Journal of Molecular Spectroscopy; Manuscript No. JMS97-0074 Title : Coriolis Interactions in the Nu2, Nu4a, Nu4b and Nu3a States of Phosphine-d1. Authors : R.J. Kshirsagar and V.A. Job APPENDIX C : Wave numbers (cm-1) of newly assigned lines in the Nu2 band of PH2D. O-C is (Observed Minus Calculated frequency) x 10**-4 cm-1. J' Ka' Kc' J" Ka" Kc" FREQ. O-C 11 11 1 12 12 1 780.3540 -2 11 11 0 12 12 0 780.3540 -2 11 10 1 12 11 1 783.7840 -7 11 10 2 12 11 2 783.7840 -7 10 10 0 11 11 0 790.2306 -4 10 10 1 11 11 1 790.2306 -4 13 4 9 14 5 9 790.2497 -9 11 8 4 12 9 4 790.6330 -5 11 8 3 12 9 3 790.6330 -3 10 9 1 11 10 1 793.6811 -10 10 9 2 11 10 2 793.6811 -10 12 5 8 13 6 8 793.9598 -2 12 5 7 13 6 7 793.9598 7 10 8 3 11 9 3 797.1197 -8 10 8 2 11 9 2 797.1197 -7 11 1 11 12 2 11 811.4093 2 10 1 9 11 3 8 811.9750 -2 12 2 11 13 2 12 813.9021 11 10 2 9 11 3 9 815.9734 10 10 6 5 11 6 6 822.4944 -1 10 6 4 11 6 5 822.4944 7 8 4 5 9 5 5 823.3595 8 8 4 4 9 5 4 823.3595 -7 7 5 2 8 5 3 842.3091 -2 7 5 3 8 5 4 842.3091 -10 14 12 3 14 13 1 842.7398 8 14 12 2 14 13 2 842.7398 8 4 4 1 5 5 1 848.4005 -6 4 4 0 5 5 0 848.4005 -6 6 4 3 7 4 4 848.9955 -1 6 1 5 7 1 6 848.9955 1 13 9 4 13 10 4 854.1634 8 13 9 5 13 10 3 854.1634 3 12 8 5 12 9 3 858.5505 -3 12 8 4 12 9 4 858.5505 5 5 2 3 6 1 5 858.8242 4 11 8 4 11 9 2 859.3979 4 11 8 3 11 9 3 859.3979 6 4 3 2 5 3 3 861.7616 -5 5 3 3 6 2 5 863.1579 -1 5 4 2 6 3 4 865.3544 -6 2 2 0 3 3 0 866.8939 -1 13 4 10 13 5 8 870.7924 3 13 3 11 13 4 9 872.4655 7 11 4 8 11 5 6 872.8639 1 16 3 13 16 4 13 874.3004 -1 15 3 12 15 4 12 874.6452 -4 2 1 1 3 0 3 876.0670 7 6 4 3 6 5 1 876.3669 -4 15 14 2 15 14 1 877.2532 9 15 14 1 15 14 2 877.2532 9 15 13 3 15 13 2 877.5546 -1 15 13 2 15 13 3 877.5546 -1 14 14 1 14 14 0 878.3571 6 14 14 0 14 14 1 878.3571 6 14 13 1 14 13 2 878.6740 -1 14 13 2 14 13 1 878.6740 -1 15 10 5 15 10 6 878.8671 -2 14 12 3 14 12 2 879.0670 -10 14 12 2 14 12 3 879.0670 -10 2 2 1 3 1 3 879.1388 -1 14 11 3 14 11 4 879.5037 -8 14 11 4 14 11 3 879.5037 -8 6 3 4 6 4 2 879.6116 -8 13 13 0 13 13 1 879.7201 -4 13 13 1 13 13 0 879.7201 -4 14 10 5 14 10 4 879.9759 6 14 10 4 14 10 5 879.9759 8 13 12 2 13 12 1 880.1141 3 13 12 1 13 12 2 880.1141 3 1 1 1 2 1 2 880.4917 9 13 11 3 13 11 2 880.5550 0 13 11 2 13 11 3 880.5550 0 17 2 15 17 3 15 880.7375 5 16 2 14 16 3 14 880.9325 -3 13 10 3 13 10 4 881.0319 6 13 10 4 13 