The supplementary material contains a complete list of all the the observed lines used to determine the final molecular constants. It is a standard .txt file that can be viewed using notepad, wordpad, textpad etc. Line Positions in cm-1 for the B8-X8, B'8-X8 and C7-X2(7) Transitions of HoF HoF A-X 0-0 Band WAVENUMBER J OBS-CALC 19092.3043 P 24. -0.0081 19090.9515 P 25. -0.0032 19089.5638 P 26. 0.0015 19088.1295 P 27. -0.0058 19086.6652 P 28. -0.0084 19085.1708 P 29. -0.0065 19083.6431 P 30. -0.0033 19082.0820 P 31. 0.0011 19080.4842 P 32. 0.0034 19078.8431 P 33. -0.0029 19077.1753 P 34. -0.0013 19075.4741 P 35. 0.0014 19073.7329 P 36. -0.0012 19071.9583 P 37. -0.0027 19070.1510 P 38. -0.0023 19068.3098 P 39. -0.0013 19066.4351 P 40. 0.0009 19064.5205 P 41. -0.0024 19062.5791 P 42. 0.0022 19060.5944 P 43. -0.0021 19058.5930 P 44. 0.0115 19056.5316 P 45. -0.0004 19054.4402 P 46. -0.0078 19052.3220 P 47. -0.0075 19050.1780 P 48. 0.0014 19047.9898 P 49. 0.0007 19045.7683 P 50. 0.0011 19043.5067 P 51. -0.0042 19041.2251 P 52. 0.0050 19038.8902 P 53. -0.0047 19036.5385 P 54. 0.0033 19034.1435 P 55. 0.0023 19031.7126 P 56. -0.0002 19029.2475 P 57. -0.0025 19026.7458 P 58. -0.0071 19024.2241 P 59. 0.0026 19021.6589 P 60. 0.0032 19019.0405 P 61. -0.0151 19016.4253 P 62. 0.0040 19013.7587 P 63. 0.0060 19008.3149 P 65. 0.0021 19005.5364 P 66. -0.0052 19002.7344 P 67. -0.0017 18999.9225 P 68. 0.0260 18997.0338 P 69. 0.0110 19112.5658 Q 10. -0.0123 19112.2130 Q 11. 0.0173 19111.7986 Q 12. 0.0201 19111.3450 Q 13. 0.0185 19110.8580 Q 14. 0.0182 19110.3310 Q 15. 0.0127 19109.7639 Q 16. 0.0018 19109.1668 Q 17. -0.0043 19107.8708 Q 19. -0.0139 19107.1904 Q 20. 0.0010 19106.4732 Q 21. 0.0139 19105.6993 Q 22. 0.0048 19104.8888 Q 23. -0.0060 19104.0537 Q 24. -0.0068 19103.1876 Q 25. -0.0037 19102.2870 Q 26. -0.0004 19101.3463 Q 27. -0.0025 19100.3756 Q 28. 0.0003 19099.3616 Q 29. -0.0056 19098.3276 Q 30. 0.0034 19097.2501 Q 31. 0.0036 19096.1327 Q 32. -0.0014 19094.9886 Q 33. 0.0017 19093.8044 Q 34. -0.0005 19092.5936 Q 35. 0.0054 19091.3394 Q 36. 0.0026 19090.0405 Q 37. -0.0101 19088.7333 Q 38. 0.0036 19087.3790 Q 39. 0.0050 19085.9880 Q 40. 0.0044 19084.5604 Q 41. 0.0019 19083.1060 Q 42. 0.0073 19081.6117 Q 43. 0.0076 19080.0773 Q 44. 0.0025 19078.5029 Q 45. -0.0079 19076.9051 Q 46. -0.0070 19075.2806 Q 47. 0.0018 19073.6128 Q 48. 0.0021 19071.9003 Q 49. -0.0076 19070.1511 Q 50. -0.0194 19068.4024 Q 51. 0.0040 19066.5848 Q 52. -0.0068 19064.7540 Q 53. 