SUPPLEMENTARY TABLE 2 OBSERVED WAVENUMBERS FOR THE B- X 0-0 TRANSITION OF CALCIUM METHOXIDE CaO13CH3 ISOTOPOLOGUE br wavenumber obs-calc N" P11..17682.2202 0.0008 1 K' = K" = 0 17681.9937 0.0042 2 17681.7649 0.0022 3 17681.5400 0.0009 4 17681.3229 0.0044 5 17681.1017 0.0008 6 17680.8876 0.0011 7 17680.6764 0.0013 8 17680.4679 0.0011 9 17680.2619 0.0003 10 17680.0593 -0.0001 11 17679.8608 0.0004 12 17679.6700 0.0057 13 17679.4719 0.0005 14 17679.2807 -0.0008 15 17679.0936 -0.0011 16 17678.9098 -0.0012 17 17678.7280 -0.0022 18 17678.5529 0.0003 19 17678.3764 -0.0016 20 17678.2063 -0.0001 21 17678.0382 0.0003 22 17677.8758 0.0033 23 17677.7096 -0.0004 24 17677.5525 0.0019 25 17677.3961 0.0019 26 17677.2417 0.0008 27 17677.0952 0.0047 28 17676.9449 0.0017 29 17676.8037 0.0048 30 17676.6603 0.0027 31 17676.5208 0.0016 32 R11 17682.6688 0.0036 0 17682.8876 -0.0010 1 17683.1147 -0.0004 2 17683.3449 0.0002 3 17683.5774 0.0001 4 17683.8112 -0.0019 5 17684.0507 -0.0012 6 17684.2926 -0.0011 7 17684.5397 0.0011 8 17684.7879 0.0013 9 17685.0357 -0.0020 10 17685.2929 0.0011 11 17685.5484 -0.0005 12 17685.8099 0.0008 13 17686.0721 -0.0002 14 17686.3362 -0.0024 15 17686.6076 -0.0003 16 17686.8800 -0.0003 17 17687.1565 0.0008 18 17687.4344 0.0004 19 17687.7126 -0.0029 20 17687.9994 -0.0005 21 17688.2876 0.0003 22 17688.5777 -0.0001 23 17688.8733 0.0021 24 17689.1709 0.0033 25 17689.4661 -0.0009 26 17689.7713 0.0019 27 17690.0782 0.0034 28 17690.3860 0.0029 29 17690.6983 0.0039 30 17691.0155 0.0069 31 17691.3327 0.0069 32 17691.6539 0.0080 33 P22 17682.0090 -0.0044 2 17681.8038 0.0015 3 17681.5970 0.0027 4 17681.3909 0.0015 5 17681.1867 -0.0009 6 17680.9909 0.0021 7 17680.7948 0.0016 8 17680.6020 0.0014 9 17680.4152 0.0041 10 17680.2251 0.0004 11 17680.0423 0.0009 12 17679.8608 -0.0004 13 17679.6840 0.0000 14 17679.5113 0.0013 15 17679.3391 0.0001 16 17679.1727 0.0016 17 17679.0082 0.0019 18 17678.8448 0.0002 19 17678.6826 -0.0033 20 17678.5300 -0.0003 21 17678.3764 -0.0014 22 17678.2274 -0.0010 23 17678.0783 -0.0037 24 17677.9388 0.0001 25 17677.8004 0.0019 26 17677.6499 -0.0114 27 R22 17682.9279 0.0005 1 17683.1694 -0.0002 2 17683.4166 0.0017 3 17683.6658 0.0026 4 17683.9143 -0.0003 5 17684.1701 0.0010 6 17684.4273 0.0006 7 17684.6898 0.0024 8 17684.9550 0.0039 9 17685.2185 0.0006 10 17685.4881 0.0003 11 17685.7622 0.0015 12 17686.0394 0.0026 13 17686.3223 0.0065 14 17686.5945 -0.0035 15 17686.8801 -0.0031 16 17687.1716 0.0002 17 17687.4634 0.0006 18 17687.7562 -0.0009 19 17688.0507 -0.0038 20 17688.3543 -0.0007 21 17688.6575 -0.0010 22 17688.9634 -0.0016 23 17689.2716 -0.0030 24 17689.5841 -0.0031 25 17689.9072 0.0044 26 ------------------------------------------------ P11 17681.9783 0.0031 2 K' = K" = 1 17681.7491 0.0011 3 17681.5213 -0.0027 4 17681.3008 -0.0025 5 17681.0840 -0.0016 6 17680.8685 -0.0026 7 17680.6587 -0.0010 