APPENDIX: Rotational lines assigned in the visible region electronic band systems of CoO (cm-1) BAND 1 C4Delta7/2 - X4Delta7/2 (0,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 13952.76* 13948.87 4 13952.76* 13948.05* 13944.35* 5 13952.76* 13947.29* 13942.66 6 13952.65 13946.31 13940.87 7 13952.28* 13945.14 13938.82 8 13951.88 13943.90 13936.72 9 13951.31 13942.45 13934.40 10 13950.46 13931.92 11 13949.60 13929.29 12 13948.60 13926.57 13 13947.29* 13935.12 13923.64 14 13945.94 13932.71 13920.52 15 13944.35* 13917.35 16 13914.01 17 13910.44 BAND 3 C4Delta7/2 - X4Delta7/2 (1,0) J-1/2 R(J) Q(J) P(J) _________________________________ 4 14475.60* 14471.66 5 14475.60* 14470.23 14466.63 6 14469.14 14463.56 7 14475.24 14467.97 14461.57 8 14474.61 14459.41 9 14473.96 14457.07 10 14473.26 14454.55 11 14472.23 14451.96 12 14471.26 13 14446.24 14 14443.18 Weak band; Perturbation at very low J. J=3.5 is not found, and J=4.5 is out of place. The intensities indicate Omega = 7/2 BAND 5 C4Delta7/2 - X4Delta7/2 (2,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 15003.45* 15000.10 4 15003.45* 14999.08 14995.41 5 15003.11 14997.87 14993.43* 6 15002.53 14996.49 14991.30 7 15001.95 14995.09 14989.09 8 15001.18 14993.43 14986.54 9 14991.64 14983.91 10 14989.69 14981.09 11 14987.57 14978.15 12 14985.34 14975.00 13 14982.93 14971.75 14 14980.34 14968.44 15 14977.63 14964.86 16 14974.78 14961.04 17 14987.03 14971.75 14957.22 18 14984.71 14953.22 19 14982.13 14965.24 14949.06 20 14961.74 14944.68 21 14976.72 14958.12 22 14973.66 14954.33 BAND 6 A 9/2 fragment, interacting with level <5>; now deperturbed successfully by trial and error J-1/2 R(J) Q(J) P(J) _________________________________ 7 15007.68h 10 15006.96 11 15006.42 12 15005.67 13 15004.82 h=head BAND 7 D4Phi9/2 - X4Delta7/2 (1,0); very wide lines J-1/2 R(J) Q(J) P(J) _________________________________ 4 15223.62h 5 15217.10b 6 15223.16 15216.92b 7 15222.57* 15215.61* 8 15221.88 15213.94* 9 15220.96 15212.41 10 15219.90 15210.48b 11 15218.71 15208.32 12 15217.20 15206.11 13 15215.61* 15203.64 b = broad; h = head BAND 8 E4Delta7/2 - X4Delta7/2 (0,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 15244.04* 4 15244.04* 15239.46 5 15238.54 15234.00 6 15243.59 15237.40 15232.02 7 15243.10 15236.10 15229.85 8 15242.46 15234.51 15227.58 9 15241.69 15225.11 10 15240.54* 15231.21 15222.57* 11 15229.16 15219.70 13 15224.64 BAND 9 (643.6 nm) see A.G. Adam et al, J. Chem. Phys. 86, 5231 (1987) BANDS 10 and 19 see D.J. Clouthier et al, J. Chem. Phys. 99, 6336 (1993) BAND 11 (641.1 nm) see A.G. Adam et al, J. Chem. Phys. 86, 5231 (1987) BAND 12 F4Delta7/2 - X4Delta7/2 (0,0) J-1/2 R(J) Q(J) P(J) _________________________________ 8 15651.092 9 15650.083 15633.860 10 15648.951 15631.044 11 15647.608 15628.073 12 15646.096 15624.918 13 15644.405 15621.598 14 15642.522 15618.077 15 15640.453 15614.379 16 15638.219 15610.498 17 15635.802 15606.436 18 15633.233 15602.202 19 15630.516 15597.800 20 15627.690 15593.219 21 15624.822 15588.514 22 15618.756 15583.694 23 15615.642 15578.830 24 15612.155 15570.767 25 15608.371 15565.669 26 15604.328 15560.184 27 15600.066 15554.405 28 15595.602 15548.372 29 15542.131 30 15535.678 Large avoided crossing at J=23; no extra lines, but the constants for the perturbing level <12a> can be obtained from the curvature of the energy level plot. BAND 13 E4Delta5/2 - X4Delta5/2 (1,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 15689.427* 4 15689.427* 5 15689.251 15683.892 15681.240 6 15688.897 15682.764 15679.401 7 15688.347 15681.346 15677.340 8 15687.620 15679.771 15675.186 687.721 9 15686.708 15670.251 686.932 10 15685.352 15667.505 685.620 667.611 11 15684.095 15664.570 684.341 664.810 12 15682.618 15661.225 682.881 661.493 13 15680.945 15657.951 681.240 658.176 14 15679.102 15654.471 679.401 654.739 15 15677.072 15650.799 677.388 651.092 16 15674.821 15646.955 675.186 647.251 17 15672.398 15642.888 672.806 643.226 18 15669.771 15638.658 670.251 639.022 19 15667.011 15634.231 667.505 634.643 20 15664.052 15629.613 664.571 630.050 21 15660.921 15624.822 661.446 625.307 22 15657.610 15619.855 658.176 620.369 23 15654.164 15614.712 654.652 615.244 24 15650.590 15606.406 650.971 609.937 25 15646.955 15603.961 647.132 604.445 26 15643.103 15598.395 643.283 598.777 27 15638.891 15592.708 639.659 592.921 28 15634.517 