10 3 881.0319 6 12 12 0 12 12 1 881.0889 13* 12 12 1 12 12 0 881.0889 13* 11 11 1 11 11 0 882.4387 -3 11 11 0 11 11 1 882.4387 -3 11 10 1 11 10 2 882.9259 -11 11 10 2 11 10 1 882.9259 -11 12 8 5 12 8 4 883.0179 -13 13 5 9 13 5 8 883.0179 3* 12 8 4 12 8 5 883.0179 -5 16 3 14 16 2 14 883.0736 -9 10 10 1 10 10 0 883.7649 5 10 10 0 10 10 1 883.7649 5 20 1 19 20 2 19 884.9302 -1 20 2 19 20 1 19 884.9536 0 11 4 8 11 4 7 885.1979 5 15 4 12 15 3 12 885.4596 3 12 3 9 12 3 10 886.7447 -6 5 1 4 5 2 4 887.2648 7 7 7 1 7 7 0 887.4370 11 7 7 0 7 7 1 887.4370 11 2 1 1 2 2 1 887.4449 4 14 4 11 14 3 11 887.5396 4 9 3 6 9 3 7 888.0460 -13 20 0 20 20 1 20 889.4173 4 20 1 20 20 0 20 889.4173 0 4 4 0 4 4 1 890.2738 -6 4 4 1 4 4 0 890.2738 -5 4 3 1 4 3 2 890.6205 5 17 6 12 17 5 12 891.2292 8 14 5 10 14 4 10 892.6332 0 6 1 5 6 1 6 893.7615 -3 16 6 10 16 5 12 894.0750 6 14 4 10 14 3 12 894.3645 3 17 4 13 17 3 15 894.3873 -2 7 1 6 7 1 7 894.4450 6 15 6 10 15 5 10 895.1089 11 8 1 7 8 1 8 895.2251 -2 16 7 10 16 6 10 896.7424 2 16 7 9 16 6 11 896.8018 2 6 2 5 6 0 6 897.0511 0 9 3 7 9 1 8 897.4348 -1 8 4 5 8 3 5 897.6621 -5 4 3 1 4 2 3 897.9465 10 11 5 6 11 4 8 897.9465 -12 9 2 8 9 0 9 897.9791 7 17 8 10 17 7 10 897.9980 5 3 3 1 3 2 1 898.1231 1 15 7 8 15 6 10 898.2631 2 10 2 9 10 0 10 898.4883 3 11 2 10 11 0 11 899.0759 6 16 8 9 16 7 9 899.5033 7 14 7 7 14 6 9 899.6147 6 12 2 11 12 0 12 899.7276 -1 15 8 7 15 7 9 900.8919 8 10 6 4 10 5 6 901.4959 4 16 9 7 16 8 9 902.1080 2 11 7 5 11 6 5 903.0494 1 11 7 4 11 6 6 903.0494 -3 15 9 7 15 8 7 903.4343 -1* 15 9 6 15 8 8 903.4575 -1 3 1 3 2 2 1 903.9631 4 5 3 3 5 0 5 904.0233 2 6 3 4 6 0 6 904.1558 5 18 11 7 18 10 9 904.3067 3 18 11 8 18 10 8 904.3067 1 16 5 12 16 2 14 905.5977 6 17 11 7 17 10 7 905.7885 -31* 17 11 6 17 10 8 905.7885 -31* 13 9 4 13 8 6 905.8967 4 13 9 5 13 8 5 905.8967 -2 15 10 5 15 9 7 906.0011 -36* 15 10 6 15 9 6 906.0380 6 9 4 5 9 2 8 906.1057 -1 13 4 10 13 1 12 906.1968 4 10 3 8 10 0 10 906.2826 5 10 4 7 10 1 9 906.5958 8 4 2 3 3 3 1 906.6856 -4 9 4 6 9 1 8 907.1267 1 11 3 9 11 0 11 907.1963 8 14 10 5 14 9 5 907.2305 7 14 10 4 14 9 6 907.2305 9 8 4 5 8 1 7 907.8249 5 12 3 10 12 0 12 908.2467 -4 12 10 3 12 9 3 909.4729 3 12 10 2 12 9 4 909.4729 3 14 11 4 14 10 4 909.7609 2 14 11 3 14 10 5 909.7609 2 11 10 2 11 9 2 910.4704 2 11 10 1 11 9 3 910.4704 2 13 11 2 13 10 4 910.9206 4 13 11 3 13 