8 17680.4519 0.0006 9 17680.2454 -0.0007 10 17680.0423 -0.0016 11 17679.8441 -0.0007 12 17679.6500 0.0012 13 17679.2641 -0.0018 15 17679.0780 -0.0010 16 17678.8934 -0.0019 17 17678.7143 -0.0002 18 17678.5344 -0.0025 19 17677.2165 -0.0085 27 17677.0688 -0.0058 28 17676.9203 -0.0069 29 17676.7736 -0.0093 30 17676.6385 -0.0030 31 17676.4992 -0.0040 32 17676.3623 -0.0055 33 17676.2339 -0.0015 34 17676.1018 -0.0042 35 R11 17682.8726 -0.0013 1 17683.0944 -0.0057 2 17683.3292 -0.0003 3 17683.5614 -0.0006 4 17683.7955 -0.0022 5 17684.0334 -0.0030 6 17684.2749 -0.0033 7 17684.5214 -0.0016 8 17684.7716 0.0006 9 17685.0184 -0.0036 10 17685.2759 -0.0001 11 17685.7916 -0.0017 13 17686.0554 -0.0011 14 17686.3189 -0.0039 15 17686.5945 0.0024 16 17686.8663 0.0019 17 17689.1441 -0.0073 25 17689.4436 -0.0072 26 17689.7468 -0.0064 27 17690.0494 -0.0091 28 17690.3623 -0.0045 29 17690.6735 -0.0045 30 17690.9910 -0.0012 31 17691.3102 0.0008 32 17691.6271 -0.0023 33 P22 17681.9937 -0.0009 2 17681.7875 0.0025 3 17681.5787 0.0012 4 17681.3742 0.0013 5 17681.1711 -0.0001 6 17680.9736 0.0011 7 17680.7755 -0.0014 8 17680.5813 -0.0031 9 17680.3989 0.0039 10 17680.2087 0.0001 11 17680.0259 0.0006 12 17679.8441 -0.0010 13 17679.6700 0.0020 14 17679.4942 0.0003 15 17679.3271 0.0041 16 17679.1563 0.0012 17 17678.9902 0.0000 18 17678.8298 0.0013 19 17678.6696 -0.0002 20 17678.5145 0.0002 21 17678.3634 0.0017 22 17678.2109 -0.0014 23 17678.0706 0.0047 24 17677.9248 0.0022 25 17677.7837 0.0014 26 17677.6499 0.0048 27 17677.2550 0.0032 30 17677.1269 0.0001 31 R22 17682.9107 0.0007 1 17683.1524 -0.0003 2 17683.3966 -0.0016 3 17683.6474 0.0007 4 17683.8983 0.0000 5 17684.1501 -0.0027 6 17684.4063 -0.0041 7 17684.6738 0.0027 8 17684.9370 0.0021 9 17685.2029 0.0012 10 17685.4724 0.0008 11 17685.7462 0.0017 12 17686.0218 0.0012 13 17686.3016 0.0020 14 17686.5785 -0.0033 15 17686.8663 -0.0007 16 17687.1541 -0.0011 17 17687.4465 0.0000 18 17687.7409 0.0000 19 17688.0374 -0.0009 20 17688.3389 0.0002 21 17688.6425 0.0003 22 17688.9494 0.0007 23 17689.2576 -0.0006 24 17689.5735 0.0027 25 17689.8807 -0.0057 26 17690.2079 0.0029 27 17690.5308 0.0042 28 17690.8537 0.0024 29 17691.5108 0.0013 31 ------------------------------------------------- P11 17681.7025 -0.0011 3 K" = K" = 2 17681.4803 0.0014 4 17681.2564 -0.0013 5 17681.0390 -0.0008 6 17680.8251 0.0000 7 17680.6031 -0.0104 8 17680.3966 -0.0084 9 17680.2012 0.0015 10 17679.9989 0.0015 11 17679.7954 -0.0029 12 17679.6006 -0.0016 13 17679.2190 -0.0002 15 17679.0356 0.0032 16 17678.8461 -0.0024 17 17678.6669 -0.0009 18 17678.4922 0.0021 19 17678.3167 0.0012 20 17678.1473 0.0034 21 17677.9792 0.0039 22 R11 17683.0528 -0.0022 2 17683.2832 -0.0007 3 17683.5154 -0.0007 4 17683.7519 0.0004 5 17683.9897 -0.0003 6 17684.2302 -0.0015 7 17684.4771 0.0007 8 17684.7222 -0.0020 9 17684.9754 0.0002 10 17685.2316 0.0025 