15586.897 587.076 29 15629.969 15580.666 30 15625.259 15574.316 31 15620.410 15567.760 32 15615.417 15561.073 33 15610.338 15554.220 34 15605.193 15547.247 BAND 14 7/2(4Phi7/2) - X4Delta5/2; weak band J-1/2 R(J) Q(J) P(J) _________________________________ 6 15698.054 7 15697.564 8 15697.037 15689.036 9 15696.326 15687.443 10 15695.467 15685.736 11 15694.435 15683.892 15674.181 12 15693.196 15681.838 15671.357 13 15691.783 15679.622 15668.292 14 15690.187 15677.205 15665.038 15 15688.393 15674.598 15661.622 16 15686.425 15671.817 15658.016 17 15684.277 15668.855 15654.245 18 15681.923 15665.686 15650.265 19 15679.401 15662.339 15646.097 20 15676.649 15658.793 15641.739 21 15673.726 15655.062 15637.220 22 15670.611 15651.140 15632.461 23 15667.323 15647.032 15627.533 24 15663.827 15642.719 15622.418 25 15660.141 15638.219 15617.114 26 15656.262 15633.536 15611.618 27 15652.191 15628.660 15605.930 28 15647.929 15623.582 15600.065 29 15643.469 15618.320 15593.978 30 15638.820 15612.873 15587.729 31 15633.951 15607.222 15581.273 32 15628.935 15601.374 15574.633 33 15623.708 15595.334 15567.760 34 15618.270 15589.115 15560.753 BAND 15 E4Delta7/2 - X4Delta7/2 (1,0) J-1/2 R(J) Q(J) P(J) _________________________________ 8 15651.092 9 15650.083 15633.860 10 15648.951 15631.044 11 15647.608 15628.073 12 15646.096 15624.918 13 15644.405 15621.598 14 15642.522 15618.077 15 15640.453 15614.379 16 15638.219 15610.498 17 15635.802 15606.436 18 15633.233 15602.202 19 15630.516 15597.800 20 15627.690 15593.219 21 15624.822 15588.514 22 15618.756 15583.694 23 15615.642 15578.830 24 15612.155 15570.767 25 15608.371 15565.669 26 15604.328 15560.184 27 15600.066 15554.405 28 15595.602 15548.372 29 15542.131 30 15535.678 BAND 16 D4Phi9/2 - X4Delta7/2 (2,0) J-1/2 R(J) Q(J) P(J) _________________________________ 8 15836.476 9 15835.467 15826.970 10 15834.250 15824.960 11 15832.869 15822.751 15813.450 12 15831.313 15820.372 15810.240 13 15829.592 15817.808 15806.873 14 15827.690 15815.083 15803.297 15 15825.253 15812.152 15799.570 825.555 16 15823.091 15808.745 15795.647 823.300 809.050 17 15820.880 15805.600 15791.250 805.810 791.550 18 15818.245 15802.376 15787.076 787.300 19 15815.322 15798.746 15782.876 815.481 19 15815.616 815.688 20 15812.511 15794.818 15778.233 812.643 794.980 20 15794.113 794.189 21 15809.264 15791.014 809.413 791.132 22 15806.060 15786.759 786.918 23 15802.596 15782.570 24 778.105 Other components of BAND16 (631.3nm) J-1/2 R(J) Q(J) P(J) _________________________________ 7 15838.100 8 15829.592 837.541 9 15835.986 15827.409 836.822 828.026 10 15834.875 15825.480 835.928 826.310 11 15833.659 15823.370 834.875 824.428 12 15832.304 15821.174 15810.881 832.369 822.376 12 15833.647 13 15830.870 15818.791 15807.660 831.235 818.870 13 15820.137 14 15829.284 15816.362 15804.288 830.641 817.750 15 15827.569 15813.779 15800.858 828.869 815.121 16 15825.759 15811.081 15797.277 826.920 812.358 17 15823.798 15808.254 824.783 809.413 18 15821.697 15805.297 822.490 806.285 19 15819.430 15802.199 820.008 800.977 20 15817.014 15798.936 817.370 799.511 21 15814.436 15795.512 795.862 22 15811.574 15791.941 23 15808.471 15788.072 24 15783.982 BAND 17 F4Delta5/2 - X4Delta5/2 (1,0) J-1/2 R(J) Q(J) P(J) _________________________________ 2 15860.254 3 15860.545 4 15856.009 5 15860.667 15850.484 6 15860.491 15854.123 7 15860.163 15852.944 15846.587 8 15859.686 15851.639 15844.399 9 15859.057 15850.212 15842.063 10 15858.275 15839.577 11 15857.347 15836.934 12 15856.273 15834.144 13 15855.057 15831.207 14 15853.696 15828.126 15 15852.204 15824.901 16 15850.576 15821.535 17 15848.820 15818.033 18 15846.942 15814.400 19 15844.941 15810.637 20 15842.820 15806.753 21 15840.582 15802.746 840.611 22 15838.246 15798.633 838.287 23 15835.790 15794.386 835.847 794.409 24 15833.217 15790.041 833.302 790.081 25 15830.492 15785.587 830.640 785.646 26 15827.606 15781.015 827.809 781.100 27 15776.292 776.440 BAND 18 [15.88] 4Phi9/2 - X4Delta7/2 J-1/2 R(J) Q(J) P(J) _________________________________ 6 15883.761 15877.518 7 15883.272 15876.235 8 15882.620 15874.770 9 15881.790 15873.120 10 15880.789 11 15879.618 15869.282 12 15878.268 15867.101 15856.770 13 15876.763 15864.758 15853.600 14 15875.070 15862.238 15850.260 15 15873.201 15846.722 16 15871.187 15856.700 15842.989 17 15869.001 15853.690 15839.198 18 