ka Kc observed calculated o - c 6 3 4 6 2 5 12889.399 12889.405 -.006 7 3 5 7 2 6 12896.299 12896.303 -.004 8 3 6 8 2 7 12906.691 12906.695 -.004 2 1 2 1 0 1 13633.890 13633.890 .000 3 0 3 2 1 2 14157.007 14157.007 .000 4 1 4 3 2 1 14303.283 14303.280 .003 4 1 3 3 2 2 14703.364 14703.366 -.002 5 2 4 4 3 1 14909.007 14908.999 .008 5 2 3 4 3 2 14925.125 14925.119 .006 Stark-modulation measurements from Ref. (2) J’ K’a K’c J Ka Kc observed calculated o - c 15 3 12 15 2 13 12216.620 12216.505 .115 40 3 37 40 2 38 12332.000 12332.003 -.003 14 3 11 14 2 12 12355.320 12355.318 .002 13 3 10 13 2 11 12475.060 12474.983 .077 33 2 31 33 1 32 12515.800 12515.676 .124 12 3 9 12 2 10 12575.680 12575.650 .030 11 3 8 11 2 9 12658.240 12658.148 .093 10 3 7 10 2 8 12723.940 12723.857 .083 26 1 25 26 0 26 12770.200 12770.143 .057 41 3 38 41 2 39 12883.980 12883.954 .026 9 3 7 9 2 8 12921.590 12921.519 .071 22 2 21 22 1 22 12927.950 12927.955 -.005 43 4 39 43 3 40 12933.790 12933.728 .062 44 4 40 44 3 41 12938.730 12938.682 .048 10 3 8 10 2 9 12941.830 12941.789 .041 11 3 9 11 2 10 12968.630 12968.585 .045 42 4 38 42 3 39 12980.780 12980.759 .021 45 4 41 45 3 42 12998.890 12998.809 .081 13 3 11 13 2 12 13046.320 13046.297 .023 41 4 37 41 3 38 13076.120 13076.074 .046 46 4 42 46 3 43 13116.850 13116.786 .064 15 3 13 15 2 14 13164.070 13164.007 .063 40 4 36 40 3 37 13215.500 13215.470 .030 16 3 14 16 2 15 13240.900 13240.817 .083 34 2 32 34 1 33 13249.000 13248.912 .088 47 4 43 47 3 44 13294.830 13294.776 .054 17 3 15 17 2 16 13331.300 13331.142 .158 Table I - continued (2) J’ K’a K’c J Ka Kc observed calculated o - c 39 4 35 39 3 36 13394.290 13394.263 .027 23 2 22 23 1 23 13395.970 13395.949 .021 18 3 16 18 2 17 13436.000 13436.096 -.096 42 3 39 42 2 40 13487.220 13487.222 -.002 27 1 26 27 0 27 13520.990 13520.932 .058 48 4 44 48 3 45 13534.460 13534.411 .049 19 3 17 19 2 18 13556.690 13556.738 -.048 38 4 34 38 3 35 13607.310 13607.328 -.018 20 3 18 20 2 19 13694.040 13694.068 -.028 49 4 45 49 3 46 13836.800 13836.769 .031 24 2 23 24 1 24 13880.620 13880.681 -.061 35 2 33 35 1 34 14007.340 14007.264 .076 22 3 20 22 2 21 14022.360 14022.392 -.032 43 3 40 43 2 41 14138.760 14138.788 -.028 50 4 46 50 3 47 14202.380 14202.330 .050 23 3 21 23 2 22 14214.920 14214.965 -.045 28 1 27 28 0 28 14272.990 14272.970 .020 35 4 31 35 3 32 14396.100 14395.983 .117 24 3 22 24 2 23 14427.360 14427.369 -.009 25 3 23 25 2 24 14660.120 14660.134 -.014 34 4 30 34 3 31 14689.200 14689.088 .112 36 2 34 36 1 35 14785.880 14785.840 .040 44 3 41 44 2 42 14834.840 14834.942 -.102 26 2 25 26 1 26 14896.720 14896.795 -.075 26 3 24 26 2 25 14913.630 14913.680 -.050 33 4 29 33 3 30 14987.620 14987.535 .085 29 1 28 29 0 29 15023.590 15023.547 .043 27 3 25 27 2 26 15188.300 15188.308 -.008 32 4 28 32 3 29 15285.850 15285.788 .062 28 3 26 28 2 27 15484.180 15484.197 -.017 31 4 27 31 3 28 15578.830 15578.733 .097 37 2 35 37 1 36 15579.810 15579.761 .049 30 1 29 30 0 30 15770.520 15770.494 .026 29 3 27 29 2 28 15801.380 15801.406 -.026 30 4 26 30 3 27 15861.840 15861.807 .033 28 2 27 28 1 28 15968.660 15968.793 -.133 29 4 25 29 3 26 16131.160 16131.113 .047 30 3 28 30 2 29 16139.820 16139.870 -.050 46 3 43 46 2 44 16343.380 16343.224 .156 28 4 24 28 3 25 16383.600 16383.499 .101 38 2 36 38 1 37 16384.340 16384.308 .032 31 3 29 31 2 30 16499.390 16499.403 -.013 31 1 30 31 0 31 16512.230 16512.177 .053 29 2 28 29 1 29 16523.180 16523.307 -.127 Table I - continued (3) J’ K’a K’c J Ka Kc observed calculated o - c 27 4 23 27 3 24 16616.700 16616.608 .092 26 4 22 26 3 23 16828.960 16828.888 .072 32 3 30 32 2 31 16879.670 16879.705 -.035 30 2 29 30 1 30 17088.710 17088.857 -.147 47 3 44 47 2 45 17145.410 17145.323 .087 24 4 20 24 3 21 17188.510 17188.568 -.058 39 2 37 39 1 38 17195.110 17195.067 .043 32 1 31 32 0 32 17247.500 17247.464 .036 33 3 31 33 2 32 17280.290 17280.360 -.070 23 4 19 23 3 20 17336.440 17336.441 -.001 22 4 18 22 3 19 17464.220 17464.219 .001 21 4 17 21 3 18 17573.340 17573.305 .035 20 4 16 20 3 17 17665.400 17665.344 .056 34 3 32 34 2 33 17700.800 17700.847 -.047 19 4 15 19 3 16 17742.150 17742.112 .038 18 4 14 18 3 15 17805.480 17805.425 .055 17 4 13 17 3 14 17857.110 17857.056 .054 16 4 12 16 3 13 17898.710 17898.688 .022 15 4 11 15 3 12 17931.900 17931.871 .029 14 4 10 14 3 11 17958.070 17958.005 .065 