0.0038 19062.8793 Q 54. 0.0052 19060.9647 Q 55. 0.0013 19059.0233 Q 56. 0.0052 19057.0286 Q 57. -0.0096 19055.0339 Q 58. 0.0102 19052.9758 Q 59. 0.0012 19050.8718 Q 60. -0.0191 19048.7803 Q 61. 0.0076 19046.6222 Q 62. 0.0023 19044.4340 Q 63. 0.0013 19042.2258 Q 64. 0.0149 19039.9476 Q 65. -0.0070 19037.6626 Q 66. -0.0012 19035.3244 Q 67. -0.0142 19030.5750 Q 69. -0.0099 19025.6875 Q 71. -0.0061 19023.2005 Q 72. 0.0041 19020.6549 Q 73. -0.0100 19015.5102 Q 75. 0.0111 19118.1830 R 14. -0.0034 19118.1564 R 15. 0.0021 19118.0793 R 16. -0.0080 19117.9729 R 17. -0.0127 19117.8328 R 18. -0.0161 19117.6727 R 19. -0.0048 19117.4759 R 20. 0.0048 19117.2190 R 21. -0.0109 19116.9455 R 22. -0.0084 19116.6420 R 23. -0.0009 19116.2951 R 24. -0.0020 19115.9115 R 25. -0.0050 19115.4979 R 26. -0.0030 19115.0475 R 27. -0.0030 19114.5672 R 28. 0.0020 19114.0469 R 29. 0.0019 19113.4898 R 30. -0.0001 19112.8994 R 31. -0.0005 19112.2790 R 32. 0.0040 19111.6185 R 33. 0.0033 19110.9214 R 34. 0.0009 19110.1909 R 35. 0.0000 19109.4286 R 36. 0.0022 19107.7974 R 38. 0.0047 19106.9302 R 39. 0.0068 19106.0296 R 40. 0.0103 19105.0889 R 41. 0.0087 19104.1149 R 42. 0.0086 19103.0997 R 43. 0.0023 19102.0532 R 44. -0.0004 19100.9761 R 45. 0.0012 19099.8720 R 46. 0.0106 19098.7145 R 47. 0.0016 19097.5137 R 48. -0.0158 19096.3043 R 49. -0.0069 19095.0652 R 50. 0.0072 19092.4502 R 52. 0.0033 19091.0926 R 53. 0.0035 19089.6978 R 54. 0.0015 19088.2743 R 55. 0.0056 19086.8007 R 56. -0.0056 19085.3120 R 57. 0.0030 19083.7760 R 58. -0.0008 19070.2515 R 66. -0.0148 HoF A-X 1-0 Band WAVENUMBER J OBS-CALC 19633.1838 P 15. 0.0175 19632.1003 P 16. 0.0494 19630.8947 P 17. -0.0024 19629.7338 P 18. 0.0287 19628.4727 P 19. -0.0025 19627.1693 P 20. -0.0381 19625.9045 P 21. 0.0025 19624.5502 P 22. -0.0089 19623.1783 P 23. -0.0006 19621.7529 P 24. -0.0086 19620.3140 P 25. 0.0067 19618.8108 P 26. -0.0053 19617.2497 P 27. -0.0387 19615.7157 P 28. -0.0083 19614.0775 P 29. -0.0458 19612.5064 P 30. 0.0201 19610.6815 P 31. -0.1315 19609.0057 P 32. -0.0978 19607.4362 P 33. 0.0783 19605.6907 P 34. 0.1145 19590.0212 P 42. 0.0084 19587.9230 P 43. 0.0221 19585.7515 P 44. 0.0005 19583.5604 P 45. -0.0022 19643.0875 Q 10. 0.0756 19642.6472 Q 11. 0.0713 19642.1502 Q 12. 0.0493 19641.6365 Q 13. 0.0495 19641.0595 Q 14. 0.0252 19640.4439 Q 15. 0.0008 19639.8353 Q 16. 0.0219 19639.1219 Q 17. -0.0235 19638.4795 Q 18. 