11 17685.4881 0.0019 12 17685.7462 -0.0001 13 17686.0112 0.0018 14 17686.2779 0.0023 15 17686.5451 0.0003 16 17686.8190 0.0019 17 17687.0954 0.0030 18 17687.3746 0.0039 19 17687.6548 0.0027 20 17687.9400 0.0036 21 17688.2295 0.0057 22 17688.5217 0.0076 23 17688.8096 0.0021 24 17689.1124 0.0086 25 P22 17681.7308 -0.0023 3 17681.5207 -0.0064 4 17681.3229 -0.0003 5 17681.1201 -0.0019 6 17680.9263 0.0026 7 17680.7301 0.0018 8 17680.5357 -0.0003 9 17680.3469 0.0002 10 17680.1601 -0.0003 11 17679.9789 0.0017 12 17679.7954 -0.0017 13 17679.6176 -0.0024 14 17679.4398 -0.0062 15 17679.2807 0.0056 16 17679.1062 -0.0010 17 17678.9442 0.0017 18 17678.7779 -0.0028 19 17678.6206 -0.0015 20 17678.4655 -0.0011 21 17678.3167 0.0026 22 R22 17683.0975 -0.0046 2 17683.3440 -0.0044 3 17683.5972 -0.0002 4 17683.8493 0.0001 5 17684.1052 0.0012 6 17684.3617 0.0000 7 17684.6242 0.0017 8 17684.8850 -0.0014 9 17685.1502 -0.0031 10 17685.4227 -0.0005 11 17685.6955 -0.0007 12 17685.9751 0.0029 13 17686.2499 -0.0014 14 17686.5314 -0.0021 15 17686.8190 0.0003 16 17687.1064 -0.0005 17 17687.3980 -0.0002 18 17687.6935 0.0009 19 17687.9917 0.0017 20 ------------------------------------------------- P11 17681.4001 -0.0038 4 K" = K" = 3 17681.1870 0.0051 5 17680.9636 0.0000 6 17680.7463 -0.0023 7 17680.5359 -0.0009 8 17680.3280 -0.0002 9 17680.1222 -0.0005 10 17679.9191 -0.0013 11 17679.7180 -0.0033 12 17679.5242 -0.0010 13 17679.3391 0.0069 14 17679.1402 -0.0021 15 17678.9563 0.0008 16 17678.7723 0.0005 17 17678.5915 0.0003 18 17678.4187 0.0051 19 17678.2342 -0.0048 20 17678.0708 0.0032 21 17677.9050 0.0058 22 R11 17683.2041 -0.0039 3 17683.4372 -0.0025 4 17683.6800 0.0053 5 17683.9166 0.0036 6 17684.1537 -0.0007 7 17684.3985 -0.0006 8 17684.6467 -0.0001 9 17684.8967 -0.0010 10 17685.1523 0.0007 11 17685.4078 -0.0008 12 17685.6710 0.0023 13 17685.9328 0.0009 14 17686.1984 0.0003 15 17686.4655 -0.0019 16 17686.7384 -0.0013 17 17687.0143 -0.0008 18 17687.2965 0.0030 19 17687.5743 -0.0006 20 P22 branch... exp_fr o-c N" 17681.4345 -0.0086 4 17681.2456 0.0050 5 17681.0405 0.0003 6 17680.8474 0.0050 7 17680.6493 0.0018 8 17680.4521 -0.0034 9 17680.2620 -0.0045 10 17680.0885 0.0080 11 17679.9007 0.0032 12 17679.7209 0.0033 13 17679.5381 -0.0027 14 17679.3667 -0.0003 15 17679.1929 -0.0034 16 17679.0283 -0.0003 17 17678.8608 -0.0033 18 17678.7006 -0.0020 19 17678.5344 -0.0097 20 17678.3793 -0.0095 21 R22 17683.2705 0.0051 3 17683.5156 0.0004 4 17683.7698 0.0022 5 17684.0278 0.0050 6 17684.2793 -0.0015 7 17684.8082 0.0022 9 17685.0736 0.0005 10 17685.3441 0.0009 11 17685.6170 0.0007 12 17685.9015 0.0090 13 17686.1707 -0.0011 14 17686.4502 -0.0039 15 17686.7384 -0.0011 16 17687.0375 0.0096 17 17687.3168 -0.0026 18 17687.6067 -0.0072 19 ============================================================= =============================================================