15866.622 15850.500 15835.179 19 15864.084 15847.121 15830.986 20 15861.371 15843.560 15826.617 21 15858.503 15839.881 15822.085 22 15855.448 15836.010 15817.370 23 15852.215 15831.955 15812.511 24 15848.844 15827.720 15807.468 25 15845.258 15823.363 15802.225 26 15841.439 15818.760 15796.880 27 15813.957 15791.266 28 15785.484 J' = 26 and 27 are pushed downwards BAND 19 see BAND 10 BAND 20 C4Delta7/2 - X4Delta7/2 (4,0) J-1/2 R(J) Q(J) P(J) _________________________________ 6 16074.033 16067.820 16062.417 7 16073.583 16066.517 16060.308 8 16072.955 16065.071 16058.020 9 16072.152 16063.450 16055.556 10 16071.189 16052.941 11 16070.051 16050.140 12 16068.763 16047.167 13 16067.268 16044.036 067.306 14 16065.631 16040.730 065.827 15 16063.403 16037.265 063.829 037.300 16 16061.573 16033.603 061.863 033.802 17 16059.471 16029.388 059.736 029.815 18 16057.170 16025.565 025.851 057.420 057.474 19 16054.683 16021.459 055.013 021.729 20 16052.014 16017.167 052.430 017.413 017.472 21 16049.233 16012.686 049.699 013.030 22 16046.254 046.836 23 16043.118 043.841 042.147 24 16039.823 039.277 040.722 25 16036.436 036.290 037.495 26 16034.144 033.072 27 16029.027 029.644 030.680 28 16025.136 026.037 027.099 29 16022.227 021.090 023.407 30 16018.227 019.378 016.941 31 16014.057 32 009.705 BAND 21 C4Delta5/2 - X4Delta5/2 (4,0) J-1/2 R(J) Q(J) P(J) _________________________________ 4 16142.904 5 16142.784 6 16142.489 16130.870 7 16140.604 16128.710 142.009 8 16140.031 16126.392 141.388 9 16139.269 16122.496 140.604 123.904 10 16138.375 16119.924 139.694 121.288 11 16137.244 16117.164 138.609 118.493 12 16135.894 16114.219 135.962 115.558 13 16134.393 16111.105 134.488 112.464 14 16132.685 16107.755 132.829 107.815 15 16130.787 16104.232 130.993 104.331 16 16128.710 16100.521 128.985 100.666 17 16126.461 16096.618 126.802 096.822 18 16124.462 16092.526 092.805 19 16121.962 16088.280 088.621 20 16119.314 16084.275 21 16116.538 16079.769 22 16113.597 16075.113 23 16110.604 16070.324 24 16107.222 16065.401 108.487 25 16103.778 104.937 26 16100.142 16056.282 101.232 27 16096.440 16050.734 28 16045.023 BAND 22 [16.1](4Phi9/2) - X4Delta7/2 J-1/2 R(J) Q(J) P(J) _________________________________ 8 16161.226 9 16159.991 16151.733 10 16158.550 16149.479 11 16156.925 16147.044 12 16155.051 16144.401 13 16152.970 16141.537 14 16150.687 16138.477 15 16148.182 16135.153 16 16145.484 16131.678 17 16142.570 16127.971 16114.219 18 16139.442 16124.033 16109.466 19 16136.080 16119.925 16104.550 20 16132.510 16115.559 16099.438 21 16128.726 16111.011 16094.086 22 16124.760 16106.242 16088.525 23 16101.262 16082.726 24 16116.144 16096.076 16076.786 25 16111.540 16090.665 26 16106.716 16085.055 27 16079.218 BAND 23 [16.5](4Phi7/2) - X4Delta5/2 J-1/2 R(J) Q(J) P(J) _________________________________ 13 16242.043 14 16227.458 15 16237.639 16224.409 16 16235.204 16221.074 17 16232.556 16217.621 232.684 18 16229.675 16213.949 229.851 214.103 19 16226.599 16210.080 210.266 20 16223.227 16206.003 21 16219.809 16201.640 22 16216.080 16197.200 23 16192.491 24 16208.006 16187.550 25 16203.652 16182.403 26 16199.026 16177.069 27 16194.208 16171.420 28 16189.174 16165.591 29 16183.911 16159.571 30 16178.276 16153.310 178.420 31 16172.507 16146.671 172.679 146.819 32 16166.570 16139.914 166.726 140.084 33 16160.599 16132.988 133.136 34 16154.378 16126.021 35 16118.783 BAND 24 E4Delta5/2 - X4Delta5/2 (2,0) J-1/2 R(J) Q(J) P(J) _________________________________ 2 16254.881 16251.815 3 16255.180 16251.368 4 16255.386 16250.671 16246.856 5 16255.410 16249.845 16245.130 6 16255.277 16248.864 16243.308 7 16255.001 16247.734 16241.323 8 16254.575 16246.454 16239.188 9 16253.999 16236.901 10 16253.271 16243.444 16234.464 11 16252.400 16241.715 16231.879 12 16251.376 16239.828 16229.145 13 16250.115 16226.262 250.242 14 16248.802 16223.226 248.885 15 16247.286 16219.976 247.446 220.081 16 16245.583 16216.635 245.825 216.730 17 16243.747 16213.101 244.038 213.262 18 16241.715 16209.420 242.070 209.648 19 16239.533 16205.567 205.850 20 16201.538 201.898 21 16234.600 16197.692 235.260 22 16232.605 16192.970 193.505 23 16228.910 16188.407 189.063 24 16225.789 16183.641 184.404 25 16222.412 16178.722 26 16218.737 16173.588 27 16214.615 16168.198 28 16162.530 29 16156.412 BAND 25 F4Delta7/2 - X4Delta7/2 (1,0) J-1/2 R(J) Q(J) P(J) _________________________________ 