0.0401 19637.6426 Q 19. -0.0529 19636.9054 Q 20. -0.0084 19636.0749 Q 21. -0.0196 19635.2343 Q 22. -0.0036 19634.3370 Q 23. -0.0070 19633.3983 Q 24. -0.0148 19632.4146 Q 25. -0.0306 19631.4081 Q 26. -0.0324 19630.3800 Q 27. -0.0192 19629.2739 Q 28. -0.0474 19628.2256 Q 29. 0.0186 19627.0872 Q 30. 0.0309 19625.7645 Q 31. -0.1048 19624.7209 Q 32. 0.0749 19623.5000 Q 33. 0.1136 19612.0084 Q 41. 0.0140 19610.4444 Q 42. 0.0413 19608.7772 Q 43. 0.0036 19607.1171 Q 44. 0.0117 19605.4639 Q 45. 0.0658 19603.5836 Q 46. -0.0673 19601.7957 Q 47. -0.0675 19599.9677 Q 48. -0.0667 19648.1774 R 9. -0.0808 19648.2942 R 10. -0.0525 19648.3809 R 11. -0.0152 19648.4176 R 12. 0.0111 19648.4176 R 13. 0.0395 19648.2942 R 14. -0.0169 19648.1774 R 15. -0.0282 19648.0673 R 16. 0.0056 19647.8772 R 17. -0.0025 19647.6340 R 18. -0.0257 19647.3802 R 19. -0.0216 19647.0836 R 20. -0.0228 19646.7601 R 21. -0.0133 19646.3864 R 22. -0.0166 19645.9795 R 23. -0.0160 19645.5416 R 24. -0.0094 19645.0389 R 25. -0.0307 19644.5185 R 26. -0.0328 19643.9561 R 27. -0.0404 19643.4211 R 28. 0.0161 19642.8087 R 29. 0.0317 19642.1616 R 30. 0.0490 19641.4895 R 31. 0.0777 19640.7796 R 32. 0.1051 19633.4711 R 40. 0.0159 19632.4103 R 41. 0.0256 19631.2795 R 42. 0.0037 19630.1378 R 43. 0.0098 19629.0046 R 44. 0.0638 19627.6355 R 45. -0.0782 19626.3748 R 46. -0.0710 19625.0639 R 47. -0.0727 19623.7263 R 48. -0.0588 19622.3487 R 49. -0.0418 19620.9878 R 50. 0.0360 19619.6247 R 51. 0.1568 HoF B-X 0-0 Band WAVENUMBEER C J OBS-CAL 21670.4140 P 9. -0.0186 21669.6350 P 10. -0.0020 21668.8000 P 11. -0.0120 21667.9460 P 12. -0.0116 21667.0740 P 13. 0.0003 21666.1700 P 14. 0.0098 21665.2170 P 15. 0.0004 21664.2370 P 16. -0.0056 21663.2340 P 17. -0.0034 21662.2010 P 18. 0.0011 21661.1230 P 19. -0.0059 21660.0220 P 20. -0.0009 21658.8680 P 21. -0.0118 21657.6540 P 22. -0.0432 21656.5310 P 23. 0.0587 21653.8820 P 25. 0.0006 21652.4980 P 26. -0.0087 21675.1490 Q 8. -0.0054 21674.8880 Q 9. 0.0047 21674.5850 Q 10. 0.0022 21674.2520 Q 11. -0.0007 21673.9040 Q 12. 0.0108 21673.5090 Q 13. 0.0050 21673.0860 Q 14. 0.0013 21672.6020 Q 15. -0.0328 21672.1520 Q 16. -0.0016 21671.6390 Q 17. -0.0012 21671.0920 Q 18. -0.0012 21670.5010 Q 19. -0.0100 21669.8870 Q 20. -0.0046 21669.2090 Q 21. -0.0237 21668.5870 Q 22. 0.0556 21667.7700 Q 23. -0.0142 21666.9930 Q 24. 0.0058 21666.1270 Q 25. -0.0088 21679.6030 R 8. -0.0021 21679.8400 R 9. 0.0110 21680.0320 R 10. 0.0085 21680.2000 R 11. 0.0116 21680.3500 R 12. 0.0265 21680.4450 R 13. 0.0165 21679.2410 R 24. -0.0006 HoF B'-X 0-0 Band WAVBENUMBER J OBS-CAL 21640.9950 P 9. -0.0232 21640.2080 P 10. -0.0175 21639.4560 P 11. 