TABLE S1. The observed and the obs.-calc. frequencies (MHz) for the ground state of quinoline. ________________________________________________________________________ Quinoline ground state ________________________________________________________________________ Obs-calc differences are from fit of Watson's reduced Hamiltonian in ---> reduction-A, representation-I.r <--- TRANSITION Observed Obs-Calc Error ! ! FTMW quadrupole free frequencies ! 2, 1, 2 <- 1, 0, 1 5862.751 0.000 0.002 2, 2, 1 <- 2, 1, 2 6719.377 0.000 0.002 3, 2, 2 <- 3, 1, 3 7296.680 -0.001 0.002 4, 3, 1 <- 4, 2, 2 9786.884 -0.001 0.002 3, 3, 0 <- 3, 2, 1 10079.799 -0.001 0.002 3, 3, 1 <- 3, 2, 2 10312.905 -0.001 0.002 2, 2, 1 <- 1, 1, 0 10342.334 0.000 0.002 4, 3, 2 <- 4, 2, 3 10436.823 -0.001 0.002 5, 1, 5 <- 4, 0, 4 10589.180 0.001 0.002 5, 3, 3 <- 5, 2, 4 10672.933 -0.001 0.002 2, 2, 0 <- 1, 1, 1 10756.688 0.000 0.002 6, 0, 6 <- 5, 1, 5 11393.120 0.001 0.002 3, 2, 2 <- 2, 1, 1 12153.811 0.000 0.002 6, 1, 6 <- 5, 0, 5 12165.298 0.001 0.002 7, 0, 7 <- 6, 1, 6 13375.663 0.001 0.002 3, 2, 1 <- 2, 1, 2 13488.495 0.000 0.002 4, 2, 3 <- 3, 1, 2 13777.081 0.000 0.002 ! ! MMW bR-type transitions, for each frequency region these are: ! ! 1/ type-II bandheads ! 2/ lower-J miscellaneous non-bandhead transitions ! 92, 1, 92 <- 91, 0, 91 167536.591 -0.061 0.030 88, 5, 84 <- 87, 4, 83 167539.176 0.017 0.030 87, 6, 82 <- 86, 5, 81 167544.680 -0.029 0.030 86, 7, 80 <- 85, 6, 79 167554.242 -0.024 0.030 85, 8, 78 <- 84, 7, 77 167569.433 0.028 0.030 84, 9, 76 <- 83, 8, 75 167592.227 0.013 0.030 83, 10, 74 <- 82, 9, 73 167625.509 0.007 0.030 82, 11, 72 <- 81, 10, 71 167673.120 0.007 0.030 81, 12, 70 <- 80, 11, 69 167740.424 -0.014 0.030 79, 14, 66 <- 78, 13, 65 167969.353 -0.004 0.030 74, 16, 58 <- 73, 17, 57 165173.182 -0.016 0.030 76, 14, 62 <- 75, 15, 61 164602.535 -0.050 0.030 76, 15, 62 <- 75, 14, 61 164605.102 0.023 0.030 77, 14, 64 <- 76, 13, 63 164388.116 -0.059 0.030 77, 13, 64 <- 76, 14, 63 164388.116 0.062 0.030 78, 13, 66 <- 77, 12, 65 164239.589 0.010 0.030 27, 27, 1 <- 26, 26, 0 167792.882 -0.020 0.030 31, 24, 8 <- 30, 23, 7 164269.992 -0.024 0.030 33, 23, 11 <- 32, 22, 10 164543.894 0.000 0.030 39, 20, 20 <- 38, 19, 19 165185.908 0.008 0.030 41, 19, 23 <- 40, 18, 22 165257.599 0.006 0.030 43, 18, 26 <- 42, 17, 25 165168.621 0.076 0.030 48, 16, 33 <- 47, 15, 32 165307.505 0.011 0.030 49, 15, 34 <- 48, 14, 35 164489.505 0.041 0.030 !-------------------------------- 103, 1,103 <-102, 0,102 187453.027 -0.006 0.030 99, 5, 95 <- 98, 4, 94 187453.819 0.004 0.030 98, 6, 93 <- 97, 5, 92 187457.651 -0.006 0.030 97, 7, 91 <- 96, 6, 90 187464.361 -0.035 0.030 96, 8, 89 <- 95, 7, 88 187475.054 -0.032 0.030 95, 9, 87 <- 94, 8, 86 187491.053 -0.023 0.030 94, 10, 85 <- 93, 9, 84 187514.100 0.001 0.030 93, 11, 83 <- 92, 10, 82 187546.416 -0.001 0.030 92, 12, 81 <- 91, 11, 80 187590.989 -0.029 0.030 91, 13, 79 <- 90, 12, 78 187651.949 0.014 0.030 92, 13, 80 <- 91, 12, 79 189455.821 0.015 0.030 31, 30, 2 <- 30, 29, 1 188852.659 -0.020 0.030 35, 28, 8 <- 34, 27, 7 189428.317 -0.045 0.030 36, 27, 10 <- 35, 26, 9 187518.855 -0.046 0.030 !-------------------------------- 115, 1,115 <-114, 0,114 209177.342 0.022 0.030 114, 2,113 <-113, 1,112 209176.365 0.002 0.030 113, 3,111 <-112, 2,110 209175.742 0.015 0.030 112, 4,109 <-111, 3,108 209175.742 0.002 0.030 111, 5,107 <-110, 4,106 209176.828 0.028 0.030 110, 6,105 <-109, 5,104 209179.399 0.005 0.030 109, 7,103 <-108, 6,102 209184.116 -0.001 0.030 108, 8,101 <-107, 7,100 209191.699 -0.001 0.030 107, 9, 99 <-106, 8, 98 209203.059 0.013 0.030 106, 10, 97 <-105, 9, 96 209219.291 0.011 0.030 105, 11, 95 <-104, 10, 94 209241.852 0.038 0.030 104, 12, 93 <-103, 11, 92 209272.419 -0.017 0.030 103, 13, 91 <-102, 12, 90 209313.393 -0.049 0.030 102, 14, 89 <-101, 13, 88 209367.786 -0.032 0.030 101, 15, 87 <-100, 14, 86 209439.500 -0.014 0.030 100, 16, 85 <- 99, 15, 84 209533.887 0.020 0.030 99, 17, 83 <- 98, 16, 82 209658.273 -0.012 0.030 98, 18, 81 <- 97, 17, 80 209823.395 0.006 0.030 !-------------------------------- 116, 1,116 <-115, 0,115 210987.544 0.003 0.030 115, 2,114 <-114, 1,113 210986.580 -0.001 0.030 114, 3,112 <-113, 2,111 210985.914 -0.021 0.030 113, 4,110 <-112, 3,109 210985.914 -0.007 0.030 112, 5,108 <-111, 4,107 210986.936 0.005 0.030 111, 6,106 <-110, 5,105 210989.452 0.010 0.030 110, 7,104 <-109, 6,103 210994.039 0.008 0.030 109, 8,102 <-108, 7,101 211001.422 0.014 0.030 108, 9,100 <-107, 8, 99 211012.436 -0.016 0.030 107, 10, 98 <-106, 9, 97 211028.281 0.032 0.030 106, 11, 96 <-105, 10, 95 211050.150 -0.014 0.030 105, 12, 94 <-104, 11, 93 211079.900 -0.018 0.030 104, 13, 92 <-103, 12, 91 211119.747 0.036 0.030 103, 14, 90 <-102, 13, 89 211172.414 0.016 0.030 !-------------------------------- 119, 1,119 <-118, 0,118 216418.086 0.012 0.030 117, 3,115 <-116, 2,114 216416.392 -0.034 0.030 115, 5,111 <-114, 4,110 216417.172 -0.039 0.030 114, 6,109 <-113, 5,108 216419.497 0.014 0.030 113, 7,107 <-112, 6,106 216423.636 -0.056 0.030 112, 8,105 <-111, 7,104 216430.419 -0.073 0.030 111, 9,103 <-110, 8,102 216440.627 -0.061 0.030 110, 10,101 <-109, 9,100 216455.226 -0.041 0.030 109, 11, 99 <-108, 10, 98 216475.408 -0.050 0.030 108, 12, 97 <-107, 11, 96 216502.734 -0.070 0.030 107, 13, 95 <-106, 12, 94 216539.236 -0.018 0.030 106, 14, 93 <-105, 13, 92 216587.334 0.024 0.030 105, 15, 91 <-104, 14, 90 216650.258 0.031 0.030 104, 16, 89 <-103, 15, 88 216732.276 -0.039 0.030 103, 17, 87 <-102, 16, 86 216839.375 -0.036 0.030 102, 18, 85 <-101, 17, 84 216979.644 0.013 0.030 101, 19, 83 <-100, 18, 82 217164.660 -0.018 0.030 99, 20, 79 <- 98, 21, 78 217748.036 -0.004 0.030 99, 21, 79 <- 98, 20, 78 217752.893 0.019 0.030 !