33 1 32 33 0 33 17975.690 17975.667 .023 11 4 7 11 3 8 18005.790 18005.712 .078 40 2 38 40 1 39 18008.110 18008.045 .065 35 3 33 35 2 34 18140.490 18140.547 -.057 2 2 1 1 1 0 18826.190 18826.231 -.041 2 2 0 1 1 1 18866.590 18866.472 .118 3 1 3 2 0 2 19133.000 19132.983 .017 4 0 4 3 1 3 19771.070 19770.966 .104 3 2 2 2 1 1 24344.970 24344.979 -.009 3 2 1 2 1 2 24466.700 24466.623 .077 4 1 4 3 0 3 24612.820 24612.896 -.076 Millimetre-wave transitions (present work) J’ K’a K’c J Ka Kc observed calculated o - c 55 20 35 55 19 36 100005.112 100005.113 -.001 18 10 8 17 10 7 100034.158 100034.157 .001 18 9 9 17 9 8 100038.199 100038.194 .005 18 8 10 17 8 9 100042.373 100042.355 .018 18 7 11 17 7 10 100046.910 100046.918 -.008 Table I - continued (4) J’ K’a K’c J Ka Kc observed calculated o - c 18 4 14 17 4 13 100073.940 100073.924 .016 18 3 16 17 3 15 100076.571 100076.558 .013 50 20 30 50 19 31 100110.020 100109.998 .022 20 2 18 19 3 17 100229.206 100229.214 -.008 40 20 20 40 19 21 100283.267 100283.261 .006 37 20 17 37 19 18 100326.428 100326.427 .001 18 1 18 17 0 17 100328.938 100328.942 -.004 30 20 10 30 19 11 100412.494 100412.488 .006 20 20 0 20 19 1 100502.110 100502.107 .003 130 21 109 130 20 110 101378.192 101378.213 -.021 129 21 108 129 20 109 101466.614 101466.608 .006 128 21 107 128 20 108 101553.595 101553.588 .007 127 21 106 127 20 107 101639.198 101639.176 .022 126 21 105 126 20 106 101723.392 101723.391 .001 125 21 104 125 20 105 101806.258 101806.255 .003 120 21 99 120 20 100 102200.988 102200.984 .004 115 21 94 115 20 95 102564.772 102564.767 .005 110 21 89 110 20 90 102899.755 102899.765 -.010 105 21 84 105 20 85 103207.959 103207.960 -.001 100 21 79 100 20 80 103491.166 103491.171 -.005 99 21 79 99 20 80 103544.965 103544.965 .000 90 21 69 90 20 70 103989.242 103989.223 .019 80 21 59 80 20 60 104405.849 104405.847 .002 10 10 0 9 9 1 104529.712 104529.722 -.010 19 0 19 18 1 18 104580.810 104580.817 -.007 70 21 49 70 20 50 104751.222 104751.221 .001 18 2 17 17 1 16 104876.208 104876.210 -.002 11 9 2 10 8 3 104932.331 104932.341 -.010 60 21 39 60 20 40 105033.997 105034.007 -.010 19 1 19 18 1 18 105122.054 105122.030 .024 37 19 18 36 20 17 105124.713 105124.711 .002 19 0 19 18 0 18 105211.602 105211.618 -.016 50 21 29 50 20 30 105261.518 105261.520 -.002 38 20 18 37 21 17 105514.109 105514.105 .004 19 2 18 18 2 17 105515.556 105515.522 .034 19 10 10 18 10 9 105590.718 105590.717 .001 19 9 10 18 9 9 105595.104 105595.108 -.004 28 21 7 28 20 8 105595.695 105595.694 .001 19 8 11 18 8 10 105599.691 105599.684 .007 27 21 7 27 20 8 105606.018 105606.017 .001 19 6 14 18 6 13 105610.988 105610.996 -.008 19 5 14 18 5 13 105619.748 105619.791 -.043 24 21 3 24 20 4 105634.627 105634.627 .000 19 3 17 18 3 16 105636.192 105636.165 .027 Table I - continued (5) J’ K’a K’c J Ka Kc observed calculated o - c 21 21 0 21 20 1 105659.742 105659.757 -.015 19 3 16 18 3 15 105699.579 105699.605 -.026 19 1 19 18 0 18 105752.824 105752.831 -.007 19 1 18 18 1 17 105814.334 105814.370 -.036 19 2 17 18 2 16 105900.826 105900.783 .043 39 21 18 38 22 17 105901.757 105901.755 .002 22 1 22 21 2 19 106012.467 106012.451 .016 21 2 19 20 3 18 106102.098 106102.094 .004 17 3 15 16 2 14 106487.220 106487.216 .004 17 2 15 16 1 16 106510.921 106510.910 .011 20 1 19 19 2 18 107047.446 107047.443 .003 22 2 21 21 3 18 107868.771 107868.762 .009 17 3 14 16 2 15 107883.002 107882.983 .019 35 16 20 34 17 17 109508.579 109508.575 .004 36 17 20 35 18 17 109902.480 109902.492 -.012 19 2 18 18 1 17 110126.467 110126.466 .001 61 22 39 61 21 40 110154.788 110154.787 .001 20 0 20 19 1 19 110183.064 110183.065 -.001 59 22 37 59 21 38 110206.603 110206.604 -.001 37 18 20 36 19 17 110295.059 110295.054 .005 39 20 20 38 21 17 111075.599 111075.598 .001 20 1 20 19 0 19 111186.012 111186.014 -.002 40 21 20 39 22 17 111463.340 111463.342 -.002 18 3 16 17 2 15 111835.625 111835.629 -.004 41 22 20 40 23 17 111849.257 111849.252 .005 22 2 20 21 3 19 111997.117 111997.116 .001 42 23 20 41 24 17 112233.217 112233.221 -.004 43 24 20 42 25 17 112615.143 112615.144 -.001 18 2 16 17 1 17 112752.400 112752.402 -.002 21 1 20 20 2 19 112890.104 112890.105 -.001 44 25 20 43 26 17 112994.914 112994.919 -.005 23 2 22 22 3 19 113107.868 113107.856 .012 45 26 20 44 27 17 113372.448 113372.446 .002 18 3 15 17 2 16 113582.336 