0.0410 21638.5960 P 12. 0.0057 21637.7610 P 13. 0.0056 21636.8970 P 14. -0.0176 21636.0580 P 15. -0.0143 21635.2280 P 16. -0.0054 21634.3930 P 17. -0.0100 21633.5520 P 18. -0.0341 21632.8040 P 19. 0.0157 21632.1190 P 20. 0.1038 21645.7200 Q 8. -0.0200 21645.4650 Q 9. -0.0068 21645.1910 Q 10. 0.0053 21644.8910 Q 11. 0.0055 21644.5840 Q 12. 0.0091 21644.2620 Q 13. 0.0036 21643.9360 Q 14. -0.0044 21643.6170 Q 15. -0.0086 21643.2830 Q 16. -0.0362 21643.0200 Q 17. -0.0064 21642.7430 Q 18. -0.0096 21642.5420 Q 19. 0.0387 21642.2720 Q 20. -0.0123 21650.1990 R 8. 0.0054 21650.4470 R 9. 0.0150 21650.6720 R 10. 0.0158 21650.8920 R 11. 0.0219 21651.0790 R 12. 0.0011 21651.2810 R 13. -0.0032 21651.4980 R 14. 0.0043 21651.7110 R 15. -0.0004 21651.9380 R 16. -0.0047 21652.1800 R 17. -0.0128 21652.4960 R 18. 0.0285 21652.6940 R 19. -0.0784 HoF B'-X 1-0 Band WAVENUMBER J OBS-CALC 22160.0642 P 11. 0.0534 22159.1162 P 12. 0.0339 22158.1422 P 13. 0.0261 22157.1082 P 14. -0.0038 22156.0508 P 15. -0.0189 22154.9726 P 16. -0.0164 22153.8442 P 17. -0.0255 22152.6940 P 18. -0.0175 22151.4932 P 19. -0.0210 22150.2544 P 20. -0.0232 22148.9736 P 21. -0.0278 22147.6597 P 22. -0.0259 22146.3017 P 23. -0.0282 22144.9176 P 24. -0.0167 22143.4781 P 25. -0.0205 22142.0087 P 26. -0.0140 22138.9516 P 28. 0.0008 22137.3642 P 29. 0.0093 22134.0766 P 31. 0.0325 22132.3749 P 32. 0.0452 22130.6287 P 33. 0.0520 22128.8392 P 34. 0.0539 22126.9895 P 35. 0.0331 22125.0982 P 36. 0.0077 22123.1569 P 37. -0.0317 22119.2192 P 39. -0.0614 22117.1761 P 40. -0.1008 22115.1812 P 41. -0.0607 22166.5318 Q 8. 0.0544 22166.1961 Q 9. 0.0480 22165.8149 Q 10. 0.0333 22165.3926 Q 11. 0.0151 22164.9536 Q 12. 0.0180 22164.4666 Q 13. 0.0108 22163.9195 Q 14. -0.0182 22163.3775 Q 15. -0.0037 22162.7738 Q 16. -0.0122 22162.1350 Q 17. -0.0168 22161.4595 Q 18. -0.0189 22160.7441 Q 19. -0.0215 22159.9902 Q 20. -0.0231 22159.1970 Q 21. -0.0241 22158.3657 Q 22. -0.0233 22157.4868 Q 23. -0.0300 22156.5795 Q 24. -0.0249 22155.6271 Q 25. -0.0247 22154.6481 Q 26. -0.0109 22153.6174 Q 27. -0.0086 22152.5562 Q 28. 0.0033 22151.4932 Q 29. 0.0532 22150.3226 Q 30. 0.0352 22149.1449 Q 31. 0.0494 22147.9174 Q 32. 0.0527 22146.6599 Q 33. 0.0643 22145.3256 Q 34. 0.0370 22143.9546 Q 35. 0.0100 22142.5358 Q 36. -0.0286 22139.6389 Q 38. -0.0604 22128.8392 Q 45. 0.1182 22171.1712 R 10. 0.0230 22171.2435 R 11. 