-------------------------------- 120, 1,120 <-119, 0,119 218228.248 0.041 0.030 116, 5,112 <-115, 4,111 218227.288 0.025 0.030 115, 6,110 <-114, 5,109 218229.494 0.033 0.030 114, 7,108 <-113, 6,107 218233.557 0.006 0.030 104, 17, 88 <-103, 16, 87 218636.348 0.018 0.030 35, 35, 1 <- 34, 34, 0 218100.857 0.009 0.030 35, 33, 3 <- 34, 32, 2 209910.714 0.013 0.030 37, 32, 6 <- 36, 31, 5 210200.002 0.004 0.030 43, 29, 15 <- 42, 28, 14 211033.497 0.036 0.030 38, 33, 6 <- 37, 32, 5 216488.107 -0.047 0.030 39, 33, 7 <- 38, 32, 6 218680.078 0.011 0.030 40, 32, 9 <- 39, 31, 8 216774.302 -0.036 0.030 41, 32, 10 <- 40, 31, 9 218964.722 -0.031 0.030 42, 31, 12 <- 41, 30, 11 217054.459 -0.015 0.030 46, 27, 20 <- 45, 26, 19 209338.612 -0.001 0.030 48, 26, 23 <- 47, 25, 22 209535.970 -0.011 0.030 48, 28, 21 <- 47, 27, 20 217809.650 -0.037 0.030 50, 25, 26 <- 49, 24, 25 209679.664 0.021 0.030 52, 24, 29 <- 51, 23, 28 209742.559 -0.006 0.030 54, 23, 32 <- 53, 22, 31 209682.515 0.023 0.030 54, 25, 30 <- 53, 24, 29 218214.337 0.003 0.030 56, 22, 35 <- 55, 21, 34 209429.767 0.037 0.030 56, 24, 33 <- 55, 23, 32 218164.923 0.005 0.030 58, 23, 36 <- 57, 22, 35 217938.340 0.041 0.030 61, 20, 42 <- 60, 19, 41 209320.491 0.032 0.030 61, 20, 41 <- 60, 19, 42 209624.506 -0.008 0.030 63, 21, 43 <- 62, 20, 42 218170.306 0.005 0.030 63, 19, 44 <- 62, 18, 45 209233.755 -0.023 0.030 66, 19, 47 <- 65, 18, 48 218871.489 0.017 0.030 65, 20, 45 <- 64, 19, 46 217125.097 0.019 0.030 89, 23, 67 <- 88, 22, 66 216821.737 0.057 0.030 93, 21, 72 <- 92, 22, 71 209361.638 -0.020 0.030 94, 21, 73 <- 93, 22, 72 211179.448 -0.083 0.030 95, 23, 73 <- 94, 22, 72 216614.310 0.010 0.030 96, 23, 74 <- 95, 22, 73 217901.128 0.023 0.030 97, 22, 76 <- 96, 21, 75 216568.147 -0.018 0.030 98, 21, 77 <- 97, 22, 76 218196.264 0.014 0.030 !-------------------------------- 128, 1,128 <-127, 0,127 232708.514 0.066 0.030 127, 2,126 <-126, 1,125 232707.470 0.015 0.030 125, 4,122 <-124, 3,121 232706.431 0.014 0.030 122, 7,116 <-121, 6,115 232711.855 0.004 0.030 120, 9,112 <-119, 8,111 232725.334 0.030 0.030 119, 10,110 <-118, 9,109 232736.900 0.008 0.030 118, 11,108 <-117, 10,107 232752.907 0.010 0.030 117, 12,106 <-116, 11,105 232774.448 -0.008 0.030 116, 13,104 <-115, 12,103 232802.961 -0.010 0.030 115, 14,102 <-114, 13,101 232840.184 -0.008 0.030 114, 15,100 <-113, 14, 99 232888.349 0.022 0.030 113, 16, 98 <-112, 15, 97 232950.208 0.008 0.030 111, 18, 94 <-110, 17, 93 233131.035 0.060 0.030 108, 21, 88 <-107, 20, 87 233648.645 0.009 0.030 106, 22, 84 <-105, 23, 83 234327.721 0.028 0.030 106, 23, 84 <-105, 22, 83 234335.858 0.016 0.030 105, 22, 83 <-104, 23, 82 232585.956 0.025 0.030 105, 23, 83 <-104, 22, 82 232599.708 -0.053 0.030 38, 37, 2 <- 37, 36, 1 232868.836 -0.020 0.030 40, 36, 5 <- 39, 35, 4 233159.250 0.029 0.030 44, 34, 11 <- 43, 33, 10 233731.449 0.010 0.030 48, 32, 17 <- 47, 31, 16 234274.611 -0.006 0.030 51, 30, 22 <- 50, 29, 21 232579.083 -0.010 0.030 55, 28, 28 <- 54, 27, 27 232937.645 -0.030 0.030 53, 29, 25 <- 52, 28, 24 232781.048 0.011 0.030 55, 28, 28 <- 54, 27, 27 232937.645 -0.030 0.030 61, 25, 37 <- 60, 24, 36 232882.180 -0.005 0.030 63, 24, 40 <- 62, 23, 39 232525.487 0.066 0.030 66, 23, 44 <- 65, 22, 43 233724.747 0.022 0.030 66, 23, 43 <- 65, 22, 44 233734.926 -0.001 0.030 69, 22, 48 <- 68, 21, 47 233687.830 0.008 0.030 99, 25, 75 <- 98, 24, 74 232563.258 -0.038 0.030 100, 25, 76 <- 99, 24, 75 232534.389 0.026 0.030 ! ! bQ-type transitions ! 95, 3, 93 <- 95, 2, 94 167579.371 0.050 0.030 101, 7, 94 <-101, 6, 95 164606.444 -0.032 0.030 104, 9, 95 <-104, 8, 96 164228.998 0.046 0.030 109, 12, 97 <-109, 11, 98 164249.094 0.003 0.030 111, 13, 99 <-111, 12,100 167930.953 -0.011 0.030 113, 14, 99 <-113, 13,100 165264.385 -0.040 0.030 116, 15,101 <-116, 14,102 167565.815 -0.005 0.030 116, 16,100 <-116, 15,101 164223.017 0.007 0.030 118, 16,102 <-118, 15,103 167966.004 -0.010 0.030 118, 17,101 <-118, 16,102 164556.025 0.000 0.030 122, 19,103 <-122, 18,104 165064.712 -0.020 0.030 124, 20,104 <-124, 19,105 165236.360 0.073 0.030 59, 41, 18 <- 59, 40, 19 165282.537 -0.014 0.030 60, 41, 19 <- 60, 40, 20 165228.443 0.015 0.030 61, 41, 20 <- 61, 40, 21 165171.490 -0.031 0.030 62, 41, 21 <- 62, 40, 22 165111.753 0.019 0.030 63, 41, 22 <- 63, 40, 23 165048.965 0.002 0.030 68, 41, 27 <- 68, 40, 28 164686.633 0.007 0.030 69, 41, 28 <- 69, 40, 29 164603.657 -0.018 0.030 70, 41, 29 <- 70, 40, 30 164517.008 0.054 0.030 71, 41, 30 <- 71, 40, 31 164426.374 0.033 0.030 72, 41, 31 <- 72, 40, 32 164331.670 -0.034 0.030 73, 41, 32 <- 73, 40, 33 164232.872 -0.044 0.030 78, 42, 36 <- 78, 41, 37 167941.405 -0.010 0.030 80, 42, 38 <- 80, 41, 39 167702.098 -0.028 0.030 81, 42, 39 <- 81, 41, 40 167575.212 0.017 0.030 95, 42, 53 <- 95, 41, 54 165188.502 0.007 0.030 98, 42, 56 <- 98, 41, 57 164498.804 0.043 0.030 99, 42, 57 <- 99, 41, 58 164252.071 0.007 0.030 113, 43, 70 <-113, 42, 71 164629.213 0.037 0.030 117, 44, 73 <-117, 43, 74 167991.024 -0.021 0.030 118, 44, 74 <-118, 43, 75 167593.740 0.021 0.030 93, 47, 46 <- 93, 46, 47 187451.027 -0.019 0.030 92, 47, 45 <- 92, 46, 46 187588.305 -0.071 0.030 91, 47, 44 <- 91, 46, 45 187721.070 0.023 0.030 81, 47, 34 <- 81, 46, 35 188817.387 -0.044 0.030 73, 47, 26 <- 73, 46, 27 189440.799 0.031 0.030 115, 48, 67 <-115, 47, 68 187555.865 -0.036 0.030 107, 48, 59 <-107, 47, 60 189426.561 -0.061 0.030 130, 49, 81 <-130, 48, 82 187472.174 0.023 0.030 80, 52, 28 <- 80, 51, 29 209847.180 -0.054 0.030 81, 52, 29 <- 81, 51, 30 209782.034 0.040 0.030 82, 52, 30 <- 82, 51, 31 209714.290 0.014 0.030 83, 52, 31 <- 83, 51, 32 209644.006 -0.005 0.030 84, 52, 32 <- 84, 51, 33 209571.126 -0.007 0.030 85, 52, 33 <- 85, 51, 34 209495.602 0.029 0.030 86, 52, 34 <- 86, 51, 35 209417.296 0.036 0.030 87, 52, 35 <- 87, 51, 36 209336.108 -0.012 0.030 88, 52, 36 <- 88, 51, 37 209252.135 0.054 0.030 89, 52, 37 <- 89, 51, 38 209165.054 -0.016 0.030 56, 54, 2 <- 56, 53, 3 219047.872 -0.031 0.030 57, 54, 3 <- 57, 53, 4 219027.448 0.016 0.030 58, 54, 4 <- 58, 53, 5 219005.899 0.011 0.030 59, 54, 5 <- 59, 53, 6 218983.263 0.030 0.030 60, 54, 6 <- 60, 53, 7 218959.421 -0.008 0.030 62, 54, 8 <- 62, 53, 9 218908.261 0.044 0.030 63, 54, 9 <- 63, 53, 10 218880.717 -0.012 0.030 69, 54, 15 <- 69, 53, 16 218686.734 -0.042 0.030 70, 54, 16 <- 70, 53, 17 218649.222 0.021 0.030 71, 54, 17 <- 71, 53, 18 218610.021 0.016 0.030 79, 54, 25 <- 79, 53, 26 218232.074 -0.035 0.030 80, 54, 26 <- 80, 53, 27 218176.041 -0.012 0.030 81, 54, 27 <- 81, 53, 28 218117.894 0.038 0.030 84, 54, 30 <- 84, 53, 31 217929.854 0.014 0.030 85, 54, 31 <- 85, 53, 32 217862.505 0.009 0.030 86, 54, 32 <- 86, 53, 33 217792.695 -0.018 0.030 87, 54, 33 <- 87, 53, 34 217720.440 0.010 0.030 94, 54, 40 <- 94, 53, 41 217138.830 -0.072 0.030 95, 54, 41 <- 95, 53, 42 217044.238 0.031 0.030 96, 54, 42 <- 96, 53, 43 216946.390 0.001 0.030 98, 54, 44 <- 98, 53, 45 216741.028 -0.053 0.030 99, 54, 45 <- 99, 53, 46 216633.488 0.055 0.030 100, 54, 46 <-100, 53, 47 216522.355 0.007 0.030 113, 55, 58 <-113, 54, 59 219075.114 0.018 0.030 114, 55, 59 <-114, 54, 60 218916.146 0.002 0.030 124, 55, 69 <-124, 54, 70 217056.299 -0.020 0.030 126, 55, 71 <-126, 54, 72 216619.023 -0.016 0.030 88, 58, 30 <- 88, 57, 31 234348.812 0.007 0.030 89, 58, 31 <- 89, 57, 32 234286.486 0.046 0.030 97, 58, 39 <- 97, 57, 40 233705.854 -0.015 0.030 98, 58, 40 <- 98, 57, 41 233622.265 0.003 0.030 103, 58, 45 <-103, 57, 46 233163.307 0.000 0.030 105, 58, 47 <-105, 57, 48 232959.425 -0.017 0.030 107, 58, 49 <-107, 57, 50 232743.169 -0.019 0.030 108, 58, 50 <-108, 57, 51 232630.270 0.031 0.030 109, 58, 51 <-109, 57, 52 232513.957 -0.024 0.030 ________________________________________________________________________ ________________________________________________________________________ TABLE S2. The observed and the obs.-calc. frequencies (MHz) for the ground state of isoquinoline. ________________________________________________________________________ isoquinoline ground state ________________________________________________________________________ Obs-calc differences are from fit of Watson's reduced Hamiltonian in ---> reduction-A, representation-I.r <--- TRANSITION Observed Obs-Calc Error ! ! Low J, hyperfine free frequencies from FTMW ! 3, 2, 2 <- 2, 2, 1 6392.053 0.000 0.002 3, 2, 1 <- 2, 2, 0 6554.881 0.000 0.002 4, 1, 4 <- 3, 1, 3 7757.709 0.000 0.002 4, 0, 4 <- 3, 0, 3 8138.041 0.000 0.002 4, 2, 3 <- 3, 2, 2 8490.202 0.000 0.002 4, 3, 2 <- 3, 3, 1 8597.406 0.000 0.002 4, 3, 1 <- 3, 3, 0 8616.259 0.000 0.002 5, 1, 5 <- 4, 1, 4 9638.137 0.000 0.002 5, 0, 5 <- 4, 0, 4 9956.809 0.000 0.002 5, 3, 3 <- 4, 3, 2 10766.425 0.000 0.002 5, 3, 2 <- 4, 3, 1 10831.048 0.000 0.002 2, 2, 0 <- 1, 1, 1 10876.605 -0.001 0.002 5, 1, 4 <- 4, 1, 3 11299.386 0.000 0.002 6, 1, 6 <- 5, 1, 5 11492.320 0.000 0.002 6, 0, 6 <- 5, 0, 5 11722.953 0.000 0.002 6, 2, 5 <- 5, 2, 4 12598.441 0.000 0.002 7, 1, 7 <- 6, 1, 6 13324.311 0.000 0.002 6, 1, 5 <- 5, 1, 4 13397.621 0.000 0.002 3, 2, 1 <- 2, 1, 2 13515.294 -0.001 0.002 6, 2, 4 <- 5, 2, 3 13652.504 0.000 0.002 ! ! aR0,1 type-II bandheads ! 93, 0, 93 <- 92, 0, 92 166918.501 0.043 0.030 90, 3, 87 <- 89, 3, 86 166918.501 -0.029 0.030 89, 4, 85 <- 88, 4, 84 166921.657 -0.003 0.030 88, 5, 83 <- 87, 5, 82 166927.838 -0.029 0.030 87, 6, 81 <- 86, 6, 80 166938.490 0.003 0.030 86, 7, 79 <- 85, 7, 78 166955.265 -0.011 0.030 85, 8, 77 <- 84, 8, 76 166980.556 -0.022 0.030 84, 9, 75 <- 83, 9, 74 167017.552 -0.024 0.030 82, 11, 71 <- 81, 11, 70 167146.100 -0.024 0.030 81, 12, 69 <- 80, 12, 68 167253.160 0.000 0.030 80, 13, 67 <- 79, 13, 66 167405.984 -0.042 0.030 79, 14, 65 <- 78, 14, 64 167628.558 -0.001 0.030 78, 15, 63 <- 77, 15, 62 167969.149 -0.056 0.030 78, 16, 63 <- 77, 16, 62 167954.759 0.034 0.030 90, 2, 88 <- 89, 2, 87 165132.865 0.063 0.030 89, 3, 86 <- 88, 3, 85 165133.870 -0.069 0.030 88, 4, 84 <- 87, 4, 83 165137.185 -0.001 0.030 87, 5, 82 <- 86, 5, 81 165143.596 -0.008 0.030 86, 6, 80 <- 85, 6, 79 165154.593 0.016 0.030 85, 7, 78 <- 84, 7, 77 165171.925 -0.010 0.030 84, 8, 76 <- 83, 8, 75 165198.136 0.008 0.030 83, 9, 74 <- 82, 9, 73 165236.485 -0.012 0.030 82, 10, 72 <- 81, 10, 71 165291.638 -0.058 0.030 81, 11, 