113582.335 .001 46 27 20 45 28 17 113747.626 113747.626 .000 99 23 77 99 22 78 113828.325 113828.320 .005 47 28 20 46 29 17 114120.353 114120.361 -.008 90 23 67 90 22 68 114266.241 114266.238 .003 48 29 20 47 30 17 114490.538 114490.554 -.016 80 23 57 80 22 58 114683.691 114683.691 .000 70 23 47 70 22 48 115035.577 115035.576 .001 60 23 37 60 22 38 115328.295 115328.297 -.002 20 2 19 19 1 18 115370.003 115369.998 .005 53 23 30 53 22 31 115500.937 115500.948 -.011 Table I - continued (6) J’ K’a K’c J Ka Kc observed calculated o - c 43 23 20 43 22 21 115705.081 115705.080 .001 39 23 16 39 22 17 115773.516 115773.510 .006 21 0 21 20 1 20 115774.680 115774.681 -.001 33 23 10 33 22 11 115862.698 115862.670 .028 23 23 0 23 22 1 115976.807 115976.800 .007 21 1 21 20 0 20 116628.327 116628.327 .000 34 0 34 33 3 31 151722.306 151722.279 .027 105 31 74 105 30 75 154445.593 154445.598 -.005 99 31 68 99 30 69 154802.484 154802.491 -.007 23 3 21 22 0 22 155149.413 155149.401 .012 86 31 55 86 30 56 155492.735 155492.748 -.013 73 31 42 73 30 43 156074.607 156074.622 -.015 35 1 34 34 4 31 156835.008 156834.994 .014 49 31 18 49 30 19 156881.799 156881.805 -.006 35 31 4 35 30 5 157201.081 157201.078 .003 31 31 0 31 30 1 157272.504 157272.500 .004 33 2 32 32 3 29 162306.632 162306.616 .016 52 24 28 51 25 27 162671.225 162671.221 .004 29 2 28 28 1 27 162672.543 162672.542 .001 28 3 26 27 2 25 163980.638 163980.629 .009 26 2 24 25 1 25 164801.921 164801.937 -.016 30 1 29 29 2 28 164996.985 164996.979 .006 31 2 29 30 3 28 165704.204 165704.200 .004 30 0 30 29 1 29 165749.801 165749.792 .009 30 1 30 29 0 29 165917.642 165917.620 .022 30 2 29 29 2 28 166391.144 166391.150 -.006 27 3 24 26 2 25 166641.664 166641.673 -.009 35 5 31 34 6 28 166642.410 166642.412 -.002 37 1 36 36 4 33 166806.389 166806.410 -.021 34 2 33 33 3 30 166862.946 166862.945 .001 30 2 28 29 2 27 167177.741 167177.742 -.001 25 3 23 24 0 24 167519.577 167519.611 -.034 30 2 29 29 1 28 167982.915 167982.931 -.016 24 4 21 23 1 22 168762.355 168762.364 -.009 29 3 27 28 2 26 169094.863 169094.857 .006 38 0 38 37 3 35 169553.926 169553.988 -.062 99 34 66 99 33 67 170163.614 170163.618 -.004 90 34 56 90 33 57 170686.485 170686.483 .002 31 1 30 30 2 29 170700.841 170700.838 .003 80 34 46 80 33 47 171204.016 171204.025 -.009 61 32 30 60 33 27 171217.341 171217.338 .003 31 0 31 30 1 30 171277.526 171277.519 .007 31 1 31 30 1 30 171339.844 171339.838 .006 35 2 34 34 3 31 171353.001 171353.012 -.011 Table I - continued (7) J’ K’a K’c J Ka Kc observed calculated o - c 31 0 31 30 0 30 171353.305 171353.326 -.021 31 1 31 30 0 30 171415.658 171415.646 .012 27 2 25 26 1 26 171546.812 171546.809 .003 62 33 30 61 34 27 171578.745 171578.742 .003 70 34 36 70 33 37 171656.642 171656.646 -.004 38 1 37 37 4 34 171715.276 171715.297 -.021 31 2 30 30 2 29 171915.428 171915.463 -.035 63 34 30 62 35 27 171937.217 171937.212 .005 60 34 26 60 33 27 172046.007 172046.005 .002 31 1 30 30 1 29 172094.968 172095.009 -.041 31 25 6 30 25 5 172095.755 172095.765 -.010 31 23 8 30 23 7 172122.139 172122.158 -.019 31 21 11 30 21 10 172146.657 172146.612 .045 31 20 12 30 20 11 172158.128 172158.138 -.010 31 18 14 30 18 13 172179.866 172179.864 .002 31 15 16 30 15 15 172209.550 172209.547 .003 31 12 20 30 12 19 172237.062 172237.071 -.009 31 9 22 30 9 21 172266.617 172266.627 -.010 31 8 24 30 8 23 172278.960 172278.963 -.003 64 35 30 63 36 27 172292.673 172292.651 .022 31 6 26 30 6 25 172315.851 172315.873 -.022 31 6 25 30 6 24 172316.190 172316.195 -.005 31 5 27 30 5 26 172346.702 172346.709 -.007 31 5 26 30 5 25 172353.969 172353.949 .020 31 4 28 30 4 27 172370.220 172370.210 .010 50 34 16 50 33 17 172373.539 172373.525 .014 31 4 27 30 4 26 172462.833 172462.857 -.024 40 34 6 40 33 7 172640.418 172640.402 .016 65 36 30 64 37 27 172644.966 172644.962 .004 36 34 2 36 33 3 172730.423 172730.397 .026 31 3 28 30 3 27 172745.916 172745.931 -.015 34 34 0 34 33 1 172771.852 172771.832 .020 66 37 30 65 38 27 172994.044 172994.048 -.004 31 2 30 30 1 29 173309.625 173309.634 -.009 67 38 30 66 39 27 173339.822 173339.813 .009 122 35 87 122 34 88 173661.556 173661.584 -.028 68 39 29 67 40 27 173682.168 173682.164 .004 118 35 83 118 34 84 173971.768 173971.771 -.003 116 35 81 116 34 82 174122.448 174122.437 .011 25 4 22 24 1 23 174268.322 174268.352 -.030 114 35 79 114 