0.0127 22171.2435 R 13. -0.0380 22171.2435 R 14. -0.0057 22171.1712 R 15. -0.0070 22171.0562 R 16. -0.0119 22170.8980 R 17. -0.0207 22170.7021 R 18. -0.0278 22170.4804 R 19. -0.0209 22170.2123 R 20. -0.0206 22169.9070 R 21. -0.0174 22169.5614 R 22. -0.0144 22169.1749 R 23. -0.0120 22168.7479 R 24. -0.0097 22168.2859 R 25. -0.0021 22167.7856 R 26. 0.0075 22167.2458 R 27. 0.0177 22166.6684 R 28. 0.0304 22166.0419 R 29. 0.0337 22165.3926 R 30. 0.0537 22164.6817 R 31. 0.0512 22163.9409 R 32. 0.0572 22163.1373 R 33. 0.0384 22162.2918 R 34. 0.0150 22161.3885 R 35. -0.0300 22159.5399 R 37. -0.0567 22158.5442 R 38. -0.0912 22157.5741 R 39. -0.0684 22156.6466 R 40. 0.0271 HoF B-X 3-0 Band WAVENUMBER J OBS-CALC 23180.3961 P 11. 0.1324 23179.2964 P 12. 0.0651 23178.1119 P 13. -0.0418 23176.9724 P 14. -0.0584 23175.7657 P 15. -0.0970 23174.5321 P 16. -0.1172 23173.2695 P 17. -0.1212 23171.9827 P 18. -0.1038 23170.7063 P 19. -0.0301 23169.3904 P 20. 0.0505 23168.0095 P 21. 0.1129 23166.5451 P 22. 0.1396 23164.9717 P 23. 0.1059 23163.3892 P 24. 0.1130 23161.6934 P 25. 0.0580 23159.9252 P 26. -0.0165 23158.1059 P 27. -0.0871 23156.2400 P 28. -0.1473 23187.1208 Q 8. 0.2070 23186.6544 Q 9. 0.1574 23186.1373 Q 10. 0.1028 23185.5750 Q 11. 0.0485 23184.9646 Q 12. -0.0086 23184.3191 Q 13. -0.0555 23183.6404 Q 14. -0.0903 23182.9263 Q 15. -0.1152 23182.1895 Q 16. -0.1175 23181.4315 Q 17. -0.0953 23180.6785 Q 18. -0.0221 23179.8727 Q 19. 0.0447 23179.0239 Q 20. 0.1155 23178.1119 Q 21. 0.1709 23176.9724 Q 22. 0.0476 23176.0365 Q 23. 0.1778 23174.8073 Q 24. 0.0661 23173.5598 Q 25. -0.0109 23172.2584 Q 26. -0.0868 23170.9171 Q 27. -0.1453 23169.5341 Q 28. -0.1856 23168.3020 Q 29. -0.0121 23166.9307 Q 30. 0.0884 23165.4632 Q 31. 0.1629 23191.1538 R 9. -0.1270 23191.3080 R 10. 0.0108 23191.2550 R 11. -0.0133 23191.1500 R 12. -0.0441 23190.9889 R 13. -0.0856 23190.7976 R 14. -0.1120 23190.5786 R 15. -0.1205 23190.3479 R 16. -0.0951 23190.1121 R 17. -0.0288 23189.8304 R 18. 0.0382 23189.5092 R 19. 0.1127 23189.0925 R 20. 0.1397 23188.5746 R 21. 0.1143 23188.0347 R 22. 0.1170 23185.8924 R 25. -0.0818 23185.0765 R 26. -0.1381 23184.2116 R 27. -0.1832 23183.5098 R 28. -0.0023 23182.6608 R 29. 0.0978 HoF B-X 4-0 Band WAVENUMBER J OBS-CALC 23687.1308 P 9. 0.0011 23686.1463 P 10. -0.0021 23685.1091 P 11. -0.0074 23684.0450 P 12. 0.0112 23682.8959 P 13. -0.0047 23681.7107 P 14. -0.0061 23680.4742 P 15. -0.0083 23679.1910 P 16. -0.0069 23677.8559 P 17. -0.0072 23676.4743 P 18. -0.0040 23675.0383 P 19. -0.0053 23673.5573 P 20. -0.0022 23672.0323 P 21. 