10 3 910.9206 4 15 12 4 15 11 4 911.1092 28* 15 12 3 15 11 5 911.1092 28* 11 5 7 11 2 9 911.3488 4 10 10 1 10 9 1 911.3839 -11 10 10 0 10 9 2 911.3839 -11 12 11 1 12 10 3 911.9961 -18* 12 11 1 12 10 2 911.9961 -18* 14 12 3 14 11 3 912.3478 6 14 12 2 14 11 4 912.3478 6 18 14 5 18 13 5 912.3873 9* 18 14 4 18 13 6 912.3873 10* 3 2 1 2 1 1 912.6119 -6 10 5 6 10 2 8 912.9186 7 11 11 0 11 10 2 912.9941 3 11 11 1 11 10 1 912.9941 3 13 12 1 13 11 3 913.5077 10 13 12 2 13 11 2 913.5077 10 4 3 2 3 3 1 913.6988 2 4 3 1 3 3 0 913.6988 -5 15 13 3 15 12 3 913.7549 5 15 13 2 15 12 4 913.7549 5 17 14 4 17 13 4 913.8289 8 17 14 3 17 13 5 913.8289 8 9 5 5 9 2 7 914.4740 6 12 12 1 12 11 1 914.5858 10 12 12 0 12 11 2 914.5858 10 14 13 1 14 12 3 915.0021 -10 14 13 2 14 12 2 915.0021 -10 16 14 2 16 13 4 915.2086 -29* 16 14 3 16 13 3 915.2086 -29* 14 14 1 14 13 1 917.7672 8 14 14 0 14 13 2 917.7672 8 5 3 3 4 3 2 919.0592 -10 5 3 2 4 3 1 919.0592 0 10 5 6 9 6 4 928.0073 5 10 5 5 9 6 3 928.0073 -1 5 4 2 4 3 2 928.8401 4 6 3 3 5 2 3 931.1259 -9 5 3 2 4 0 4 932.4799 -7 6 3 3 5 0 5 938.1793 3 12 4 9 11 5 7 941.0851 5 13 5 9 12 6 7 942.5254 6 13 5 8 12 6 6 942.5348 6 13 2 11 12 4 8 944.5566 11 11 10 1 10 10 0 945.9056 0 11 10 2 10 10 1 945.9056 0 10 1 10 9 1 9 946.7974 -5 12 11 1 11 11 0 950.1212 4 12 11 2 11 11 1 950.1212 4 13 2 12 12 3 10 950.2801 10 14 4 11 13 5 9 950.4373 7 12 10 3 11 10 2 950.6940 5 12 10 2 11 10 1 950.6940 5 14 4 10 13 5 8 950.7139 3 12 8 4 11 8 3 951.8674 2 12 8 5 11 8 4 951.8674 -6 14 3 12 13 4 10 953.0689 2 12 4 9 11 4 8 953.7740 4 13 11 3 12 11 2 954.8265 9 13 11 2 12 11 1 954.8265 9 13 10 3 12 10 2 955.4017 5 13 10 4 12 10 3 955.4017 4 13 9 4 12 9 3 955.9898 4 13 9 5 12 9 4 955.9898 -1 14 12 2 13 12 1 958.9001 -1 14 12 3 13 12 2 958.9001 -1 15 3 12 14 4 10 958.9554 1 14 11 3 13 11 2 959.4498 -5 14 11 4 13 11 3 959.4498 -5 14 10 5 13 10 4 960.0296 -5 14 10 4 13 10 3 960.0296 -3 14 3 11 13 3 10 961.7435 4 14 4 10 13 4 9 962.2259 -3 10 3 7 9 0 9 962.8384 -4 15 13 3 14 13 2 962.9146 -3 15 13 2 14 13 1 962.9146 -3 14 4 11 13 4 10 963.0524 -2 15 12 3 14 12 2 963.4400 -1 15 12 4 14 12 3 963.4400 -1 10 8 3 9 7 3 963.9291 -6 10 8 2 9 7 2 963.9291 -6 15 11 5 14 11 4 963.9965 15* 15 11 4 14 11 3 963.9965 15* 16 2 14 15 3 12 964.1284 -5 15 10 5 14 10 4 964.5987 -4 15 10 6 14 10 5 964.6315 -4 15 9 7 14 9 6 965.1368 0 15 8 7 14 8 6 