4 16258.743 5 16258.475 6 16258.011 7 16257.350 16250.504 16244.466 8 16256.498 16248.833 16241.999 9 16246.988 16239.338 10 16254.212 16244.949 16236.477 11 16252.767 16242.699 16233.445 12 16251.137 16240.263 16230.186 13 16249.307 16237.638 16226.766 14 16247.286 16234.795 16223.120 15 16245.073 16231.776 16219.292 16 16242.666 16228.562 16215.271 17 16240.047 16225.161 16211.058 18 16237.180 16206.650 237.274 19 16234.103 16217.665 16202.040 234.288 217.748 20 16230.996 16197.182 231.109 197.273 231.538 21 16227.723 16192.100 192.287 22 16224.184 16205.244 16187.000 187.112 187.549 23 16220.447 16200.689 16181.733 24 16216.525 16195.964 16176.199 25 16212.390 16191.012 16170.471 212.453 26 16208.103 16164.557 208.198 27 16203.652 16158.435 203.786 158.499 28 16199.064 16152.153 199.255 152.247 29 16194.399 16145.716 194.686 145.847 192.355 30 16189.794 16139.138 190.187 139.331 188.006 188.072 31 16183.217 16132.486 183.389 132.772 130.402 130.442 32 16178.094 16125.901 178.428 126.289 124.099 124.170 33 16172.828 16117.327 173.362 117.503 34 16167.522 16110.223 110.561 35 16161.962 16102.971 162.289 103.502 36 16095.690 37 16088.159 088.477 BAND 26 [16.58](4Delta5/2) - X4Delta5/2 J-1/2 R(J) Q(J) P(J) _________________________________ 4 16275.264 5 16279.669 16274.290 6 16279.345 16267.752 7 16278.827 16271.807 16265.600 8 16278.138 16263.249 9 16277.139 16260.732 277.292 10 16276.249 16258.020 11 16275.020 12 16273.612 16252.120 13 16272.028 14 16270.264 16245.473 270.586 15 16268.313 16241.862 268.644 16 16266.532 16238.101 16238.415 17 16263.863 16234.464 264.264 18 16261.386 16230.001 261.793 203.130 18 16235.081 19 16259.169 16199.102 232.684 20 16256.395 16221.182 230.088 194.889 21 16253.464 16216.978 227.310 190.486 22 16224.341 16185.901 23 16221.182 16181.109 24 16217.840 16176.141 25 16214.308 16170.983 26 16210.582 16165.637 27 16206.651 16160.099 28 16202.561 16154.378 29 16198.239 16148.461 30 16193.771 16142.362 31 16189.087 16136.080 32 16184.216 16129.579 33 16122.901 34 16116.039 BAND 27 E4Delta7/2 - X4Delta7/2 (2,0) J-1/2 R(J) Q(J) P(J) _________________________________ 5 16321.034 6 16320.652 7 16320.086 16313.146 16307.018 8 16319.335 16311.580 16304.638 9 16318.399 16309.830 16302.071 10 16317.278 16307.888 16299.318 11 16315.972 16305.768 16296.384 12 16314.486 16303.465 16293.260 13 16312.810 16289.954 14 16310.950 16298.301 16286.465 15 16308.902 16295.442 16282.791 16 16306.672 16292.397 16278.933 17 16304.261 16289.168 16274.889 18 16301.662 16285.756 16270.663 19 16298.880 16282.161 16266.253 20 16295.914 16278.369 16261.657 21 16292.762 16274.416 16256.878 22 16289.426 16270.264 16251.916 23 16285.893 16265.932 16246.771 24 16281.464 16261.386 16241.442 282.279 282.338 25 16278.071 16235.917 278.369 278.556 26 16274.193 16229.494 274.332 230.310 274.889 230.370 27 16270.017 16224.110 270.055 224.409 224.594 28 16265.659 16218.244 265.700 218.385 218.933 29 16261.168 16212.077 261.208 212.117 30 16256.621 16205.731 256.660 205.773 31 16246.145 16199.255 246.222 199.293 32 16248.374 16192.719 242.927 192.759 243.037 33 16245.287 16186.330 238.602 186.358 238.711 180.209 180.330 34 16242.440 16180.509 233.518 175.058 233.655 175.171 35 16227.965 16175.436 168.741 168.861 36 16222.060 16170.603 222.138 161.661 161.819 37 16216.061 16154.144 38 16209.794 16146.262 146.345 39 16203.330 16138.288 40 16196.641 16130.041 196.702 41 16189.770 16121.601 189.864 42 16182.740 16112.933 16182.856 113.006 43 16175.506 16104.107 175.665 104.193 44 16095.095 095.211 45 16085.895 086.054 BAND 28 D4Phi9/2 - X4Delta7/2 (3,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 16444.83* 4 16444.83* 16440.36 5 16444.83* 16439.41 6 16444.45 16438.22 7 16443.87 16436.94 8 16443.19 16435.40 9 16442.29 16433.69 10 16441.23 16431.82 11 16440.05 16429.71 12 16427.51 13 16425.20 Lines very wide because of the hf structure BAND 30 E4Delta7/2 - X4Delta7/2 (3,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 16846.90* 16843.14 4 16847.07* 16842.47* 16838.63 5 16847.07* 16841.57 16836.95 6 16846.90* 16840.55 16835.11 7 16846.54 16839.36 16833.10 8 16846.05 16838.02 16830.95 9 16845.39 16836.57 16828.61 10 16844.58 16834.92 16826.14 11 16843.59 16833.10 16823.50 12 16842.47* 16831.18 16820.69 13 16841.17 16829.04 16817.74 14 16839.68 16814.58 15 16838.02 