70 <- 80, 11, 69 165370.442 0.051 0.030 78, 14, 64 <- 77, 14, 63 165880.007 -0.007 0.030 78, 15, 64 <- 77, 15, 63 165878.364 0.017 0.030 77, 15, 62 <- 76, 15, 61 166249.944 -0.005 0.030 77, 16, 62 <- 76, 16, 61 166226.266 -0.007 0.030 76, 16, 60 <- 75, 16, 59 166956.996 0.001 0.030 76, 17, 60 <- 75, 17, 59 166703.066 0.000 0.030 75, 18, 58 <- 74, 18, 57 167046.391 -0.019 0.030 105, 0,105 <-104, 0,104 188333.200 0.003 0.030 104, 1,103 <-103, 1,102 188332.361 0.054 0.030 103, 2,101 <-102, 2,100 188331.867 -0.019 0.030 102, 3, 99 <-101, 3, 98 188332.361 -0.032 0.030 101, 4, 97 <-100, 4, 96 188334.403 0.005 0.030 100, 5, 95 <- 99, 5, 94 188338.604 -0.011 0.030 99, 6, 93 <- 98, 6, 92 188345.946 0.003 0.030 98, 7, 91 <- 97, 7, 90 188357.532 0.012 0.030 97, 8, 89 <- 96, 8, 88 188374.805 0.003 0.030 96, 9, 87 <- 95, 9, 86 188399.641 -0.029 0.030 95, 10, 85 <- 94, 10, 84 188434.569 -0.021 0.030 94, 11, 83 <- 93, 11, 82 188482.880 0.039 0.030 93, 12, 81 <- 92, 12, 80 188548.915 0.041 0.030 92, 13, 79 <- 91, 13, 78 188638.879 -0.007 0.030 91, 14, 77 <- 90, 14, 76 188761.791 0.010 0.030 88, 18, 71 <- 87, 18, 70 189504.465 0.012 0.030 88, 17, 71 <- 87, 17, 70 189510.877 0.013 0.030 116, 1,115 <-115, 1,114 209744.111 0.007 0.030 115, 2,113 <-114, 2,112 209743.551 0.036 0.030 112, 5,107 <-111, 5,106 209747.784 0.004 0.030 111, 6,105 <-110, 6,104 209752.996 0.014 0.030 110, 7,103 <-109, 7,102 209761.303 0.028 0.030 109, 8,101 <-108, 8,100 209773.662 0.022 0.030 108, 9, 99 <-107, 9, 98 209791.299 -0.003 0.030 107, 10, 97 <-106, 10, 96 209815.796 -0.010 0.030 106, 11, 95 <-105, 11, 94 209849.086 -0.032 0.030 105, 12, 93 <-104, 12, 92 209893.762 -0.014 0.030 104, 13, 91 <-103, 13, 90 209953.121 0.014 0.030 103, 14, 89 <-102, 14, 88 210031.550 0.001 0.030 102, 15, 87 <-101, 15, 86 210135.134 -0.034 0.030 101, 16, 85 <-100, 16, 84 210272.489 -0.006 0.030 100, 17, 83 <- 99, 17, 82 210455.990 -0.011 0.030 117, 1,116 <-116, 1,115 211528.285 0.005 0.030 116, 2,114 <-115, 2,113 211527.688 0.008 0.030 113, 5,108 <-112, 5,107 211531.763 -0.013 0.030 112, 6,106 <-111, 6,105 211536.816 -0.020 0.030 111, 7,104 <-110, 7,103 211544.908 -0.004 0.030 110, 8,102 <-109, 8,101 211556.953 -0.002 0.030 109, 9,100 <-108, 9, 99 211574.148 -0.004 0.030 108, 10, 98 <-107, 10, 97 211597.989 -0.006 0.030 107, 11, 96 <-106, 11, 95 211630.364 -0.013 0.030 106, 12, 94 <-105, 12, 93 211673.712 -0.019 0.030 105, 13, 92 <-104, 13, 91 211731.267 0.030 0.030 104, 14, 90 <-103, 14, 89 211807.122 0.006 0.030 103, 15, 88 <-102, 15, 87 211907.085 -0.019 0.030 102, 16, 86 <-101, 16, 85 212039.202 -0.014 0.030 118, 1,117 <-117, 1,116 213312.437 0.004 0.030 117, 2,115 <-116, 2,114 213311.832 0.010 0.030 115, 4,111 <-114, 4,110 213313.020 -0.007 0.030 114, 5,109 <-113, 5,108 213315.753 -0.002 0.030 113, 6,107 <-112, 6,106 213320.670 -0.007 0.030 112, 7,105 <-111, 7,104 213328.544 0.002 0.030 111, 8,103 <-110, 8,102 213340.260 -0.015 0.030 110, 9,101 <-109, 9,100 213357.028 0.004 0.030 109, 10, 99 <-108, 10, 98 213380.272 0.042 0.030 108, 11, 97 <-107, 11, 96 213411.701 -0.016 0.030 107, 12, 95 <-106, 12, 94 213453.811 -0.011 0.030 106, 13, 93 <-105, 13, 92 213509.623 0.039 0.030 120, 0,120 <-119, 0,119 215097.506 -0.006 0.030 119, 1,118 <-118, 1,117 215096.548 -0.016 0.030 118, 2,116 <-117, 2,115 215095.931 -0.010 0.030 116, 4,112 <-115, 4,111 215097.053 -0.019 0.030 115, 5,110 <-114, 5,109 215099.697 -0.019 0.030 114, 6,108 <-113, 6,107 215104.482 -0.022 0.030 113, 7,106 <-112, 7,105 215112.162 -0.003 0.030 121, 0,121 <-120, 0,120 216881.628 0.005 0.030 120, 1,119 <-119, 1,118 216880.656 -0.016 0.030 119, 2,117 <-118, 2,116 216880.025 -0.013 0.030 118, 3,115 <-117, 3,114 216880.025 -0.023 0.030 117, 4,113 <-116, 4,112 216881.096 0.000 0.030 116, 5,111 <-115, 5,110 216883.644 -0.014 0.030 115, 6,109 <-114, 6,108 216888.309 -0.009 0.030 114, 7,107 <-113, 7,106 216895.795 0.014 0.030 113, 8,105 <-112, 8,104 216906.937 0.015 0.030 112, 9,103 <-111, 9,102 216922.799 -0.022 0.030 111, 10,101 <-110, 10,100 216944.836 0.014 0.030 110, 11, 99 <-109, 11, 98 216974.622 0.000 0.030 109, 12, 97 <-108, 12, 96 217014.362 -0.017 0.030 108, 13, 95 <-107, 13, 94 217066.865 -0.013 0.030 107, 14, 93 <-106, 14, 92 217135.785 0.013 0.030 129, 0,129 <-128, 0,128 231153.646 -0.015 0.030 124, 5,119 <-123, 5,118 231154.537 0.036 0.030 123, 6,117 <-122, 6,116 231158.267 0.021 0.030 122, 7,115 <-121, 7,114 231164.346 0.018 0.030 121, 8,113 <-120, 8,112 231173.430 -0.021 0.030 120, 9,111 <-119, 9,110 231186.456 -0.010 0.030 119, 10,109 <-118, 10,108 231204.442 0.023 0.030 118, 11,107 <-117, 11,106 231228.642 0.040 0.030 117, 12,105 <-116, 12,104 231260.646 0.025 0.030 116, 13,103 <-115, 13,102 231302.571 0.072 0.030 113, 16, 97 <-112, 16, 96 231517.116 -0.010 0.030 112, 17, 95 <-111, 17, 94 231633.403 -0.002 0.030 110, 19, 91 <-109, 19, 90 231980.102 -0.063 0.030 109, 20, 89 <-108, 20, 88 232239.661 -0.052 0.030 109, 21, 89 <-108, 21, 88 232239.661 0.029 0.030 108, 21, 87 <-107, 21, 86 232590.643 -0.006 0.030 108, 22, 87 <-107, 22, 86 232589.415 -0.025 0.030 100, 26, 74 <- 99, 26, 73 231287.285 -0.037 0.030 103, 29, 75 <-102, 29, 74 231150.243 -0.006 0.030 106, 23, 84 <-105, 23, 83 231374.416 0.021 0.030 106, 22, 84 <-105, 22, 83 231398.471 0.001 0.030 106, 42, 64 <-105, 42, 63 231362.890 -0.025 0.030 107, 49, 58 <-106, 49, 57 232236.745 0.029 0.030 ! ! aR0,1 type-I high K-1 tails ! 