34 80 174270.193 174270.179 .014 56 26 30 55 27 28 174554.541 174554.562 -.021 110 35 75 110 34 76 174556.947 174556.965 -.018 71 42 29 70 43 27 174687.766 174687.780 -.014 Table I - continued (8) J’ K’a K’c J Ka Kc observed calculated o - c 108 35 73 108 34 74 174696.033 174696.047 -.014 105 35 70 105 34 71 174899.324 174899.332 -.008 111 40 71 111 39 72 200045.390 200045.364 .026 69 35 34 68 36 32 200109.128 200109.155 -.027 36 6 31 35 6 30 200110.999 200110.967 .032 36 6 30 35 6 29 200112.628 200112.627 .001 36 5 32 35 5 31 200152.939 200152.949 -.010 36 4 33 35 4 32 200157.436 200157.439 -.003 36 5 31 35 5 30 200179.589 200179.614 -.025 36 2 35 35 1 34 200182.933 200182.936 -.003 44 1 43 43 4 40 200197.691 200197.722 -.031 109 40 69 109 39 70 200201.142 200201.138 .004 36 2 34 35 2 33 200392.495 200392.490 .005 70 36 34 69 37 32 200462.835 200462.828 .007 36 3 33 35 3 32 200667.755 200667.764 -.009 71 37 34 70 38 32 200813.321 200813.322 -.001 100 40 60 100 39 61 200865.180 200865.168 .012 42 2 41 41 3 38 201135.078 201135.063 .015 72 38 34 71 39 32 201160.552 201160.539 .013 37 2 35 36 3 34 201529.049 201529.055 -.006 90 40 50 90 39 51 201532.825 201532.844 -.019 74 40 34 73 41 32 201844.766 201844.754 .012 75 41 34 74 42 32 202181.535 202181.561 -.026 76 42 34 75 43 32 202514.669 202514.707 -.038 80 40 40 80 39 41 202127.781 202127.739 .042 30 4 27 29 1 28 202437.734 202437.723 .011 23 15 8 22 14 8 202470.756 202470.752 .004 70 40 30 70 39 31 202650.789 202650.811 -.022 77 43 34 76 44 32 202844.120 202844.097 .023 60 40 20 60 39 21 203102.907 203102.905 .002 78 44 34 77 45 32 203169.661 203169.639 .022 56 40 16 56 39 17 203264.044 203264.034 .010 25 13 12 24 12 12 203267.151 203267.160 -.009 50 40 10 50 39 11 203484.721 203484.745 -.024 79 45 34 78 46 32 203491.240 203491.237 .003 40 40 0 40 39 1 203796.927 203796.944 -.017 80 46 34 79 47 32 203808.839 203808.800 .039 81 47 34 80 48 32 204122.198 204122.233 -.035 37 0 37 36 1 36 204394.946 204394.939 .007 37 1 37 36 1 36 204413.504 204413.478 .026 37 0 37 36 0 36 204417.735 204417.717 .018 37 1 37 36 0 36 204436.262 204436.256 .006 37 1 36 36 2 35 204548.045 204548.044 .001 33 3 30 32 2 31 204576.114 204576.123 -.009 Table I - continued (9) J’ K’a K’c J Ka Kc observed calculated o - c 36 3 34 35 2 33 204774.430 204774.423 .007 45 1 44 44 4 41 204800.244 204800.190 .054 37 2 36 36 2 35 205031.316 205031.321 -.005 43 2 42 42 3 39 205194.297 205194.308 -.011 37 33 4 36 33 3 205224.742 205224.735 .007 37 32 5 36 32 4 205245.772 205245.725 .047 37 28 9 36 28 8 205323.577 205323.578 -.001 37 18 19 36 18 18 205477.729 205477.747 -.018 37 2 36 36 1 35 205600.353 205600.344 .009 37 2 35 36 2 34 205911.018 205910.987 .031 62 41 21 62 40 22 208202.681 208202.702 -.021 57 42 15 57 41 16 213607.032 213607.056 -.024 40 2 39 39 1 38 221917.832 221917.830 .002 21 21 0 20 20 0 222303.235 222303.226 .009 23 19 4 22 18 4 223080.785 223080.783 .002 24 18 6 23 17 6 223472.465 223472.472 -.007 68 44 24 68 43 25 223479.039 223479.011 .028 25 17 8 24 16 8 223865.930 223865.930 .000 60 44 16 60 43 17 223868.953 223868.947 .006 26 16 10 25 15 10 224261.007 224260.998 .009 27 15 12 26 14 12 224657.482 224657.473 .009 28 14 14 27 13 14 225055.073 225055.076 -.003 41 2 39 40 3 38 225060.043 225060.034 .010 40 3 38 39 2 37 225322.692 225322.704 -.012 29 13 16 28 12 16 225453.406 225453.391 .015 30 12 18 29 11 18 225851.755 225851.756 -.001 31 11 20 30 10 20 226249.045 226249.041 .004 41 0 41 40 1 40 226443.804 226443.797 .007 41 1 41 40 1 40 226451.860 226451.830 .030 41 0 41 40 0 40 226453.718 226453.715 .003 41 1 41 40 0 40 226461.762 226461.748 .014 32 10 22 31 9 22 226643.186 226643.182 .004 41 1 40 40 2 39 226840.216 226840.210 .006 33 9 24 32 8 24 227030.134 227030.133 .001 41 2 40 40 1 39 227374.774 227374.780 -.006 22 21 1 21 20 1 227847.924 227847.931 -.007 23 20 3 22 19 3 228235.791 228235.805 -.014 24 19 5 23 18 5 228625.687 228625.694 -.007 25 18 7 24 17 7 229017.474 229017.476 -.002 55 0 55 54 1 54 303513.507 303513.498 .009 55 1 55 54 0 54 303514.369 303514.356 .013 56 0 56 55 1 55 309013.235 309013.241 -.006 56 1 56 55 0 55 309013.956 309013.928 .028 56 1 55 55 2 54 309644.136 309644.128 .008 Table I - continued (10) J’ K’a K’c J Ka Kc observed calculated o - c 56 2 55 55 1 54 309675.417 309675.430 -.013 36 22 14 35 21 14 