0.0061 23670.4485 P 22. 0.0045 23668.8233 P 23. 0.0098 23667.1429 P 24. 0.0077 23665.3960 P 25. -0.0136 23663.6548 P 26. 0.0173 23661.8168 P 27. -0.0028 23659.9352 P 28. -0.0217 23658.0805 P 29. 0.0302 23691.8609 Q 8. 0.0094 23691.4006 Q 9. 0.0059 23689.7211 Q 12. 0.0010 23689.0600 Q 13. -0.0006 23688.3505 Q 14. -0.0001 23687.5880 Q 15. -0.0021 23686.7768 Q 16. -0.0026 23685.9156 Q 17. -0.0030 23685.0081 Q 18. 0.0002 23684.0450 Q 19. -0.0026 23683.0409 Q 20. 0.0029 23681.9848 Q 21. 0.0053 23680.8822 Q 22. 0.0097 23679.7253 Q 23. 0.0076 23678.5108 Q 24. -0.0046 23677.2877 Q 25. 0.0211 23675.9502 Q 26. -0.0216 23696.0095 R 11. -0.0058 23695.8864 R 12. 0.0063 23695.6969 R 13. 0.0025 23695.4601 R 14. 0.0020 23695.1718 R 15. 0.0002 23694.8342 R 16. -0.0006 23694.4456 R 17. -0.0026 23694.0141 R 18. 0.0023 23693.5254 R 19. -0.0006 23692.9991 R 20. 0.0078 23692.4113 R 21. 0.0033 23691.7825 R 22. 0.0058 23691.0920 R 23. -0.0059 23690.3716 R 24. -0.0008 23689.5825 R 25. -0.0183 23688.7421 R 26. -0.0421 23687.9482 R 27. 0.0247 HoF C-X 0-0 Band WAVENUMBER J OBS-CAL 22207.9476 P 13. -0.0304 22207.2138 P 14. 0.0237 22206.3965 P 15. 0.0171 22205.5426 P 16. -0.0032 22204.6620 P 17. -0.0272 22203.8214 P 18. 0.0120 22202.9108 P 19. 0.0044 22201.9801 P 20. 0.0001 22201.0261 P 21. -0.0044 22200.0555 P 22. -0.0023 22199.0615 P 23. -0.0006 22198.0346 P 24. -0.0092 22195.9670 P 26. 0.0262 22193.7388 P 28. -0.0148 22192.6235 P 29. -0.0069 22191.5022 P 30. 0.0132 22190.3256 P 31. -0.0052 22215.3180 Q 9. 0.0265 22214.8400 Q 11. -0.0025 22214.5742 Q 12. -0.0102 22214.3001 Q 13. -0.0034 22213.9990 Q 14. -0.0006 22213.6729 Q 15. 0.0002 22213.3260 Q 16. 0.0035 22212.9525 Q 17. 0.0036 22212.5522 Q 18. 0.0003 22212.1285 Q 19. -0.0030 22211.6882 Q 20. 0.0006 22211.2246 Q 21. 0.0041 22210.7409 Q 22. 0.0105 22210.2172 Q 23. -0.0003 22209.6668 Q 24. -0.0155 22207.9476 Q 27. -0.0016 22207.3321 Q 28. 0.0003 22206.7067 Q 29. 0.0103 22206.0396 Q 30. -0.0048 22219.5500 R 7. -0.0010 22219.8602 R 8. -0.0075 22220.1604 R 9. -0.0018 22220.4373 R 10. 0.0031 22220.6808 R 11. -0.0026 22220.9076 R 12. -0.0022 22221.1096 R 13. -0.0034 22221.2863 R 14. -0.0066 22221.4513 R 15. 0.0020 22221.5848 R 16. 0.0026 22221.6895 R 17. -0.0019 22221.7849 R 18. 0.0079 22221.8532 R 19. 0.0141 22221.8519 R 23. -0.0041 22221.7849 R 24. -0.0195 22221.6410 R 26. 0.0018 22221.5330 R 27. 0.0056 22221.4090 R 28. 0.0112 22221.2435 R 29. -0.0083 C C : : : : : : O : : : : : : -6 -5 -4 -3 -2 -1 0 1 2 3 4 5 6