71, 18, 53 <- 70, 18, 52 165174.611 -0.007 0.030 72, 18, 54 <- 71, 18, 53 167603.477 -0.011 0.030 72, 17, 55 <- 71, 17, 54 165152.478 0.007 0.030 74, 17, 57 <- 73, 17, 56 167593.391 -0.026 0.030 75, 22, 53 <- 74, 22, 52 167560.867 -0.011 0.030 75, 22, 54 <- 74, 22, 53 167400.796 -0.004 0.030 75, 24, 52 <- 74, 24, 51 165948.646 0.007 0.030 75, 24, 51 <- 74, 24, 50 165951.592 -0.040 0.030 76, 29, 47 <- 75, 29, 46 166225.044 -0.037 0.030 76, 27, 50 <- 75, 27, 49 166887.155 -0.009 0.030 76, 30, 46 <- 75, 30, 45 165953.131 -0.020 0.030 76, 33, 43 <- 75, 33, 42 165301.493 0.009 0.030 77, 31, 46 <- 76, 31, 45 167985.962 0.005 0.030 77, 33, 44 <- 76, 33, 43 167557.133 0.017 0.030 77, 36, 41 <- 76, 36, 40 167056.114 0.013 0.030 77, 38, 39 <- 76, 38, 38 166790.659 0.000 0.030 77, 48, 29 <- 76, 48, 28 165937.439 -0.036 0.030 77, 60, 17 <- 76, 60, 16 165423.526 0.073 0.030 77, 61, 16 <- 76, 61, 15 165393.500 0.064 0.030 78, 49, 29 <- 77, 49, 28 168069.007 0.012 0.030 78, 50, 28 <- 77, 50, 27 168012.785 0.014 0.030 78, 51, 27 <- 77, 51, 26 167959.798 -0.011 0.030 78, 52, 26 <- 77, 52, 25 167909.835 -0.016 0.030 78, 53, 25 <- 77, 53, 24 167862.630 -0.034 0.030 78, 57, 21 <- 77, 57, 20 167697.636 -0.067 0.030 78, 58, 20 <- 77, 58, 19 167661.545 -0.034 0.030 78, 60, 18 <- 77, 60, 17 167594.508 0.004 0.030 78, 61, 17 <- 77, 61, 16 167563.313 -0.011 0.030 78, 62, 16 <- 77, 62, 15 167533.546 -0.033 0.030 78, 63, 15 <- 77, 63, 14 167505.134 -0.039 0.030 81, 20, 61 <- 80, 20, 60 188437.110 -0.041 0.030 84, 21, 64 <- 83, 21, 63 188758.603 0.026 0.030 84, 19, 65 <- 83, 19, 64 188456.788 0.018 0.030 85, 20, 66 <- 84, 20, 65 188833.499 0.028 0.030 85, 26, 60 <- 84, 26, 59 188857.984 0.017 0.030 86, 31, 55 <- 85, 31, 54 188665.876 0.014 0.030 86, 32, 54 <- 85, 32, 53 188329.082 0.023 0.030 86, 18, 68 <- 85, 18, 67 188402.660 0.048 0.030 87, 38, 49 <- 86, 38, 48 189169.962 0.017 0.030 87, 40, 47 <- 86, 40, 46 188837.507 0.049 0.030 87, 41, 46 <- 86, 41, 45 188690.635 0.021 0.030 87, 42, 45 <- 86, 42, 44 188554.838 -0.001 0.030 87, 43, 44 <- 86, 43, 43 188429.000 0.018 0.030 88, 57, 31 <- 87, 57, 30 189503.449 0.010 0.030 91, 22, 69 <- 90, 22, 68 210297.432 0.011 0.030 92, 22, 70 <- 91, 22, 69 211508.807 0.000 0.030 93, 24, 70 <- 92, 24, 69 209942.336 0.017 0.030 94, 26, 69 <- 93, 26, 68 211395.220 -0.001 0.030 94, 27, 68 <- 93, 27, 67 210376.040 0.030 0.030 94, 27, 67 <- 93, 27, 66 210533.427 0.003 0.030 95, 22, 74 <- 94, 22, 73 210485.841 -0.024 0.030 95, 28, 68 <- 94, 28, 67 211931.081 -0.014 0.030 95, 28, 67 <- 94, 28, 66 211972.248 -0.004 0.030 95, 30, 66 <- 94, 30, 65 210408.203 -0.013 0.030 95, 30, 65 <- 94, 30, 64 210408.978 0.025 0.030 95, 31, 64 <- 94, 31, 63 209820.942 -0.003 0.030 95, 31, 65 <- 94, 31, 64 209820.942 0.080 0.030 96, 20, 76 <- 95, 20, 75 209890.454 -0.010 0.030 96, 21, 76 <- 95, 21, 75 209836.467 0.009 0.030 96, 29, 68 <- 95, 29, 67 213558.909 0.009 0.030 96, 29, 67 <- 95, 29, 66 213568.829 -0.019 0.030 96, 32, 64 <- 95, 32, 63 211678.718 -0.017 0.030 96, 34, 62 <- 95, 34, 61 210809.601 0.013 0.030 96, 35, 61 <- 95, 35, 60 210447.488 0.016 0.030 96, 36, 60 <- 95, 36, 59 210122.920 -0.011 0.030 96, 37, 59 <- 95, 37, 58 209830.218 0.015 0.030 97, 20, 77 <- 96, 20, 76 211568.321 -0.015 0.030 97, 21, 77 <- 96, 21, 76 211534.277 0.004 0.030 97, 28, 69 <- 96, 28, 68 217060.808 -0.017 0.030 97, 28, 70 <- 96, 28, 69 216953.215 0.031 0.030 97, 33, 65 <- 96, 33, 64 213566.934 0.002 0.030 97, 38, 59 <- 96, 38, 58 211847.917 0.011 0.030 97, 39, 58 <- 96, 39, 57 211597.009 -0.044 0.030 97, 40, 57 <- 96, 40, 56 211367.684 0.001 0.030 97, 43, 54 <- 96, 43, 53 210784.215 0.020 0.030 97, 44, 53 <- 96, 44, 52 210618.322 0.018 0.030 97, 45, 52 <- 96, 45, 51 210464.268 0.018 0.030 97, 46, 51 <- 96, 46, 50 210320.853 0.001 0.030 97, 47, 50 <- 96, 47, 49 210187.125 0.038 0.030 97, 48, 49 <- 96, 48, 48 210062.035 -0.020 0.030 97, 49, 48 <- 96, 49, 47 209944.944 -0.024 0.030 97, 50, 47 <- 96, 50, 46 209835.081 -0.046 0.030 98, 41, 57 <- 97, 41, 56 213418.989 0.015 0.030 98, 50, 48 <- 97, 50, 47 212052.136 0.013 0.030 98, 51, 47 <- 97, 51, 46 211945.552 0.002 0.030 98, 52, 46 <- 97, 52, 45 211845.244 -0.023 0.030 98, 53, 45 <- 97, 53, 44 211750.727 -0.034 0.030 98, 54, 44 <- 97, 54, 43 211661.568 -0.005 0.030 98, 55, 43 <- 97, 55, 42 211577.313 0.020 0.030 98, 56, 42 <- 97, 56, 41 211497.528 -0.018 0.030 98, 57, 41 <- 97, 57, 40 211422.008 0.010 0.030 98, 58, 40 <- 97, 58, 39 211350.312 -0.030 0.030 98, 59, 39 <- 97, 59, 38 211282.315 0.011 0.030 98, 68, 30 <- 97, 68, 29 210797.385 -0.006 0.030 98, 70, 28 <- 97, 70, 27 210713.599 -0.014 0.030 98, 71, 27 <- 97, 71, 26 210674.266 0.021 0.030 98, 72, 26 <- 97, 72, 25 210636.433 0.003 0.030 98, 73, 25 <- 97, 73, 24 210600.115 0.034 0.030 99, 36, 63 <- 98, 36, 62 217050.359 -0.050 0.030 99, 58, 41 <- 98, 58, 40 213546.784 0.057 0.030 99, 59, 40 <- 98, 59, 39 213476.562 0.004 0.030 99, 60, 39 <- 98, 60, 38 213409.950 0.084 0.030 100, 46, 54 <- 99, 46, 53 217026.495 -0.018 0.030 100, 47, 53 <- 99, 47, 52 216879.009 0.010 0.030 101, 73, 28 <-100, 73, 27 217122.157 -0.009 0.030 101, 76, 25 <-100, 76, 24 217011.748 -0.074 0.030 ! ! b-type transitions ! 