310548.158 310548.183 -.025 56 3 54 55 2 53 310620.244 310620.240 .004 57 0 57 56 1 56 314512.250 314512.272 -.022 57 1 57 56 0 56 314512.841 314512.822 .019 57 1 56 56 2 55 315145.612 315145.624 -.012 57 2 56 56 1 55 315171.230 315171.232 -.002 58 0 58 57 1 57 320010.581 320010.582 -.001 58 1 58 57 0 57 320011.039 320011.021 .018 58 1 57 57 2 56 320645.964 320645.921 .043 58 2 57 57 1 56 320666.824 320666.850 -.026 59 1 59 58 0 58 325508.501 325508.512 -.011 35 26 9 34 25 9 325615.563 325615.575 -.012 59 2 58 58 1 57 326162.170 326162.180 -.010 60 1 59 59 2 58 331643.192 331643.204 -.012 60 2 59 59 1 58 331657.127 331657.137 -.010 61 1 60 60 2 59 337140.301 337140.295 .006 61 2 60 60 1 59 337151.643 337151.646 -.003 62 1 61 61 2 60 342636.413 342636.404 .009 62 2 61 61 1 60 342645.626 342645.644 -.018 63 1 62 62 2 61 348131.550 348131.561 -.011 63 2 62 62 1 61 348139.070 348139.074 -.004 Table II Analysed transition frequencies (MHz) of HFC 134a in the first torsional state Stark-modulation measurements from Ref. (2) J’ K’a K’c J Ka Kc observed calculated o - c 15 3 12 15 2 13 12363.260 12363.227 .033 14 3 11 14 2 12 12470.120 12470.066 .054 23 2 22 23 1 23 12516.420 12516.496 -.076 28 1 27 28 0 28 12555.940 12555.854 .086 13 3 10 13 2 11 12560.930 12560.884 .046 44 3 41 44 2 42 12570.530 12570.477 .053 36 2 34 36 1 35 12576.640 12576.528 .112 12 3 9 12 2 10 12636.390 12636.379 .011 11 3 8 11 2 9 12697.760 12697.640 .120 10 3 7 10 2 8 12746.110 12746.049 .061 9 3 6 9 2 7 12783.280 12783.181 .099 8 3 5 8 2 6 12810.820 12810.703 .117 7 3 4 7 2 5 12830.430 12830.293 .137 7 3 5 7 2 6 12871.210 12871.353 -.143 8 3 6 8 2 7 12878.850 12878.747 .103 47 4 43 47 3 44 12901.090 12900.996 .094 10 3 8 10 2 9 12903.980 12903.894 .086 48 4 44 48 3 45 12916.040 12916.010 .030 11 3 9 11 2 10 12923.150 12923.197 -.047 46 4 42 46 3 43 12930.840 12930.793 .047 24 2 23 24 1 24 12932.050 12932.019 .031 12 3 10 12 2 11 12948.160 12948.100 .060 49 4 45 49 3 46 12978.340 12978.243 .097 13 3 11 13 2 12 12979.550 12979.484 .066 14 3 12 14 2 13 13018.290 13018.253 .037 15 3 13 15 2 14 13065.390 13065.328 .062 50 4 46 50 3 47 13089.800 13089.737 .063 44 4 40 44 3 41 13113.390 13113.346 .044 16 3 14 16 2 15 13121.720 13121.636 .084 17 3 15 17 2 16 13188.180 13188.097 .083 29 1 28 29 0 29 13245.080 13245.017 .063 37 2 35 37 1 36 13252.540 13252.519 .021 43 4 39 43 3 40 13259.490 13259.463 .027 18 3 16 18 2 17 13265.780 13265.617 .163 25 2 24 25 1 25 13362.360 13362.371 -.011 42 4 38 42 3 39 13437.180 13437.146 .034 20 3 18 20 2 19 13457.290 13457.330 -.040 21 3 19 21 2 20 13573.180 13573.182 -.002 2 1 2 1 0 1 13632.180 13632.175 .005 41 4 37 41 3 38 13642.230 13642.268 -.038 Table II - continued (1) J’ K’a K’c J Ka Kc observed calculated o - c 46 3 43 46 2 44 13671.020 13671.011 .009 22 3 20 22 2 21 13703.380 13703.392 -.012 26 2 25 26 1 26 13806.890 13806.910 -.020 40 4 36 40 3 37 13870.300 13870.461 -.161 30 1 29 30 0 30 13936.160 13936.095 .065 38 2 36 38 1 37 13949.710 13949.626 .084 24 3 22 24 2 23 14009.610 14009.637 -.027 39 4 35 39 3 36 14117.340 14117.180 .160 25 3 23 25 2 24 14186.890 14186.885 .005 27 2 26 27 1 27 14264.910 14264.952 -.042 47 3 44 47 2 45 14282.480 14282.501 -.021 38 4 34 38 3 35 14377.890 14377.790 .100 27 3 25 27 2 26 14592.110 14592.124 -.014 31 1 30 31 0 31 14626.830 14626.823 .007 37 4 33 37 3 34 14647.730 14647.653 .077 39 2 37 39 1 38 14664.070 14664.030 .040 28 2 27 28 1 28 14735.700 14735.781 -.081 28 3 26 28 2 27 14820.860 14820.876 -.016 36 4 32 36 3 33 14922.300 14922.229 .071 48 3 45 48 2 46 14930.820 14930.905 -.085 29 3 27 29 2 28 15067.420 15067.418 .002 35 4 31 35 3 32 15197.220 15197.172 .048 29 2 28 29 1 29 15218.560 15218.657 -.097 32 1 31 32 0 32 15315.350 15315.319 .031 30 3 28 30 2 29 15331.900 15331.921 -.021 40 2 38 40 1 39 15391.990 15391.915 .075 34 4 30 34 3 31 15468.470 15468.430 .040 31 3 29 31 2 30 15614.470 15614.467 .003 33 4 29 33 3 30 15732.380 15732.329 .051 32 3 30 32 2 31 15914.990 15915.049 -.059 32 4 28 32 3 29 15985.740 15985.655 .085 33 1 32 33 0 33 16000.130 16000.090 .040 31 2 30 31 1 31 16217.400 16217.510 -.110 31 4 27 31 3 28 16225.750 16225.710 .040 33 3 31 33 2 32 16233.550 16233.575 -.025 30 4 26 30 3 27 16450.410 16450.361 .049 34 3 32 34 2 33 16569.850 16569.866 -.016 29 4 25 29 3 26 16658.100 16658.050 .050 28 