Term values (in MHz) for 14N16O.

The term values shown below were calculated from the molecular parameters 
derived from a least-squares fit to the far-infrared and microwave data of 
14N16O (see Table 5).  The parametrized Hamiltonian was written in matrix 
form and diagonalized in the fitting process in order to extract the 
eigenvalues.  The matrix is diagonal in F, and for each value of F, the 
matrix divides into two separate matrices according to the total parity of 
the levels.  For a 2-PI state, for (J - 0.5 = odd) levels, even parity (+) 
corresponds to e-symmetry and odd parity (-) corresponds to f-symmetry.  
For the (J - 0.5 = even) levels, even parity (+) corresponds to f-symmetry 
and odd parity (-) corresponds to e-symmetry.

The table shown below is organized in the following manner.  The first row 
indicates the value of F, with the total parity indicated in parentheses.  
The next row contains the energies (in MHz) of the levels which exist for 
that value of F and parity, given in order of energy rank from highest to 
lowest. The next row is blank.  This three-row pattern is repeated 
throughout the table.  The term values are listed in two blocks (labeled # 
1 and # 2) which alternate in parity for consecutive values of F.
 
For the F = 0.5 level, the energy levels are listed in the following order, 
where F1 indicates the lower (omega = 1/2) electron spin component and F2 
indicates the upper (omega = 3/2) spin component:

(F2,J=1.5);  (F1,J=1.5);  (F1,J=0.5)

For the F = 1.5 level, the energy levels are listed in the following order:

(F2,J=2.5);  (F2,J=1.5);  (F1,J=2.5);  (F1,J=1.5);  (F1,J=0.5)

For levels with 1.5 < F < 20.5, the energy levels are listed in the 
following order:

(F2,J=F+1);  (F2,J=F);  (F2,J=F-1);  (F1,J=F+1);  (F1,J=F);  (F1,J=F-1)

For levels with F = 20.5 and higher, the relative ordering of the third and 
fourth ranked levels changes, resulting in the following order:

(F2,J=F+1);  (F2,J=F);  (F1,J=F+1);  (F2,J=F-1);  (F1,J=F);  (F1,J=F-1)