16811.29 16 16836.21 16807.79 17 16834.15 16804.13 18 16831.86 19 16829.38 20 16826.64 This undergoes an avoided crossing with BAND 30a 7/2-7/2 J-1/2 R(J) Q(J) P(J) _________________________________ 3 16847.97 16843.91 4 16848.41 16843.46 5 16848.72 16842.87 6 16848.91* 16842.18 7 16848.91* 16841.38 8 16848.91* 10 16829.04 BAND 31 unassigned; quite strong J-1/2 R(J) Q(J) P(J) _________________________________ 3 16860.33* 16856.69 4 16860.33* 16855.86* 16852.23 5 16860.03 16854.74 16850.33* 6 16859.55 16853.46 7 16858.89 16852.02 8 16858.03 16850.33* 9 16856.90* 10 16855.86* 11 16854.28 12 16852.69 13 16850.90 BAND 32 F4Delta7/2 - X4Delta7/2 (2,0); OMEGA-doubled at high J J-1/2 R(J) Q(J) P(J) _________________________________ 316909.36* 16905.74 4 16909.36* 16904.88 16901.37 5 16909.05 16903.84 16899.38 6 16908.56 16902.52 16897.38 7 16907.88 16901.06 16895.04 8 16907.00 16899.38 16892.55 9 16905.83 16889.84 10 16904.63 16895.33 16886.98 11 16903.13 16893.11 16883.90 12 16901.37 16890.62 16880.60 13 16899.61 16887.88 16877.10 899.38* 14 16897.38w 16873.38w 15 16895.33 16869.51 895.04* 16 16892.82 16865.52 892.55* 865.34 17 16890.23 16861.30 889.84 861.06 18 16887.35 886.90* 19 16884.34 883.61 w=wide BAND 36 E4Delta7/2 - X4Delta7/2 (4,0), interacts with the 9/2 state of <37> J-1/2 R(J) Q(J) P(J) _________________________________ 3 17369.69 17366.38 4 17369.29 17365.20 17361.90 5 17368.68 17363.77 17359.70 6 17367.96 17362.16 17357.28 367.62 7 17366.65 17360.45 17354.69* 8 17358.15 17351.63 9 17355.81 17348.68 10 17345.32 BAND 37 9/2 component of interacting pair J-1/2 R(J) Q(J) P(J) _________________________________ 3 17371.37* 4 17371.37* 17366.88 5 17371.12 17365.86 17361.37 6 17370.69 17364.63 17359.37 7 17370.04 17363.20 17357.12 8 17369.18 17361.53 17354.70 9 17368.12 17359.68 17352.03 10 17366.85 17357.62 17349.16 11 17365.39 17355.34 17346.42 12 17363.71 17352.91 17342.84 13 17361.89 17350.21 14 17359.68 17347.38 BAND 38 570.7 nm, 7/2-7/2 band, unassigned J-1/2 R(J) Q(J) P(J) _________________________________ 3 17514.46* 17510.71 4 17514.62* 17510.01 17506.23 5 17514.62* 17509.16 17504.60 6 17514.46* 17508.14 17502.71 7 17514.06 17506.98 17500.71 8 17513.49 17505.61 17498.56 9 17512.70 17504.12 17496.22 10 17511.67 17502.33 17493.63 11 17510.33 17500.31 17490.86 17510.71* 12 17509.16 17487.85 13 17507.46 17484.47 17484.90 14 17505.61 17481.34 15 17503.41 17477.58 16 17501.05 17473.60 BAND 39 F4Delta7/2 - X4Delta7/2 (3,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 17574.89* 17571.31 4 17575.83 17570.43 17566.78 574.89* 5 17575.47 17570.32* 17564.94 574.49 569.36 6 17574.89* 17568.97 17563.76 573.83 568.01 562.86 7 17574.30 17567.47 17561.37 572.99 560.50 8 17573.52 17565.82 17558.93 557.87 9 17572.59 17564.06 17556.32 554.99 10 17571.37* 17562.08 17553.53 11 17570.22 17559.96 17550.56 12 17568.73 17557.66 17547.42 13 17567.05 17555.22 17544.13 14 17565.05 17540.69 15 17562.63 17536.97 16 17533.10 17 17528.60 BAND 39a (fragment) 569 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 17562.08* 17558.25 4 17562.08* 17557.52 17553.67 5 17562.08* 17556.61 17551.97 6 17561.67 17555.55 17550.09 7 17554.32 17548.00 8 17545.72 9 17543.56 BAND 40 fairly strong; unassigned 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 17758.82 17755.24 4 17758.64 17754.29 17750.78 5 17758.21 17753.06* 17748.78 6 17757.59 17751.71 17746.60 7 17756.76 17750.10 17744.20 8 17755.67 17748.24 17741.58 9 17754.37* 17746.18 17738.74 10 17752.91 17743.90 17735.68 11 17751.19 17741.38 17732.46* 12 17749.20 17728.92 13 17747.01 17725.19 14 17744.58 17721.24 15 17741.93 17717.09 16 17739.07 17712.68 17 17735.93 18 17732.62 BAND 41 E4Delta7/2 - X4Delta7/2 (5,0); interacts with <42> J-1/2 R(J) Q(J) P(J) _________________________________ 3 17901.45 17898.10 4 17901.26 17897.00 5 17900.80 17895.81 17891.54 6 17900.13 17894.37 17889.32 7 17899.22 17892.70 17886.88 8 17898.10 17890.81 17884.22 9 17896.78 17888.66 17881.32 10 17895.19 17886.36 17878.18 11 17893.42 17883.77 17874.85 12 17891.36 17880.80 17871.22 13 17889.04 17877.87 17867.39 14 17886.54 17874.58 17863.31 15 17883.77 17859.05 16 17880.80 17854.54 17 17877.57 17849.75 18 17874.13 17844.73 19 17870.43 17839.52 20 17866.55 17834.10 21 17862.45 17828.41 22 17858.23p 17822.51 23 17853.95p p = perturbed BAND 42 interacts with <41>; about x2 