965.7110 -6 15 8 8 14 8 7 965.7220 -2 10 9 2 9 8 2 966.3160 -10 15 6 9 14 6 8 966.6743 -3 16 14 3 15 14 2 966.9357 -8 16 14 2 15 14 1 966.9357 -8 17 3 14 16 4 12 967.3498 5 16 13 3 15 13 2 967.3621 -2 16 13 4 15 13 3 967.3621 -2 17 2 15 16 3 13 967.7937 -12 16 12 5 15 12 4 967.8999 2 16 12 4 15 12 3 967.8999 2 16 11 6 15 11 5 968.4600 4 16 11 5 15 11 4 968.4600 4 16 10 6 15 10 5 969.0221 15* 16 10 7 15 10 6 969.0221 -43* 13 4 10 12 3 10 969.1126 -1 11 4 7 10 1 9 969.1777 -6 14 4 10 13 3 10 969.5250 -6 11 3 8 10 0 10 969.5840 -1 16 9 8 15 9 7 969.6050 -2 16 9 7 15 9 6 969.6230 -4 16 8 8 15 8 7 970.1435 14* 16 8 9 15 8 8 970.1665 -6 16 4 12 15 4 11 970.2538 -3 16 3 13 15 3 12 970.3209 -1 16 7 9 15 7 8 970.6568 1 16 7 10 15 7 9 970.6700 -13* 12 7 5 11 6 5 971.0354 2 12 7 6 11 6 6 971.0354 -11 16 6 11 15 6 10 971.0811 1 16 5 12 15 5 11 971.4371 0 16 4 13 15 4 12 972.1380 -2 17 12 6 16 12 5 972.2785 -5 17 12 5 16 12 4 972.2785 -5 17 11 7 16 11 6 972.8442 -1 17 11 6 16 11 5 972.8442 -1 16 2 14 15 2 13 972.8903 3 15 4 11 14 3 11 973.3748 0 12 8 5 11 7 5 973.4445 -8 12 8 4 11 7 4 973.4445 0 11 10 1 10 9 1 973.5254 -8 11 10 2 10 9 2 973.5254 -8 15 3 12 14 2 12 973.5943 0 14 4 11 13 3 11 974.0927 -5 17 8 9 16 8 8 974.4511 10* 17 8 10 16 8 9 974.5187 -3 12 4 8 11 1 10 974.5766 2 17 3 14 16 3 13 974.7013 -3 17 7 10 16 7 9 974.9465 7* 17 7 11 16 7 10 974.9994 0 17 5 12 16 5 11 975.1035 3 17 6 11 16 6 10 975.3342 0 17 6 12 16 6 11 975.3737 -3 17 5 13 16 5 12 975.7417 1 11 11 0 10 10 0 975.9721 -3 11 11 1 10 10 1 975.9721 -3 18 12 6 17 12 5 976.5784 1 18 12 7 17 12 6 976.5784 1 17 4 14 16 4 13 976.6484 9* 18 11 7 17 11 6 977.1510 9 18 11 8 17 11 7 977.1510 8 14 6 8 13 5 8 977.4700 -1 17 2 15 16 2 14 977.9072 -1 12 10 2 11 9 2 978.2361 -5 12 10 3 11 9 3 978.2361 -5 18 9 10 17 9 9 978.2718 2* 18 9 9 17 9 8 978.3072 -2* 17 3 15 16 3 14 978.6407 0 12 5 7 11 2 9 979.4800 -5 15 5 11 14 4 11 979.7053 6 18 5 14 17 5 13 979.9800 5* 14 7 7 13 6 7 980.1196 0 13 4 9 12 1 11 980.2167 -4 13 9 4 12 8 4 980.4575 -1 13 9 5 12 8 5 980.4575 -6 12 11 2 11 10 2 980.6754 -1 12 11 1 11 10 1 980.6754 -1 19 12 8 18 12 7 980.7974 -9 19 12 7 18 12 6 980.7974 -9 17 1 16 16 1 15 981.3967 -6 17 4 13 16 3 13 981.4452 -1 17 2 16 16 2 15 981.4689 8 13 10 3 12 9 3 982.8577 -3 13 10 4 12 9 4 982.8577 -3 18 2 16 17 2 15 982.9443 -4 12 12 1 11 11 1 983.1721 -2 12 12 0 11 11 