 Term energies of levels in block # 1:
 -------------------------------------

F = 0.5(+)
2000541.218,-1593956.454,-1743976.153

F = 1.5(-)
2258408.574,2000587.674,-1343507.928,-1593331.804,-1744202.089

F = 2.5(+)
2619364.916,2258442.949,2000660.966,-992813.131,-1342516.195,-1594025.633

F = 3.5(-)
3083395.297,2619396.460,2258483.116,-541870.953,-991464.678,-1343588.791

F = 4.5(+)
3650468.714,3083430.344,2619417.793,9317.850,-540171.767,-992899.265

F = 5.5(-)
4320545.071,3650513.100,3083434.958,660751.457,11362.332,-541959.750

F = 6.5(+)
5093576.720,4320604.815,3650499.194,1412426.963,663135.527,9227.731

F = 7.5(-)
5969509.096,5093658.269,4320568.616,2264340.193,1415144.409,660660.803

F = 8.5(+)
6948281.116,5969619.405,5093594.714,3216485.467,2267384.241,1412336.274

F = 9.5(-)
8029825.513,6948427.663,5969522.452,4268855.335,3219848.777,2264249.811

F = 10.5(+)
9214069.148,8030016.281,6948290.468,5421440.301,4272530.036,3216395.631

F = 11.5(-)
10500933.304,9214312.589,8029831.322,6674228.544,5425418.032,4268766.220

F = 12.5(+)
11890333.973,10501238.297,9214071.762,8027205.642,6678500.502,5421352.035

F = 13.5(-)
13382182.137,11890709.775,10500932.991,9480354.301,8031762.637,6674141.224

F = 14.5(+)
14976384.027,13382638.335,11890330.949,11033654.096,9485186.804,8027119.341

F = 15.5(-)
16672841.370,14976930.486,13382176.578,12687081.226,11038752.294,9480269.072

F = 16.5(+)
18471451.624,16673488.188,14976376.080,14440608.287,12692435.070,11033569.977

F = 17.5(-)
20372108.185,18472209.087,16672831.161,16294204.062,14446207.536,12686998.246

F = 18.5(+)
22374700.583,20372986.723,18471439.263,18247833.329,16300038.328,14440526.464

F = 19.5(-)
24479114.650,22375710.733,20372093.769,20301456.691,18253892.116,16294123.406

F = 20.5(+)
26685232.678,24480267.020,22455030.426,22374684.198,20307729.430,18247753.843

F = 21.5(-)
28992933.545,26686537.915,24708506.354,24479096.377,22461506.508,20301378.374

F = 22.5(+)
31402092.833,28994402.309,27061831.728,26685212.588,24715175.159,22454953.272

F = 23.5(-)
33912582.923,31403735.771,29514949.135,28992911.705,27068682.646,24708430.354

F = 24.5(+)
36524273.074,33914410.648,32067796.422,31402069.307,29521971.591,27061756.870

F = 25.5(-)
39237029.489,36526296.149,34720306.630,33912557.770,32074979.890,29514875.404

F = 26.5(+)
42050715.361,39239258.410,37472407.947,36524246.350,34727640.651,32067723.800

F = 27.5(-)
44965190.913,42053160.546,40324023.673,39237001.246,37479882.142,34720235.098

F = 28.5(+)
47980313.426,44967862.694,43275072.194,42050685.651,40331627.750,37472337.485

F = 29.5(-)
51095937.252,47983222.039,46325466.967,44965159.784,43282795.955,40323954.260

F = 30.5(+)
54311913.821,51099092.831,49475116.517,47980280.924,46333300.317,43275003.808

F = 31.5(-)
57628091.646,54315326.397,52723924.434,51095903.421,49483049.465,46325399.585

F = 32.5(+)
61044316.311,57631771.144,56071789.385,54311878.705,52731947.096,49475050.115

F = 33.5(-)
64560430.462,61048272.547,59518605.126,57628055.284,56079891.985,52723858.989

F = 34.5(+)
68176273.791,64564673.147,63064260.519,61044278.743,59526777.996,56071724.873

F = 35.5(-)
71891683.014,68180812.529,66708639.558,64560391.726,63072494.097,59518541.523

F = 36.5(+)
75706491.853,71896527.306,70451621.387,68176233.922,66716924.386,63064197.803

F = 37.5(-)
79620531.003,75711651.097,74293080.334,71891642.048,70459948.109,66708577.703

F = 38.5(+)
83633628.115,79626014.502,78232885.932,75706449.823,74301439.692,70451560.371

F = 39.5(-)
87745607.760,83639445.076,82270902.959,79620487.943,78241268.766,74293020.133



 Term energies of levels in block # 2:
 -------------------------------------

F = 0.5(-)
2000542.366,-1593395.600,-1744182.104

F = 1.5(+)
2258412.383,2000587.062,-1342578.670,-1593983.347,-1743770.899

F = 2.5(-)
2619374.045,2258439.829,2000661.995,-991526.708,-1343542.694,-1593224.436

F = 3.5(+)
3083413.257,2619388.122,2258487.038,-540233.730,-992852.007,-1342428.014

F = 4.5(-)
3650499.839,3083413.231,2619427.349,11300.248,-541912.223,-991384.496

F = 5.5(+)
4320594.476,3650482.835,3083453.741,663073.223,9275.116,-540095.874

F = 6.5(-)
5093650.259,4320556.237,3650531.618,1415081.831,660707.822,11435.607

F = 7.5(+)
5969613.312,5093585.484,4320619.876,2267321.360,1412382.793,663207.074

F = 8.5(-)
6948423.182,5969515.830,5093670.738,3219785.585,2264295.741,1415214.750

F = 9.5(+)
8030013.181,6948286.086,5969629.852,4272466.532,3216440.914,2267453.704

F = 10.5(-)
9214310.688,8029828.915,6948436.484,5425354.222,4268810.814,3219917.580

F = 11.5(+)
10501237.446,9214071.129,8030023.768,6678436.400,5421395.913,4272598.326

F = 12.5(-)
11890709.853,10500933.980,9214318.964,8031698.256,6674184.367,5425485.913

F = 13.5(+)
13382639.237,11890333.438,10501243.732,9485122.162,8027161.737,6678568.048

F = 14.5(-)
14976932.123,13382180.468,11890714.410,11038687.408,9480310.715,8031829.899

F = 15.5(+)
16673490.484,14976381.286,13382642.284,12692369.958,11033610.866,9485253.821

F = 16.5(-)
18472211.972,16672837.614,14976933.844,14446142.218,12687038.381,11038819.093

F = 17.5(+)
20372990.139,18471446.899,16673491.036,16299972.823,14440565.849,12692501.670

F = 18.5(-)
22375714.624,20372102.535,18472211.494,18253826.441,16294162.048,14446273.952

F = 19.5(+)
24480271.340,22374694.044,20372988.750,20307663.604,18247791.751,16300104.569

F = 20.5(-)
26686542.620,24479107.258,22461440.550,22375712.430,20301415.558,18253958.188

F = 21.5(+)
28994407.359,26685224.464,24715109.083,24480268.435,22454989.743,20307795.338

F = 22.5(-)
31403741.130,28992924.537,27068616.468,26686539.088,24708466.125,22461572.255

F = 23.5(+)
33914416.285,31402083.060,29521905.326,28994403.275,27061791.953,24715240.745

F = 24.5(-)
36526302.034,33912572.410,32074913.553,31403736.562,29514909.815,27068748.072

F = 25.5(+)
39239264.516,36524261.845,34727574.256,33914411.293,32067757.553,29522036.856

F = 26.5(-)
42053166.849,39237017.567,37479815.700,36526296.673,34720268.208,32075044.994

F = 27.5(+)
44967869.171,42050702.768,40331561.273,39239258.836,37472369.968,34727705.594

F = 28.5(-)
47983228.669,44965177.672,43282729.455,42053160.895,40323986.131,37479946.922

F = 29.5(+)
51099099.596,47980299.556,46333233.803,44967862.983,43275035.082,40331692.366

F = 30.5(-)
54315333.281,51095922.771,49482982.947,47983222.284,46325430.279,43282860.407

F = 31.5(+)
57631778.130,54311898.750,52731880.582,51099093.046,49475080.244,46333364.604

F = 32.5(-)
61048279.621,57628076.002,56079825.483,54315326.597,52723888.569,49483113.586

F = 33.5(+)
64564680.296,61044300.111,59526711.514,57631771.339,56071753.919,52732011.051

F = 34.5(-)
68180819.741,64560413.722,63072427.642,61048272.749,59518570.051,56079955.773

F = 35.5(+)
71896534.571,68176256.528,66716857.964,64564673.364,63064225.827,59526841.617

F = 36.5(-)
75711658.405,71891665.244,70459881.726,68180812.769,66708605.239,63072557.552

F = 37.5(+)
79626021.844,75706473.589,74301373.352,71896527.576,70451587.432,66716987.674

F = 38.5(-)
83639452.443,79620512.261,78241202.474,75711651.404,74293046.734,70460011.232

F = 39.5(+)
87751774.685,83633608.908,82279233.957,79626014.852,78232852.679,74301502.649
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