weaker J-1/2 R(J) Q(J) P(J) _________________________________ 3 17932.78 17929.34 4 17932.43 17928.30 17924.90 5 17931.84 17926.98 17922.79 6 17931.05 17925.41 17920.48 7 17929.99 17923.53 17917.88 8 17928.69 17921.50 17915.04 9 17927.17 17919.20 17911.99 10 17925.41 17916.68 17908.67 11 17923.44 17913.91 17905.13 12 17921.21 17910.88 13 17918.69 17907.68 17897.31 14 17916.02 15 17913.04 16 17909.91 17 17906.57 17879.06 18 17902.98 19 17868.57 20 17863.02 21 17857.24 22 17851.22 23 17881.99 17844.98 24 17877.14 17838.58 25 17872.10 17832.02 26 17866.81 17825.17 27 17861.36 28 17855.72 BAND 46 F4Delta7/2 - X4Delta7/2 (4,0) possibly J-1/2 R(J) Q(J) P(J) _________________________________ 3 18200.88 18197.22 4 18200.88 18196.36 18192.66 5 18200.58 18195.34 18190.89 6 18200.21 18194.11 18188.76 7 18199.50 18192.66 18186.60 8 18198.61 18190.89 18184.12 9 18189.10 18181.41 10 18196.36 18186.99 18178.56 11 18194.87 18184.81 18175.60 12 18193.19 18182.36 18172.32 13 18191.32 18168.88 14 18176.85 18165.18 15 18161.44 perturbed at J' = 15.5 BAND 48 546.9 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 18280.83 18277.58 4 18280.51 18276.33 18272.95 5 18280.00 18274.85 18270.86 6 18279.18 18273.37 18268.47 7 18278.11 18271.81 18265.81 8 18276.90 18269.65 18263.14 9 18259.85 BAND 49 545 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 18325.98 18322.59 4 18325.62 18321.46 18318.09 5 18325.11 18320.18 18315.95 6 18324.23 18318.52 18313.67 7 18323.08 18311.17 8 18321.82 18314.58 18308.27 9 18320.18 18312.31 18305.18 10 18309.71 18301.75 11 18316.46 18306.92 18298.17 12 18314.16 18294.36 13 18311.64 18290.39 14 18308.88 18286.14 15 18305.85 16 18302.58 BAND 50 544.2 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 18367.64 4 18370.85 18366.52 5 18370.42 18365.38 6 18369.78 18363.94 18358.93 7 18368.91 18362.29 18356.50 8 18367.85 18360.41 18353.85 9 18366.52 18358.38 18350.92 10 18365.02 18356.10 18347.82 11 18363.27 18353.58 18344.52 12 18361.31 18350.92 18340.95 13 18359.15 18337.21 14 18356.74 18333.27 15 18354.15 18329.03 16 18351.36 18324.53 17 18348.34 Probably OMEGA-doubling, but it is hard to pick out the other component securely. BAND 52 E4Delta7/2 - X4Delta7/2 (6,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 18452.56 4 18456.03 18451.70 18448.01 5 18455.68 18450.50 18446.15 6 18455.05 18449.09 18444.01 7 18454.30 18447.58 18441.66 8 18453.30 18445.81 18439.12 9 18452.10 18443.90 18436.35 10 18441.66 18433.31 11 18449.09 18439.12 18430.12 12 18447.20 18436.57 18426.73 13 18445.13 18433.71 18423.06 14 18442.88 18430.55 18419.22 15 18440.40 18427.19 18415.13 16 18437.74 18423.94 18410.86 17 18434.72 18 18431.60 19 18428.24 20 18424.66 strong and unperturbed BAND 54 529.1 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 18876.92 18873.41 4 18876.77 18872.45 18868.83 5 18876.34 18871.22 18866.94 6 18875.65 18869.78 18864.76 7 18874.65 18868.14 18862.35 8 18873.50* 18866.23 18859.68 9 18872.26 18864.17 18856.73 10 18870.61 18861.82 18853.66 11 18868.95 18859.31 18850.27 12 18866.94 18856.45 18846.68 13 18864.56 18853.30 18842.98 14 18862.06 18849.87 18838.77 15 18834.48 BAND 56 E4Delta7/2 - X4Delta7/2 (7,0) perturbed J-1/2 R(J) Q(J) P(J) _________________________________ 3 18980.22* 18976.62 4 18980.22* 18975.67 18972.11 5 18980.03 18974.61 18970.13 6 18979.52 7 18978.97 18965.87 8 18978.26 18970.41 18963.44 9 18977.27 18968.62 18960.84 10 18976.25 18958.10 11 18975.02 18955.14 12 18973.75* 18952.07 13 18972.11 18948.86 14 18970.41 18945.50 15 18968.50 18942.00 16 18966.69 18938.33 17 18964.63 18934.56 18 18962.41 18930.54 19 18960.11 18926.50 20 18922.30 21 18917.94 Small perturbation at J = 16.5. Levels 56 and 57 interact; band <56> starts weak and becomes strong; <57> starts strong and becomes weak. BAND 57 interacts with <56> J-1/2 R(J) Q(J) P(J) _________________________________ 3 18978.26* 18974.61 4 18978.26* 5 18978.26* 18972.77 18968.34 6 18977.73 18971.59 18966.23 7 18977.15 18964.03 8 18976.25 18968.50 18961.62 9 18975.26 18966.69 18959.01 10 18964.63 18956.15 11 18962.41 18953.11 12 18970.99 18949.90 13 18969.09 18946.44 BAND 58 F4Delta7/2 - X4Delta7/2 (6,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 19013.37* 19009.87 4 19013.37* 19008.92 5 19013.06 19007.85 19003.44 6 19012.56 19006.54 19001.44 7 19011.85 19005.05 18999.05 8 19010.97 19003.44 