4 24 28 3 25 16847.920 16847.798 .122 35 3 33 35 2 34 16923.650 16923.660 -.010 26 4 22 26 3 23 17172.160 17172.213 -.053 36 3 34 36 2 35 17294.570 17294.616 -.046 25 4 21 25 3 22 17307.410 17307.419 -.009 24 4 20 24 3 21 17425.590 17425.611 -.021 23 4 19 23 3 20 17527.910 17527.879 .031 22 4 18 22 3 19 17615.560 17615.493 .067 Table II - continued (2) J’ K’a K’c J Ka Kc observed calculated o - c 37 3 35 37 2 36 17682.280 17682.315 -.035 21 4 17 21 3 18 17689.800 17689.828 -.028 20 4 16 20 3 17 17752.320 17752.296 .024 19 4 15 19 3 16 17804.390 17804.300 .090 18 4 14 18 3 15 17847.200 17847.185 .015 17 4 13 17 3 14 17882.270 17882.216 .054 16 4 12 16 3 13 17910.590 17910.552 .038 15 4 11 15 3 12 17933.280 17933.242 .038 14 4 10 14 3 11 17951.260 17951.221 .039 13 4 9 13 3 10 17965.450 17965.305 .145 38 3 36 38 2 37 18086.210 18086.271 -.061 2 2 0 1 1 1 18844.280 18844.212 .068 3 1 3 2 0 2 19136.890 19136.993 -.103 4 0 4 3 1 3 19745.150 19745.045 .105 3 2 2 2 1 1 24331.540 24331.677 -.137 4 1 4 3 0 3 24625.460 24625.471 -.011 Millimetre-wave transitions (present work) J’ K’a K’c J Ka Kc observed calculated o - c 18 4 15 17 4 14 100002.290 100002.322 -.032 18 4 14 17 4 13 100003.519 100003.507 .012 18 3 16 17 3 15 100008.268 100008.269 -.001 18 3 15 17 3 14 100038.536 100038.537 -.001 45 20 25 45 19 26 100044.966 100044.967 -.001 12 7 5 11 6 5 100089.490 100089.500 -.010 18 1 17 17 1 16 100190.581 100190.577 .004 18 2 16 17 2 15 100192.578 100192.583 -.005 25 7 18 24 8 16 100334.804 100334.798 .006 13 6 7 12 5 7 100498.020 100498.037 -.017 18 1 18 17 0 17 100499.059 100499.069 -.010 19 1 18 18 2 17 100712.201 100712.198 .003 26 8 18 25 9 16 100736.785 100736.780 .005 14 5 10 13 4 9 100903.943 100903.956 -.013 14 5 9 13 4 10 100904.184 100904.210 -.026 27 9 18 26 10 16 101140.428 101140.420 .008 16 3 14 15 2 13 101221.668 101221.673 -.005 15 4 12 14 3 11 101283.851 101283.861 -.010 15 4 11 14 3 12 101309.481 101309.485 -.004 28 10 18 27 11 16 101544.701 101544.695 .006 29 11 18 28 12 16 101949.003 101948.998 .005 Table II - continued (3) J’ K’a K’c J Ka Kc observed calculated o - c 115 21 94 115 20 95 102579.365 102579.361 .004 31 13 18 30 14 16 102756.204 102756.200 .004 110 21 89 110 20 90 102879.930 102879.920 .010 106 21 85 106 20 86 103104.703 103104.690 .013 104 21 83 104 20 84 103212.090 103212.074 .016 100 21 79 100 20 80 103417.243 103417.227 .016 33 15 18 32 16 16 103559.930 103559.925 .005 95 21 74 95 20 75 103656.390 103656.392 -.002 90 21 69 90 20 70 103877.373 103877.363 .010 85 21 64 85 20 65 104081.149 104081.141 .008 80 21 59 80 20 60 104268.651 104268.652 -.001 35 17 18 34 18 16 104358.810 104358.808 .002 10 10 0 9 9 0 104418.037 104418.040 -.003 75 21 54 75 20 55 104440.764 104440.757 .007 19 0 19 18 1 18 104458.541 104458.536 .005 70 21 49 70 20 50 104598.255 104598.250 .005 65 21 44 65 20 45 104741.868 104741.862 .006 62 21 41 62 20 42 104821.658 104821.651 .007 11 9 2 10 8 2 104825.254 104825.261 -.007 60 21 39 60 20 40 104872.276 104872.270 .006 55 21 34 55 20 35 104990.092 104990.091 .001 51 21 30 51 20 31 105075.671 105075.665 .006 50 21 29 50 20 30 105095.895 105095.888 .007 49 21 28 49 20 29 105115.656 105115.651 .005 37 19 18 36 20 16 105151.780 105151.776 .004 43 21 22 43 20 23 105224.769 105224.768 .001 12 8 4 11 7 4 105233.307 105233.317 -.010 40 21 19 40 20 20 105273.405 105273.405 .000 35 21 14 35 20 15 105345.995 105345.993 .002 30 21 9 30 20 10 105408.301 105408.297 .004 25 21 4 25 20 5 105460.637 105460.628 .009 22 21 1 22 20 2 105487.347 105487.351 -.004 21 2 19 20 3 18 105523.187 105523.180 .007 17 2 15 16 1 16 105615.473 105615.475 -.002 52 35 17 51 36 15 105617.797 105617.797 .000 19 1 19 18 0 18 105920.492 105920.490 .002 39 21 18 38 22 16 105937.880 105937.890 -.010 20 1 19 19 2 18 106527.348 106527.335 .013 17 3 15 16 2 14 106638.040 106638.043 -.003 41 23 18 40 24 16 106716.279 106716.280 -.001 22 1 22 21 2 19 107561.793 107561.770 .023 17 3 14 16 2 15 107650.685 107650.693 -.008 45 27 18 44 28 16 108246.572 108246.580 -.008 22 2 21 21 3 18 108265.833 108265.823 .010 47 29 18 46 30 16 108996.871 108996.883 -.012 90 22 68 90 21 69 108997.704 108997.693 .011 Table II - continued (4) J’ K’a K’c J Ka Kc observed calculated o - c 20 0 20 19 1 19 110072.022 110072.021 .001 50 32 18 49 33 16 110101.556 110101.566 -.010 50 22 28 