39, 31, 9 <- 38, 30, 8 213332.716 -0.012 0.030 41, 30, 12 <- 40, 29, 11 213359.806 0.005 0.030 43, 29, 15 <- 42, 28, 14 213377.521 -0.015 0.030 47, 27, 21 <- 46, 26, 20 213361.266 0.014 0.030 49, 26, 24 <- 48, 25, 23 213308.451 -0.015 0.030 54, 23, 32 <- 53, 22, 31 210692.064 0.005 0.030 56, 22, 35 <- 55, 21, 34 210277.951 -0.058 0.030 59, 21, 39 <- 58, 20, 38 211547.798 0.041 0.030 59, 21, 38 <- 58, 20, 39 211549.661 0.041 0.030 60, 21, 39 <- 59, 20, 40 213466.074 -0.034 0.030 60, 21, 40 <- 59, 20, 39 213462.579 0.066 0.030 62, 20, 43 <- 61, 19, 42 212056.822 0.005 0.030 ________________________________________________________________________ ________________________________________________________________________ TABLE S3. The observed and the obs.-calc. frequencies (MHz) for the measured hyperfine components in the ground state of quinoline. ------------------------------------------------------------------------------- Quinoline ground state ------------------------------------------------------------------------------- J K-1 K+1 F <- J K-1 K+1 F obs o-c error blends o-c wt 2 1 2 2 1 0 1 1 5861.5803 0.0002 0.002 2 1 2 2 1 0 1 2 5862.0178 -0.0010 0.002 2 1 2 3 1 0 1 2 5863.0551 0.0011 0.002 2 1 2 1 1 0 1 0 5864.2876 -0.0006 0.002 2 2 1 2 2 1 2 3 6718.7809 -0.0008 0.002 2 2 1 1 2 1 2 1 6718.9360 -0.0011 0.002 2 2 1 3 2 1 2 3 6719.2491 -0.0025 0.002 2 2 1 2 2 1 2 2 6719.8159 -0.0010 0.002 3 2 2 2 3 1 3 2 7296.0656 -0.0026 0.002 3 2 2 4 3 1 3 4 7296.4263 -0.0009 0.002 3 2 2 3 3 1 3 3 7297.4491 -0.0001 0.002 4 3 1 4 4 2 2 4 9786.1208 0.0005 0.002 4 3 1 5 4 2 2 5 9787.1636 0.0015 0.002 3 3 0 3 3 2 1 3 10078.9763 -0.0032 0.002 3 3 0 4 3 2 1 4 10080.0708 -0.0026 0.002 3 3 0 2 3 2 1 2 10080.4550 -0.0012 0.002 3 3 1 3 3 2 2 3 10312.4933 -0.0017 0.002 3 3 1 4 3 2 2 4 10313.0392 0.0005 0.002 3 3 1 2 3 2 2 2 10313.2285 -0.0019 0.002 2 2 1 2 1 1 0 1 10341.1651 0.0006 0.002 2 2 1 1 1 1 0 1 10341.8951 -0.0008 0.002 2 2 1 2 1 1 0 2 10342.1298 -0.0007 0.002 2 2 1 3 1 1 0 2 10342.6015 0.0012 0.002 2 2 1 1 1 1 0 0 10344.3105 -0.0007 0.002 4 3 2 4 4 2 3 4 10436.7116 0.0001 0.002 4 3 2 5 4 2 3 5 10436.8660 0.0011 0.002 4 3 2 3 4 2 3 3 10436.9052 0.0011 0.002 5 1 5 5 4 0 4 4 10588.6608 0.0012 0.002 5 1 5 6 4 0 4 5 10589.3868 0.0007 0.002 5 1 5 4 4 0 4 3 10589.5152 0.0004 0.002 5 3 3 4 5 2 4 4 10672.8774 0.0007 0.002 5 3 3 6 5 2 4 6 10672.9019 0.0005 0.002 5 3 3 5 5 2 4 5 10673.0166 -0.0031 0.002 2 2 0 1 1 1 1 1 10758.0457 -0.0015 0.002 2 2 0 1 1 1 1 0 10754.5338 -0.0002 0.002 2 2 0 3 1 1 1 2 10756.5084 0.0009 0.002 2 2 0 2 1 1 1 1 10757.6713 -0.0001 0.002 2 2 0 2 1 1 1 2 10756.2655 -0.0008 0.002 6 0 6 5 5 1 5 4 11393.0424 0.0025 0.002 6 0 6 7 5 1 5 6 11393.0995 0.0008 0.002 6 0 6 6 5 1 5 5 11393.2053 0.0021 0.002 3 2 2 3 2 1 1 2 12152.6446 -0.0003 0.002 3 2 2 4 2 1 1 3 12154.1500 0.0020 0.002 3 2 2 2 2 1 1 1 12154.9821 -0.0005 0.002 6 1 6 6 5 0 5 5 12164.9575 0.0006 0.002 6 1 6 7 5 0 5 6 12165.4417 0.0000 0.002 6 1 6 5 5 0 5 4 12165.4968 0.0018 0.002 7 0 7 6 6 1 6 5 13375.6350 -0.0006 0.002 3 2 1 2 2 1 2 1 13487.3501 0.0008 0.002 3 2 1 4 2 1 2 3 13488.1245 0.0009 0.002 3 2 1 3 2 1 2 2 13489.7264 0.0002 0.002 4 2 3 4 3 1 2 3 13775.9852 0.0005 0.002 4 2 3 5 3 1 2 4 13777.4446 0.0018 0.002 4 2 3 3 3 1 2 2 13777.9664 -0.0004 0.002 CONSTANTS IN FIT: 10000 A /MHz [3145.533013007] 20000 B /MHz [1271.57797278] 30000 C /MHz [905.739406362] 200 DJ /kHz [ 0.0191103] 1100 DJK /kHz [ 0.0470313] 2000 DK /kHz [ 0.161461] 40100 delJ /kHz [ 0.0056621] 41000 delK /kHz [ 0.060622] 110010000 chi.aa*3/2 /MHz 2.1943(23) 110040000 chi(b-c)/4 /MHz -1.97634(74) 110610000 chi.ab /MHz [-0.35] MICROWAVE AVG = -.86424E-04 MHz, IR AVG = .00000 MICROWAVE RMS = .13138E-02 MHz, IR RMS = .00000 END OF ITERATION 1 OLD, NEW RMS ERROR= .65690 .65690 distinct frequency lines in fit: 54 distinct constants in fit: 2 for standard errors previous errors are multiplied by: .669414 FITTED CONSTANTS AND STANDARD ERRORS: 110010000 chi.aa*3/2 /MHz 2.1943(15) 110040000 chi(b-c)/4 /MHz -1.97634(49) CORRELATION COEFFICIENTS, C.ij: chi.aa*3 chi(b-c) chi.aa*3/21.0000 chi(b-c)/4-.0866 1.0000 Mean value of |C.ij|, i.ne.j = .0866 Mean value of C.ij, i.ne.j = -.0866 ------------------------------------------------------------------------------- TABLE S4. The observed and the obs.-calc. frequencies (MHz) for the measured hyperfine components in the ground state of isoquinoline. ------------------------------------------------------------------------------- Isoquinoline ground state ------------------------------------------------------------------------------- J K-1 K+1 F <- J K-1 K+1 F obs o-c error blends o-c wt 3 2 2 3 2 2 1 2 6391.1739 0.0011 0.002 3 2 2 4 2 2 1 3 6392.3034 0.0010 0.002 3 2 2 2 2 2 1 1 6392.9288 -0.0016 0.002 3 2 1 3 2 2 0 2 6554.0833 -0.0006 0.002 3 2 1 4 2 2 0 3 6555.1015 -0.0011 0.002 4 1 4 4 3 1 3 3 7757.6001 0.0011 0.002 4 1 4 3 3 1 3 2 7757.6961 -0.0003 0.002 4 1 4 5 3 1 3 4 7757.7819 0.0006 0.002 4 0 4 4 3 0 3 3 8137.9483 0.0000 0.002 4 0 4 3 3 0 3 2 8138.0201 0.0006 0.002 4 0 4 5 3 0 3 4 8138.1049 -0.0002 0.002 4 0 4 3 3 0 3 3 8139.8444 -0.0019 0.002 4 2 3 4 3 2 2 3 8489.8384 0.0000 0.002 4 2 3 5 3 2 2 4 8490.3343 -0.0005 0.002 4 2 3 3 3 2 2 2 8490.4612 -0.0006 0.002 4 3 2 4 3 3 1 3 8596.6388 -0.0008 0.002 4 3 2 5 3 3 1 4 8597.6540 0.0023 0.002 4 3 2 3 3 3 1 2 8598.0487 -0.0007 0.002 