18996.58 9 19009.87 19001.44 18993.90 10 19008.61 18999.41 18991.02 11 19007.10 18997.05 18987.96 12 19005.48 18994.63 18984.69 13 19003.64 18992.07 18981.21 14 18989.25 18977.64 15 18999.41 18986.21 18973.76 16 18997.05 18969.76 17 18994.48 18965.51 18 18991.77 18961.15 19 18988.89 18956.63 20 18985.88 18951.86 21 18982.70 18946.94 Possibly the negative D results from the calibration BAND 60 513.7 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 19496.78 19493.25 4 19496.78 19492.33 19488.73 5 19496.29 19491.19 19486.77 6 19495.77 19489.76 19484.52 7 19494.93 19482.18 8 19493.89 19479.63 9 19492.76 19476.84 10 19491.60 11 19490.46 BAND 61 J-1/2 R(J) Q(J) P(J) _________________________________ 3 19496.79* 19493.19 4 19496.79* 19492.25 19488.70 5 19496.31 19491.26b 6 19495.70 19489.64b 7 19494.87 8 19493.95 9 19492.73 b = broad BAND 62 E4Delta7/2 - X4Delta7/2 (8,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 19533.08 19529.58 4 19532.91 19528.64 19525.10* 5 19532.46 19527.26 19522.98* 6 19531.78 19525.77* 19520.76* 7 19530.97 19524.19* 19518.45* 8 19529.92 19515.78* 9 19528.64 19513.02 10 19509.94 11 19506.67 BAND 62a level <62a> interacts with level <62> J-1/2 R(J) Q(J) P(J) _________________________________ 3 19526.44 19522.98 4 19526.22 19521.93 19518.45 5 19525.77 19520.76 19516.46 6 19525.10 19519.26 19514.22 7 19524.19 19517.57 19511.78 8 19522.98 19515.78 19509.09 9 19521.59 19513.47 19506.16 10 19519.985 19511.14 19503.00 11 19499.58 12 19495.93 BAND 63 F4Delta7/2 - X4Delta7/2 (7,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 19608.33 19604.84 4 19608.33 19603.92 19600.32 5 19607.98 19602.79 19598.44 596.86 6 19607.38 19601.48 19596.30 594.91 7 19606.62 19599.98 19593.98 592.60 8 19605.61 19598.20 19591.44 590.01 9 19588.66 587.25 10 19603.57 19585.63 584.12 11 19601.94 19592.12 19582.19 583.21 580.83 12 19589.47 19579.61 577.10 13 19575.97 14 19596.30 19572.19 15 19568.59 568.23 16 19564.29 The combination differences for the extra P branch are totally blended, though some hints of R branch structure can just be seen. Numbering therefore uncertain. BAND 64 508.4 nm, 7/2?-7/2 band; perturbed J-1/2 R(J) Q(J) P(J) _________________________________ 3 19666.18 19662.69 4 19666.18 19661.75 5 19665.83 19660.57 19656.28 6 19665.39 19659.38 19654.08 7 19664.67 19657.82 19651.89 8 19664.01 19649.40 9 19663.16 19654.48 19646.72 10 19662.28 19652.66 19644.00 11 19661.34 19641.23 12 19661.07 19638.31 13 19659.96 19635.26 14 19658.76 19633.18 15 19657.60 19630.00 16 19626.84 17 19623.59 18 19620.30 perturbed between J' = 13.5 and 14.5 BAND 66 499.5 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 20012.27 20008.82 4 20011.98 20007.75 20004.34 5 20011.45 20006.47 20002.22 6 20010.68 20004.94 19999.83 7 20009.66 20003.21 19997.27 8 20008.43 20001.08 19994.63 9 20006.96 19998.76 19991.63 10 20005.24 19996.38 19988.37 11 20003.21 19993.71 19984.89 12 20001.08 19990.78 19981.20 13 19998.50 19987.58 19977.25 14 19996.03 19973.10 15 19993.10 19968.71 16 19989.96 19964.09 17 19986.64 19959.21 18 19983.01 19954.06 19 19979.15 19948.79 20 19943.28 BAND 67a 498.5 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 20062.52* 20059.01 4 20062.52* 20058.01 20054.53 5 20062.06 20052.53 6 20061.32 20055.38 7 20060.38 20047.85 8 20045.17 9 20042.15 BAND 67 E4Delta7/2 - X4Delta7/2 (9,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 20087.53 20084.27 4 20087.30 20083.04 20079.80 5 20086.75 20081.83 20077.54 6 20086.00 20080.29 20075.28 7 20085.02 20078.62 20072.82 8 20083.80 20076.47 20070.04 9 20082.31 20074.33 20067.08 10 20080.62 20071.86 20063.85 11 20078.62 20069.17 20060.38 12 20076.47 20066.17 20056.61 13 20074.10 20063.02 20052.69 14 20071.46 20059.74 20048.50 15 20068.56 20044.06 16 20065.42 20039.36 17 20034.40 18 20058.42 20029.24 19 20023.80 20 20018.11 BAND 70 E4Delta7/2 - X4Delta7/2 (10,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 20643.71 20640.23 4 20643.52 20639.18 20635.69 5 20642.98 20637.99 20633.63 6 20642.29 20636.47 20631.51 7 20641.34 20634.82 20628.96 8 20640.10 20632.79 20626.21 9 20638.57 20630.56 20623.21 10 20636.76 20628.00 20620.04 11 20634.77 20625.25 20616.55 12 20632.28 20622.16 20612.79 13 20629.56 BAND 72 F4Delta7/2 - X4Delta7/2 (9,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 20884.80 20881.39 4 20884.54 20880.33 