50 21 29 110239.153 110239.150 .003 19 2 18 18 1 17 110504.230 110504.233 -.003 20 16 4 19 16 3 111046.466 111046.471 -.005 20 15 5 19 15 4 111052.231 111052.213 .018 20 10 10 19 10 9 111076.904 111076.890 .014 20 7 13 19 7 12 111090.695 111090.685 .010 20 6 14 19 6 13 111096.426 111096.415 .011 53 35 18 52 36 16 111178.975 111178.990 -.015 20 1 20 19 0 19 111349.466 111349.474 -.008 22 2 20 21 3 19 111350.726 111350.707 .019 54 36 18 53 37 16 111531.613 111531.624 -.011 18 2 16 17 1 17 111720.765 111720.758 .007 18 3 16 17 2 15 112032.379 112032.384 -.005 126 23 103 126 22 104 112096.158 112096.130 .028 125 23 102 125 22 103 112166.219 112166.212 .007 23 1 23 22 2 20 112297.608 112297.586 .022 123 23 100 123 22 101 112303.691 112303.704 -.013 21 1 20 20 2 19 112344.891 112344.874 .017 17 4 14 16 3 13 112355.052 112355.052 .000 122 23 99 122 22 100 112371.127 112371.134 -.007 121 23 98 121 22 99 112437.700 112437.697 .003 120 23 97 120 22 98 112503.400 112503.402 -.002 119 23 96 119 22 97 112568.279 112568.259 .020 118 23 95 118 22 96 112632.259 112632.276 -.017 117 23 94 117 22 95 112695.449 112695.461 -.012 116 23 93 116 22 94 112757.827 112757.822 .005 115 23 92 115 22 93 112819.350 112819.369 -.019 114 23 91 114 22 92 112880.071 112880.108 -.037 113 23 90 113 22 91 112940.083 112940.047 .036 112 23 89 112 22 90 112999.187 112999.195 -.008 111 23 88 111 22 89 113057.556 113057.560 -.004 110 23 87 110 22 88 113115.135 113115.148 -.013 105 23 82 105 22 83 113391.703 113391.708 -.005 23 2 22 22 3 19 113595.645 113595.649 -.004 101 23 78 101 22 79 113599.723 113599.726 -.003 95 23 72 95 22 73 113890.707 113890.712 -.005 90 23 67 90 22 68 114114.776 114114.780 -.004 85 23 62 85 22 63 114322.881 114322.881 .000 80 23 57 80 22 58 114515.690 114515.695 -.005 75 23 52 75 22 53 114693.854 114693.852 .002 70 23 47 70 22 48 114857.937 114857.938 -.001 65 23 42 65 22 43 115008.490 115008.494 -.004 60 23 37 60 22 38 115146.036 115146.017 .019 55 23 32 55 22 33 115270.961 115270.966 -.005 Table II - continued (5) J’ K’a K’c J Ka Kc observed calculated o - c 50 23 27 50 22 28 115383.747 115383.758 -.011 45 23 22 45 22 23 115484.766 115484.772 -.006 40 23 17 40 22 18 115574.343 115574.348 -.005 35 23 12 35 22 13 115652.791 115652.792 -.001 21 0 21 20 1 20 115675.919 115675.923 -.004 30 23 7 30 22 8 115720.357 115720.369 -.012 25 23 2 25 22 3 115777.313 115777.310 .003 20 2 19 19 1 18 115780.165 115780.177 -.012 23 23 0 23 22 1 115797.150 115797.154 -.004 50 24 26 49 25 24 151569.875 151569.859 .016 51 25 26 50 26 24 151955.238 151955.238 .000 120 31 89 120 30 90 153198.425 153198.418 .007 55 29 26 54 30 24 153473.226 153473.232 -.006 116 31 85 116 30 86 153477.400 153477.408 -.008 115 31 84 115 30 85 153545.429 153545.441 -.012 56 30 26 55 31 24 153846.328 153846.328 .000 110 31 79 110 30 80 153875.451 153875.459 -.008 107 31 76 107 30 77 154065.456 154065.439 .017 104 31 73 104 30 74 154249.477 154249.477 .000 101 31 70 101 30 71 154427.598 154427.634 -.036 100 31 69 100 30 70 154485.699 154485.724 -.025 95 31 64 95 30 65 154766.557 154766.550 .007 90 31 59 90 30 60 155031.554 155031.529 .025 60 34 26 59 35 24 155310.062 155310.059 .003 28 2 27 27 2 26 155312.810 155312.817 -.007 81 31 50 81 30 51 155469.329 155469.334 -.005 80 31 49 80 30 50 155514.917 155514.918 -.001 75 31 44 75 30 45 155733.778 155733.775 .003 70 31 39 70 30 40 155937.688 155937.681 .007 60 31 29 60 30 30 156301.378 156301.373 .005 63 37 26 62 38 24 156375.018 156375.008 .010 51 31 20 51 30 21 156579.300 156579.291 .009 50 31 19 50 30 20 156607.293 156607.320 -.027 40 31 9 40 30 10 156856.644 156856.634 .010 39 31 8 39 30 9 156878.503 156878.487 .016 31 31 0 31 30 1 157033.356 157033.343 .013 65 39 26 64 40 24 157067.845 157067.870 -.025 66 40 26 65 41 24 157408.874 157408.881 -.007 69 43 26 68 44 24 158409.091 158409.080 .011 71 45 26 70 46 24 159055.910 159055.902 .008 73 47 26 72 48 24 159685.835 159685.858 -.023 69 42 27 68 43 25 163642.959 163642.913 .046 116 33 83 116 32 84 163644.073 163644.067 .006 70 43 27 69 44 25 163972.793 163972.777 .016 71 44 27 70 45 25 164298.640 164298.621 .019 72 45 27 71 46 25 164620.339 164620.349 -.010 Table II - continued (6) J’ K’a K’c J Ka Kc observed calculated o - c 97 33 64 97 32 65 164877.198 164877.194 .004 96 33 63 96 32 64 164935.483 164935.475 .008 73 46 27 