4 3 1 4 3 3 0 3 8615.5022 0.0013 0.002 4 3 1 5 3 3 0 4 8616.5030 0.0023 0.002 5 1 5 5 4 1 4 4 9638.0676 0.0007 0.002 5 1 5 4 4 1 4 3 9638.1259 0.0010 0.002 5 1 5 6 4 1 4 5 9638.1884 0.0000 0.002 5 0 5 5 4 0 4 4 9956.7203 0.0010 0.002 5 0 5 4 4 0 4 3 9956.8142 -0.0010 0.002 5 0 5 6 4 0 4 5 9956.8662 0.0001 0.002 5 3 3 5 4 3 2 4 10766.0418 -0.0011 0.002 5 3 3 6 4 3 2 5 10766.5647 0.0015 0.002 5 3 3 4 4 3 2 3 10766.6963 0.0011 0.002 5 3 2 5 4 3 1 4 10830.6879 0.0000 0.002 5 3 2 6 4 3 1 5 10831.1787 -0.0001 0.002 5 3 2 4 4 3 1 3 10831.3034 -0.0014 0.002 2 2 0 1 1 1 1 1 10875.6347 -0.0048 0.002 2 2 0 1 1 1 1 2 10875.6831 0.0046 0.002 2 2 0 1 1 1 1 0 10875.7339 -0.0020 0.002 2 2 0 3 1 1 1 2 10876.3455 0.0001 0.002 2 2 0 2 1 1 1 1 10877.5054 -0.0021 0.002 2 2 0 2 1 1 1 2 10877.5471 0.0005 0.002 5 1 4 5 4 1 3 4 11299.2970 0.0006 0.002 5 1 4 4 4 1 3 3 11299.4285 0.0015 0.002 0.0006 .50 5 1 4 6 4 1 3 5 11299.4285 -0.0003 0.002 0.0006 .50 6 1 6 6 5 1 5 5 11492.2680 -0.0003 0.002 6 1 6 5 5 1 5 4 11492.3139 0.0002 0.002 6 1 6 7 5 1 5 6 11492.3592 -0.0002 0.002 6 0 6 6 5 0 5 5 11722.8793 0.0017 0.002 6 0 6 5 5 0 5 4 11722.9641 -0.0002 0.002 6 0 6 7 5 0 5 6 11723.0013 0.0001 0.002 6 2 5 6 5 2 4 5 12598.3146 -0.0007 0.002 6 2 5 7 5 2 4 6 12598.5040 0.0043 0.002 0.0013 .50 6 2 5 5 5 2 4 4 12598.5040 -0.0018 0.002 0.0013 .50 7 1 7 7 6 1 6 6 13324.2708 0.0008 0.002 7 1 7 6 6 1 6 5 13324.3098 0.0014 0.002 7 1 7 8 6 1 6 7 13324.3433 0.0002 0.002 6 1 5 6 5 1 4 5 13397.5366 0.0013 0.002 6 1 5 5 5 1 4 4 13397.6613 0.0006 0.002 -0.0004 .50 6 1 5 7 5 1 4 6 13397.6613 -0.0013 0.002 -0.0004 .50 3 2 1 2 2 1 2 1 13514.3358 -0.0045 0.002 3 2 1 4 2 1 2 3 13515.0080 0.0001 0.002 3 2 1 3 2 1 2 2 13516.2772 0.0003 0.002 6 2 4 6 5 2 3 5 13652.4525 0.0020 0.002 6 2 4 7 5 2 3 6 13652.5291 -0.0002 0.002 -0.0008 .50 6 2 4 5 5 2 3 4 13652.5291 -0.0014 0.002 -0.0008 .50 CONSTANTS IN FIT: 10000 A /MHz [3199.000208195] 20000 B /MHz [1237.931586883] 30000 C /MHz [892.753595089] 200 DJ /kHz [ 0.0188548] 1100 DJK /kHz [ 0.047004] 2000 DK /kHz [ 0.1572] 40100 delJ /kHz [ 0.0054543] 41000 delK /kHz [ 0.061465] 110010000 chi.aa*3/2 /MHz -5.2671(32) 110040000 chi(b-c)/4 /MHz -0.8126(11) 110610000 chi.ab /MHz 2.81(57) MICROWAVE AVG = .68810E-04 MHz, IR AVG = .00000 MICROWAVE RMS = .14548E-02 MHz, IR RMS = .00000 END OF ITERATION 1 OLD, NEW RMS ERROR= .72738 .72738 distinct frequency lines in fit: 58 distinct constants in fit: 3 for standard errors previous errors are multiplied by: .746954 FITTED CONSTANTS AND STANDARD ERRORS: 110010000 chi.aa*3/2 /MHz -5.2671(23) 110040000 chi(b-c)/4 /MHz -0.81264(87) 110610000 chi.ab /MHz 2.81(42) CORRELATION COEFFICIENTS, C.ij: chi.aa*3 chi(b-c) chi.ab chi.aa*3/21.0000 chi(b-c)/4-.1416 1.0000 chi.ab .0079 .0541 1.0000 Mean value of |C.ij|, i.ne.j = .0679 Mean value of C.ij, i.ne.j = -.0265 ------------------------------------------------------------------------------- TABLE S5. The observed and the obs.-calc. frequencies (MHz) for the measured Stark components in the ground state of quinoline. TRANSITIONS (F and MF in units of 1/2): J K K <- J K K F MF<- F MF Volts Obs Obs-Calc -1 +1 -1 +1 2 2 0 1 1 1 2 0 0 0 0.0 10754.53430 0.00029 2 2 0 1 1 1 2 0 0 0 1199.4 10754.62580 0.00209 2 2 0 1 1 1 2 0 0 0 1787.6 10754.73040 0.00101 2 2 0 1 1 1 2 0 0 0 2107.1 10754.80150 0.00053 2 2 0 1 1 1 2 0 0 0 2486.8 10754.89840 0.00247 2 2 0 1 1 1 2 0 0 0 2659.1 10754.94050 -0.00108 2 2 0 1 1 1 2 0 0 0 3001.9 10755.03660 0.00165 2 2 0 1 1 1 2 0 0 0 3587.2 10755.19260 -0.00109 2 2 0 1 1 1 2 0 0 0 3984.2 10755.29110 -0.00312 2 2 0 1 1 1 2 0 0 0 4172.9 10755.34010 0.00137 2 2 0 1 1 1 2 0 0 0 4858.8 10755.48040 0.00106 2 2 0 1 1 1 4 2 4 2 1602.2 10756.39520 -0.00059 2 2 0 1 1 1 4 2 4 2 2001.1 10756.44490 -0.00016 2 2 0 1 1 1 4 2 4 2 2568.6 10756.50600 0.00105 2 2 0 1 1 1 4 2 4 2 3142.6 10756.54420 0.00048 2 2 0 1 1 1 4 2 4 2 3000.6 10756.53730 0.00075 2 2 0 1 1 1 4 2 4 2 3587.2 10756.55660 0.00149 2 2 0 1 1 1 4 2 4 2 4173.3 10756.54220 -0.00233 2 2 0 1 1 1 4 2 4 2 4858.8 10756.49630 -0.00167 2 2 0 1 1 1 4 4 4 4 1313.5 10756.50260 -0.00056 2 2 0 1 1 1 4 4 4 4 2001.1 10756.78770 0.00218 2 2 0 1 1 1 4 4 4 4 2568.6 10757.07930 -0.00113 2 2 0 1 1 1 4 4 4 4 3142.2 10757.43800 0.00120 2 2 0 1 1 1 4 4 4 4 3587.2 10757.75360 -0.00277 2 2 0 1 1 1 6 0 4 0 0.0 10756.50840 0.00090 2 2 0 1 1 1 6 0 4 0 1313.5 10756.55160 -0.00049 2 2 0 1 1 1 6 0 4 0 1993.0 10756.62090 0.00437 2 2 0 1 1 1 6 0 4 0 3996.6 10757.14300 -0.00274 2 2 0 1 1 1 6 0 4 0 2994.5 10756.79860 0.00203 2 2 0 1 1 1 6 0 4 0 1199.4 10756.54620 0.00177 2 2 0 1 1 1 6 0 4 0 1787.6 10756.59720 0.00391 2 2 0 1 1 1 6 0 4 0 2107.1 10756.63360 0.00252 2 2 0 1 1 1 6 0 4 0 2486.8 10756.69500 0.00566 2 2 0 1 1 1 6 0 4 0 3000.6 10756.79870 0.00060 2 2 0 1 1 1 6 0 4 0 3587.2 10756.97880 0.00118 2 2 0 1 1 1 6 0 4 0 4172.9 10757.23650 0.00638 2 2 0 1 1 1 6 2 4 2 1313.5 10756.59380 0.00416 2 2 0 1 1 1 6 2 4 2 1993.0 10756.68630 0.00224 2 2 0 1 1 1 6 2 4 2 2994.5 10756.84130 -0.00031 2 2 0 1 1 1 6 2 4 2 3996.6 10756.97250 -0.00164 2 2 0 1 1 1 6 2 4 2 1199.4 10756.57890 0.00237 2 2 0 1 1 1 6 2 4 2 1787.6 10756.65430 0.00116 2 2 0 1 1 1 6 2 4 2 2107.1 10756.70250 0.00069 2 2 0 1 1 1 6 2 4 2 2486.8 10756.76250 0.00026 2 2 0 1 1 1 6 2 4 2 3000.6 10756.84380 0.00128 2 2 0 1 1 1 6 2 4 2 3587.2 10756.92430 -0.00051 2 2 0 1 1 1 6 2 4 2 4172.9 10756.99500 0.00173 2 2 0 1 1 1 6 2 4 2 4858.0 10757.05550 -0.00104 2 2 0 1 1 1 6 4 4 4 1199.4 10756.69700 0.00415 2 2 0 1 1 1 6 4 4 4 1602.2 10756.84990 0.00189 2 2 0 1 1 1 6 4 4 4 2000.9 10757.05720 0.00095 2 2 0 1 1 1 4 0 2 0 0.0 10757.67130 -0.00011 2 2 0 1 1 1 4 0 2 0 1199.4 10757.82350 0.00071 2 2 0 1 1 1 4 0 2 0 1602.2 10757.94240 0.00092 2 2 0 1 1 1 4 0 2 0 2000.9 10758.09320 0.00072 2 2 0 1 1 1 4 0 2 0 2568.6 10758.36340 -0.00152 2 2 0 1 1 1 4 0 2 0 3142.6 10758.70960 0.00083 2 2 0 1 1 1 4 0 2 0 3587.2 10759.02070 -0.00149 2 2 0 1 1 1 4 0 2 0 4173.6 10759.49190 -0.00625 2 2 0 1 1 1 4 0 2 0 4858.0 10760.14550 0.00231 2 2 0 1 1 1 4 2 2 2 1199.4 10757.76120 0.00202 2 2 0 1 1 1 4 2 2 2 1787.6 10757.86270 0.00072 2 2 0 1 1 1 4 2 2 2 2107.1 10757.93640 0.00151 2 2 0 1 1 1 4 2 2 2 2486.8 10758.04160 0.00164 2 2 0 1 1 1 4 2 2 2 3000.6 10758.21970 -0.00016 2 2 0 1 1 1 4 2 2 2 3587.2 10758.48450 -0.00191 2 2 0 1 1 1 4 2 2 2 4173.8 10758.82090 -0.00210 Standard deviation = 0.002212 FINAL RESULTS OF LEAST SQUARES FITTING PROCEDURE ================================================ FITTED CONSTANTS: A /MHz 3145.533013 1:Xab /MHz -0.35 B /MHz 1271.577972 1:XJ.a/kHz 0. C /MHz 905.739406 1:XK.a/kHz 0. DJ /kHz 0.0191103 1:XJbc/kHz 0. DJK /kHz 0.0470313 1:Ma /MHz 0. DK /kHz 0.161461 1:Mb-c/MHz 0. dJ /kHz 0.0056621 1:Tr /MHz 0. dK /kHz 0.060622 1:Xd /kHz 0. HJ / Hz 0. HJK / Hz 0. HKJ / Hz 0. HK / Hz 0. hJ / Hz 0. hJK / Hz 0. Mu.a /D 0.14355(16) hK / Hz 0. Mu.b /D 2.01454(74) LKKJ /mHz 0. Mu.c /D 0. 1:Xa /MHz 1.46287 d /cm 26.93 1:Xb-c/MHz -7.90536 k /cm 0. 1:X.bb /MHz -4.684115 1:X.cc /MHz 3.221245 CORRELATION COEFFICIENTS: Mu.a Mu.b Mu.a 1.0000 Mu.b -0.6752 1.0000 ------------------------------------------------------------------------------ TABLE S6. The observed and the obs.-calc. frequencies (MHz) for the measured Stark components in the ground state of isoquinoline. TRANSITIONS (F and MF in units of 1/2): J K K <- J K K F MF<- F MF Volts Obs Obs-Calc -1 +1 -1 +1 5 2 3 4 2 2 10 0 8 0 0.0 11255.82500 0.00004 5 2 3 4 2 2 10 0 8 0 1191.5 11255.81020 0.00190 5 2 3 4 2 2 10 0 8 0 1999.1 11255.77690 -0.00119 5 2 3 4 2 2 10 0 8 0 2801.5 11255.73350 0.00053 5 2 3 4 2 2 10 0 8 0 4001.4 11255.63200 -0.00552 5 2 3 4 2 2 10 0 8 0 5202.7 11255.50870 0.00011 5 2 3 4 2 2 10 0 8 0 6004.2 11255.40300 -0.00117 5 2 3 4 2 2 10 2 8 2 1999.1 11255.84060 0.00115 5 2 3 4 2 2 10 2 8 2 2412.3 11255.87370 0.00134 5 2 3 4 2 2 10 2 8 2 2816.7 11255.90840 -0.00319 5 2 3 4 2 2 10 2 8 2 3213.6 11255.95520 -0.00001 5 2 3 4 2 2 10 2 8 2 4001.4 11256.05160 -0.00156 5 2 3 4 2 2 10 2 8 2 5202.7 11256.22760 0.00060 5 2 3 4 2 2 10 2 8 2 6004.2 11256.35960 -0.00005 5 2 3 4 2 2 10 4 8 4 1191.5 11255.76410 0.00011 5 2 3 4 2 2 10 4 8 4 1999.1 11255.75010 -0.00118 5 2 3 4 2 2 10 4 8 4 2412.1 11255.74230 -0.00326 5 2 3 4 2 2 10 4 8 4 4001.4 11255.67190 -0.00132 5 2 3 4 2 2 10 4 8 4 5202.7 11255.55950 -0.00219 5 2 3 4 2 2 10 4 8 4 6004.2 11255.46370 -0.00040 5 2 3 4 2 2 12 0 10 0 0.0 11255.97910 0.00235 5 2 3 4 2 2 12 0 10 0 1191.5 11255.98570 -0.00221 5 2 3 4 2 2 12 0 10 0 2001.7 11256.02440 0.00134 5 2 3 4 2 2 12 0 10 0 2412.3 11256.05240 0.00299 5 2 3 4 2 2 12 0 10 0 2796.1 11256.08060 0.00211 5 2 3 4 2 2 12 0 10 0 3213.6 11256.11490 0.00026 5 2 3 4 2 2 12 0 10 0 4001.4 11256.19870 0.00349 5 2 3 4 2 2 12 0 10 0 5202.7 11256.35090 0.00211 5 2 3 4 2 2 12 0 10 0 6004.2 11256.47110 -0.00103 5 2 3 4 2 2 12 2 10 2 1191.5 11255.95560 -0.00158 5 2 3 4 2 2 12 2 10 2 1999.1 11255.92670 0.00096 5 2 3 4 2 2 12 2 10 2 2412.3 11255.90300 -0.00186 5 2 3 4 2 2 12 2 10 2 2801.5 11255.88290 0.00099 5 2 3 4 2 2 12 2 10 2 3202.5 11255.85400 -0.00072 5 2 3 4 2 2 12 2 10 2 4001.4 11255.79360 0.00428 5 2 3 4 2 2 12 2 10 2 5202.7 11255.66300 0.00064 5 2 3 4 2 2 12 2 10 2 6004.2 11255.56010 0.00144 5 2 3 4 2 2 12 4 10 4 1191.5 11255.86740 0.00195 5 2 3 4 2 2 12 4 10 4 2001.7 11255.63400 0.00055 5 2 3 4 2 2 12 4 10 4 2409.2 11255.47210 -0.00082 5 2 3 4 2 2 12 4 10 4 2816.7 11255.28670 0.00250 5 2 3 4 2 2 12 4 10 4 3213.8 11255.07590 0.00255 5 2 3 4 2 2 8 0 6 0 2001.7 11255.95980 0.00024 5 2 3 4 2 2 8 0 6 0 2412.3 11255.93180 -0.00484 5 2 3 4 2 2 8 0 6 0 2803.2 11255.91110 0.00024 5 2 3 4 2 2 8 0 6 0 3202.5 11255.88330 0.00244 5 2 3 4 2 2 8 2 6 2 1191.5 11255.91040 -0.00328 5 2 3 4 2 2 8 2 6 2 2001.7 11255.69390 0.00328 5 2 3 4 2 2 8 2 6 2 2409.2 11255.52430 -0.00037 5 2 3 4 2 2 8 2 6 2 2796.1 11255.33510 -0.00255 5 2 3 4 2 2 8 2 6 2 3213.8 11255.10500 -0.00066 Standard deviation = 0.002119 FINAL RESULTS OF LEAST SQUARES FITTING PROCEDURE ================================================ FITTED CONSTANTS: A /MHz 3199.000200 1:Xab /MHz 2.81 B /MHz 1237.931586 1:XJ.a/kHz 0. C /MHz 892.753595 1:XK.a/kHz 0. DJ /kHz 0.0188548 1:XJbc/kHz 0. DJK /kHz 0.047004 1:Ma /MHz 0. DK /kHz 0.1572 1:Mb-c/MHz 0. dJ /kHz 0.0054543 1:Tr /MHz 0. dK /kHz 0.061465 1:Xd /kHz 0. HJ / Hz 0. HJK / Hz 0. HKJ / Hz 0. HK / Hz 0. hJ / Hz 0. hJK / Hz 0. Mu.a /D 2.3601(10) hK / Hz 0. Mu.b /D 0.9051(12) LKKJ /mHz 0. Mu.c /D 0. 1:Xa /MHz -3.51140 d /cm 26.93 1:Xb-c/MHz -3.25056 k /cm 0. 1:X.bb /MHz 0.130420000000 1:X.cc /MHz 3.380980000000 CORRELATION COEFFICIENTS: Mu.a Mu.b Mu.a 1.0000 Mu.b 0.4378 1.0000 ------------------------------------------------------------------------------