20877.12 5 20883.92 20879.08 20874.87 6 20883.14 20877.62 20872.73 7 20882.19 20875.88 20870.25 8 20880.96 20873.86 20867.47 9 20879.54 20871.70 20864.48 10 20877.83 20869.14 20861.23 11 20875.88 20866.43 20857.78 12 20873.66 20863.47 20854.00 13 20871.19 20860.29 20849.95 14 20868.49 20856.87 20845.70 15 20865.48 20841.15 16 20862.44 20836.27 17 20858.85 18 20855.69 BAND 74 G4Phi7/2 - X4Delta7/2 (v,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 21047.95 4 21047.68 21043.58 5 21047.26 21042.14 6 21046.71 21040.87 7 21045.90 21039.18 8 21044.92 21037.35 9 21043.65 21035.35 10 21042.14 21032.99 11 21040.41 21030.55 12 21038.47 21027.74 13 21036.36 21024.93 14 21034.04 21021.80 15 21031.35 16 21028.51 BAND 78 J-1/2 R(J) Q(J) P(J) _________________________________ 3 21218.78 21215.44 4 21218.41 21214.42 21210.96 5 21217.86 21212.94 21208.87 6 21216.99 21211.32 21206.53 7 21215.94 21209.42 21203.90 8 21214.42 21207.47 21201.04 9 21212.86 21204.92 21197.66 10 21210.96 11 21208.81 21199.53 12 21206.41 13 21203.84 14 21200.94 BAND 80 J-1/2 R(J) Q(J) P(J) _________________________________ 3 21447.90 21444.59 4 21447.34 21443.32 21440.01 5 21446.51 21441.85 21437.88 6 21445.41 21440.01 21435.25 7 21444.10 21437.88 21432.48 8 21442.48 21435.56 21429.42 9 21440.55 21432.91 21426.04 10 21438.40 21430.04 21422.34 11 21435.56 21426.86 21418.48 12 21432.91 21424.64 21414.32 13 21429.82 21419.40 21409.47 14 21426.50 21415.63 21404.81 15 21422.92 21411.00 16 21418.93 17 21414.78 18 21410.31 19 21405.51 BAND 83 J-1/2 R(J) Q(J) P(J) _________________________________ 3 21535.06 21531.59 4 21534.81 21530.50 21527.11 5 21534.27 21529.19 21524.98 6 21533.47 21527.66 21522.68 7 21532.46 21525.93 21520.18 8 21531.25 21523.86 21517.40 9 21529.70 21514.40 10 21527.99 21511.10 11 21525.96 21516.49 21507.68 12 21523.86 13 21521.58 15 21515.71 BAND 84 J-1/2 R(J) Q(J) P(J) _________________________________ 3 21608.18 21604.64 4 21608.18 21603.71 21600.03 5 21607.89 21602.61 21598.19 6 21607.38 21601.29 21596.00 7 21606.63 21599.78 21593.70 8 21605.78 21598.07 21591.21 9 21604.64 21596.16 21588.56 10 21603.34 21594.08 21585.70 11 21601.87 21582.62 12 21600.03 21579.45 13 21576.05 14 21572.43 15 21568.30 16 21564.36 BAND 88 J-1/2 R(J) Q(J) P(J) _________________________________ 3 21952.74 4 21952.53 21948.37 5 21952.08 21947.00 21942.66 6 21951.57 21945.78 21940.48 7 21950.83 21944.00 21938.12 8 21949.70 21942.31 21935.72 9 21940.13 21932.79 10 21929.57 BAND 92 J-1/2 R(J) Q(J) P(J) _________________________________ 3 22134.14 22130.63 4 22133.84 22129.46 22126.09 5 22133.33 22128.27 22124.02 6 22132.66 22126.82 22121.78 7 22131.71 22125.00 22119.32 8 22130.63 22123.12 22116.53 9 22129.36 22121.05 22113.77 10 22127.96 22118.78 22110.69 11 22126.51 22116.53 22107.48 12 22124.93 22114.05 22104.09 13 22111.45 22100.62 14 22097.05 BAND 92a J-1/2 R(J) Q(J) P(J) _________________________________ 3 22122.51 22118.78 22115.98 4 22122.51 22117.84 22114.17 5 22122.20 22117.00 22112.58 6 22121.78 22115.58 22110.52 7 22114.05 22108.15 8 22105.56 BAND 95 G4Phi7/2 - X4Delta7/2 (v+3,0) J-1/2 R(J) Q(J) P(J) _________________________________ 3 22406.36 4 22406.36 22401.93 5 22406.36 22400.99 22396.36 6 22406.16 22399.74 22394.29 7 22406.04 22398.64 22392.37 8 22405.82 22397.55 22390.14 9 22405.60 22396.19 22387.90 10 22405.23 22395.08 22385.66 BAND 96 J-1/2 R(J) Q(J) P(J) _________________________________ 3 22444.41 22440.63 4 22444.41 22439.85 22436.19 5 22444.20 22438.88 22434.40 6 22443.78 22437.74 22432.41 7 22443.12 22436.33 22430.13 8 22442.28 22434.73 22427.78 9 22441.35 22432.92 22425.13 10 22440.16 22430.82 22422.33 11 22438.88 22428.69 22419.30 12 22437.38 22426.36 22416.10 13 22435.61 22423.88 22412.78 14 22433.83 22421.13 22409.25 15 22431.82 22418.26 22405.60 16 22429.63 22415.32 22401.72 17 22427.35 22412.10 22397.74 18 22424.89 22408.76 22393.50 19 22422.29 22405.34 20 22419.30 22401.72 21 22397.74 BAND 99 442.1 nm, 7/2-7/2 band J-1/2 R(J) Q(J) P(J) _________________________________ 3 22613.39 22609.81 4 22613.02 22608.75 22605.30 5 22612.39 22607.40 22603.17 6 22611.58 22605.67 22600.88 7 22610.41 22603.90 22598.05 8 22609.06 22601.85 22595.29 9 22607.40 22599.50 22592.20 10 22605.67 22596.91 22588.96 11 22603.72 22593.94 22585.24 12 22601.35 22581.50 13 22598.85 22577.60 14 22596.06 22573.14 15 22593.09