72 47 25 164937.842 164937.867 -.025 20 11 9 19 10 9 165065.054 165065.055 -.001 74 47 27 73 48 25 165251.068 165251.081 -.013 85 33 52 85 32 53 165534.005 165534.005 .000 99 34 65 99 33 66 169869.069 169869.063 .006 88 34 54 88 33 55 170504.290 170504.297 -.007 76 34 42 76 33 43 171107.857 171107.858 -.001 52 34 18 52 33 19 172042.624 172042.630 -.006 46 34 12 46 33 13 172220.733 172220.736 -.003 37 34 3 37 33 4 172446.850 172446.846 .004 36 34 2 36 33 3 172468.952 172468.944 .008 35 34 1 35 33 2 172490.467 172490.439 .028 34 34 0 34 33 1 172511.364 172511.331 .033 37 3 34 36 3 33 205990.058 205990.044 .014 90 41 49 90 40 50 206329.109 206329.099 .010 85 41 44 85 40 45 206647.779 206647.752 .027 80 41 39 80 40 40 206948.006 206948.005 .001 70 41 29 70 40 30 207493.476 207493.520 -.044 65 41 24 65 40 25 207738.868 207738.876 -.008 49 12 37 48 13 35 207964.910 207964.901 .009 60 41 19 60 40 20 207966.015 207966.021 -.006 55 41 14 55 40 15 208174.992 208174.996 -.004 50 41 9 50 40 10 208365.792 208365.835 -.043 34 3 31 33 2 32 208435.085 208435.075 .010 48 41 7 48 40 8 208437.076 208437.100 -.024 45 41 4 45 40 5 208538.570 208538.571 -.001 41 41 0 41 40 1 208663.746 208663.746 .000 40 3 37 39 4 36 209812.207 209812.207 .000 38 1 37 37 2 36 209888.561 209888.581 -.020 38 0 38 37 1 37 209972.992 209973.001 -.009 38 1 38 37 0 37 210035.020 210035.031 -.011 70 34 36 69 35 34 210911.720 210911.753 -.033 98 42 56 98 41 57 210913.844 210913.864 -.020 38 16 22 37 16 21 210916.799 210916.749 .050 38 3 36 37 3 35 210962.858 210962.889 -.031 38 12 26 37 12 25 210963.801 210963.811 -.010 97 42 55 97 41 56 210986.605 210986.585 .020 38 10 28 37 10 27 210988.073 210988.099 -.026 37 3 35 36 2 34 211036.504 211036.503 .001 94 42 52 94 41 53 211200.187 211200.220 -.033 38 2 37 37 1 36 211332.979 211332.974 .005 38 2 36 37 2 35 211359.764 211359.728 .036 90 42 48 90 41 49 211474.523 211474.514 .009 87 42 45 87 41 46 211672.349 211672.333 .016 Table II - continued (7) J’ K’a K’c J Ka Kc observed calculated o - c 42 3 40 41 4 37 211875.538 211875.516 .022 59 22 37 58 23 35 211922.125 211922.111 .014 83 42 41 83 41 42 211925.602 211925.577 .025 39 2 37 38 3 36 212075.787 212075.767 .020 60 23 37 59 24 35 212313.242 212313.239 .003 74 38 36 73 39 34 212338.220 212338.216 .004 61 24 37 60 25 35 212702.618 212702.611 .007 46 1 45 45 4 42 212705.573 212705.563 .010 62 25 37 61 26 35 213090.078 213090.079 -.001 63 26 37 62 27 35 213475.538 213475.510 .028 44 42 2 44 41 3 213768.965 213768.970 -.005 64 27 37 63 28 35 213858.788 213858.773 .015 65 28 37 64 29 35 214239.760 214239.746 .014 35 3 32 34 2 33 214796.916 214796.903 .013 29 11 18 28 10 18 214974.838 214974.835 .003 39 0 39 38 1 38 215490.636 215490.631 .005 39 1 38 38 2 37 215498.005 215498.008 -.003 39 1 39 38 1 38 215513.889 215513.923 -.034 39 0 39 38 0 38 215518.758 215518.752 .006 39 1 39 38 0 38 215542.048 215542.045 .003 41 0 41 40 1 40 226521.927 226521.952 -.025 41 1 41 40 0 40 226557.105 226557.144 -.039 55 0 55 54 1 54 303639.190 303639.180 .010 55 1 55 54 0 54 303641.400 303641.405 -.005 56 0 56 55 1 55 309141.835 309141.907 -.072 56 1 56 55 0 55 309143.722 309143.724 -.002 56 1 55 55 2 54 309701.341 309701.333 .008 56 2 55 55 1 54 309775.746 309775.753 -.007 57 0 57 56 1 56 314643.912 314643.907 .005 57 1 57 56 0 56 314645.396 314645.389 .007 57 1 56 56 2 55 315208.972 315208.974 -.002 57 2 56 56 1 55 315271.109 315271.122 -.013 58 0 58 57 1 57 320145.166 320145.175 -.009 59 0 59 58 1 58 325645.691 325645.702 -.011 59 1 59 58 0 58 325646.665 325646.687 -.022 36 25 11 35 24 11 325668.601 325668.601 .000 59 1 58 58 2 57 326219.416 326219.403 .013 59 2 58 58 1 57 326262.563 326262.597 -.034 60 1 60 59 0 59 331146.305 331146.284 .021 60 1 59 59 2 58 331722.422 331722.444 -.022 60 2 59 59 1 58 331758.391 331758.395 -.004 61 0 61 60 1 60 336644.491 336644.507 -.016 61 1 61 60 0 60 336645.185 336645.159 .026 61 1 60 60 2 59 337224.174 337224.168 .006 61 2 60 60 1 59 337254.100 337254.061 .039 62 0 62 61 1 61 342142.768 342142.765 .003 Table II - continued (8) J’ K’a K’c J Ka Kc observed calculated o - c 62 1 62 61 0 61 342143.317 342143.296 .021 63 0 63 62 1 62 347640.243 347640.248 -.005 63 1 63 62 0 62 347640.716 347640.680 .036 63 1 62 62 2 61 348223.966 348223.976 -.010 63 2 62 62 1 61 348244.568 348244.582 -.014 21 1 16