0 983.1721 -2 13 5 8 12 2 10 983.6411 -5 16 5 12 15 4 12 984.1894 5 17 1 17 16 1 16 984.3972 -4* 17 0 17 16 0 16 984.3972 16* 13 11 2 12 10 2 985.2895 -6 13 11 3 12 10 3 985.2895 -6 15 2 14 14 1 14 985.5196 -1 16 2 14 15 1 14 985.5776 0 16 6 11 15 5 11 986.2063 5 18 1 17 17 1 16 986.5583 -5 15 8 7 14 7 7 986.9879 -4 15 8 8 14 7 8 986.9992 -2 14 10 4 13 9 4 987.3904 -3 14 10 5 13 9 5 987.3904 -5 13 12 1 12 11 1 987.7768 -3 13 12 2 12 11 2 987.7768 -3 16 7 9 15 6 9 988.7426 -1 16 7 10 15 6 10 988.7898 0 15 9 7 14 8 7 989.4028 -1 15 9 6 14 8 6 989.4259 -2 13 13 0 12 12 0 990.3352 -2 13 13 1 12 12 1 990.3352 -2 17 6 12 16 5 12 990.3818 4 16 8 8 15 7 8 991.2905 18* 16 8 9 15 7 9 991.3146 -5 16 1 15 15 0 15 991.6340 -3 19 1 18 18 1 17 991.6991 -4 19 2 18 18 2 17 991.7270 -1 16 2 15 15 1 15 991.7937 2 15 10 5 14 9 5 991.8537 -1 14 12 3 13 11 3 992.2933 2 14 12 2 13 11 2 992.2933 2 17 7 10 16 6 10 992.8286 -6 16 9 8 15 8 8 993.7514 -4 15 11 4 14 10 4 994.2507 -6 15 11 5 14 10 5 994.2507 -6 14 13 1 13 12 1 994.8350 -3 14 13 2 13 12 2 994.8350 -3 15 12 4 14 11 4 996.7191 -2 15 12 3 14 11 3 996.7191 -2 20 1 19 19 1 18 996.8169 2 20 2 19 19 2 18 996.8339 6 14 14 0 13 13 0 997.4786 -3 14 14 1 13 13 1 997.4786 -3 17 9 9 16 8 9 997.9944 -3 17 9 8 16 8 8 998.0188 -7* 16 11 6 15 10 6 998.5965 -3 16 11 5 15 10 5 998.5965 -3 15 13 2 14 12 2 999.2439 0 15 13 3 14 12 3 999.2439 0 20 0 20 19 0 19 1000.1421 -4 20 1 20 19 1 19 1000.1421 -8 16 12 5 15 11 5 1001.0555 -1 16 12 4 15 11 4 1001.0555 -1 15 14 2 14 13 2 1001.8862 -1 15 14 1 14 13 1 1001.8862 0 17 11 7 16 10 7 1002.8519 -2 17 11 6 16 10 6 1002.8519 -2 16 13 3 15 12 3 1003.5623 3 16 13 4 15 12 4 1003.5623 3 15 15 0 14 14 0 1004.6003 -3 15 15 1 14 14 1 1004.6003 -3 17 12 6 16 11 6 1005.3018 3 17 12 5 16 11 5 1005.3018 3 16 14 2 15 13 2 1006.2100 -2 16 14 3 15 13 3 1006.2100 -2 18 11 7 17 10 7 1007.0181 6 18 11 8 17 10 8 1007.0181 5 17 13 5 16 12 5 1007.7906 5 17 13 4 16 12 4 1007.7906 5 18 12 7 17 11 7 1009.4589 17* 18 12 6 17 11 6 1009.4589 17* 17 14 3 16 13 3 1010.4549 -5 17 14 4 16 13 4 1010.4549 -5 19 11 9 18 10 9 1011.0958 4* 19 11 8 18 10 8 1011.0958 11* 18 13 5 17 12 5 1011.9304 16* 18 13 6 17 12 6 1011.9304 16* 17 15 2 16 14 2 1013.1181 1 17 15 3 16 14 3 1013.1181 1 19 12 7 18 11 7 1013.5242 13* 19 12 8 18 11 8 1013.5242 13* 18 15 3 17 14 3 1017.2486 -1 18 15 4 17 14 4 1017.2486 -1