Table 7. Observed and computed line strengths (cm-2/atm. at 296K) of the (001)-(010) band of H216O observed upper lower observed computed frequency o-c J Ka Kc J Ka Kc strength %s strength (o-c)% Z(001) Z(100) Z(020) 1876.27753 93. 9 3 7 10 3 8 5.43E-07 15. 4.99E-07 8.1 6.69E-04 5.86E-05 -2.09E-05 1913.30647 -92. 9 2 8 10 2 9 1.29E-06 35. 1.13E-06 12.0 1.06E-03 9.78E-06 -2.92E-06 1913.61161 28. 5 2 4 5 4 1 1.74E-06 15. 1.74E-06 -.3 -3.97E-04 -2.00E-03 1.08E-03 1919.23048 -10. 6 4 2 7 4 3 3.52E-06 28. 3.46E-06 1.7 1.75E-03 2.32E-04 -1.22E-04 1935.34344 9. 8 2 7 9 2 8 1.20E-06 4. 1.01E-06 15.8 9.92E-04 1.82E-05 -5.11E-06 1936.22360 74. 8 1 7 9 1 8 2.70E-06 15. 3.02E-06 -12.0 1.74E-03 -4.02E-06 4.85E-06 1936.86250 160. 10 1 10 11 1 11 3.50E-07 15. 4.13E-07 -17.9 6.42E-04 4.88E-07 1.28E-07 1936.87540 82. 10 0 10 11 0 11 1.14E-06 15. 1.24E-06 -8.8 1.11E-03 5.61E-07 -3.74E-07 1946.89060 4. 5 4 2 6 4 3 5.50E-06 9. 5.79E-06 -5.2 2.32E-03 2.15E-04 -1.32E-04 1947.28000 -26. 6 3 4 7 3 5 2.42E-06 5. 2.51E-06 -3.5 1.36E-03 3.61E-04 -1.41E-04 1956.30898 1. 9 1 9 10 1 10 3.30E-06 10. 3.24E-06 1.7 1.80E-03 1.54E-06 -6.34E-07 1956.33015 50. 9 0 9 10 0 10 1.08E-06 10. 1.08E-06 -.1 1.04E-03 6.55E-07 0.00E+00 1957.18703 14. 7 2 6 8 2 7 7.09E-06 5. 7.25E-06 -2.2 2.62E-03 1.09E-04 -3.44E-05 1958.10675 -4. 6 2 4 7 2 5 1.01E-05 4. 9.68E-06 4.2 3.18E-03 -1.28E-04 6.10E-05 1958.61650 -15. 7 1 6 8 1 7 2.20E-06 10. 2.41E-06 -9.7 1.56E-03 -9.84E-06 7.73E-06 1965.56288 -1. 5 3 2 6 3 3 3.15E-06 7. 3.60E-06 -14.3 1.53E-03 6.08E-04 -2.44E-04 1971.34370 -76. 4 1 4 4 3 1 5.74E-07 15. 6.39E-07 -11.2 -3.35E-04 -9.87E-04 5.22E-04 1972.59250 6. 5 3 3 6 3 4 1.29E-05 3. 1.37E-05 -5.8 3.24E-03 7.71E-04 -3.16E-04 1972.98878 29. 4 4 0 5 4 1 6.98E-06 6. 6.47E-06 7.4 2.52E-03 1.34E-04 -1.07E-04 1973.12208 50. 4 4 1 5 4 2 1.88E-06 15. 2.16E-06 -14.7 1.45E-03 7.78E-05 -6.20E-05 1975.77075 73. 8 1 8 9 1 9 2.72E-06 12. 2.57E-06 5.7 1.60E-03 2.15E-06 -4.46E-07 1975.80807 40. 8 0 8 9 0 9 8.14E-06 7. 7.71E-06 5.3 2.77E-03 1.86E-06 6.67E-08 1978.02355 -2. 6 2 5 7 2 6 4.80E-06 11. 4.83E-06 -.6 2.00E-03 2.97E-04 -1.02E-04 1981.02682 1. 6 1 5 7 1 6 1.58E-05 6. 1.57E-05 .8 3.97E-03 -4.73E-05 3.09E-05 1984.78070 37. 5 2 3 6 2 4 6.84E-06 5. 6.83E-06 .2 2.67E-03 -1.06E-04 4.69E-05 *1986.33413 54. 7 7 1 7 7 0 1.12E-06 37. 1.14E-06 -2.2 1.08E-03 -2.88E-05 2.16E-05 1994.10910 -108. 8 1 7 8 3 6 6.17E-07 15. 5.40E-07 12.5 -6.59E-04 -9.31E-05 1.70E-05 1995.24558 14. 7 1 7 8 1 8 1.67E-05 2. 1.66E-05 .8 4.06E-03 9.52E-06 -2.02E-06 1995.31042 -10. 7 0 7 8 0 8 5.80E-06 6. 5.52E-06 4.8 2.35E-03 1.46E-06 4.44E-07 1995.96922 14. 4 3 1 5 3 2 1.86E-05 2. 1.96E-05 -5.4 4.04E-03 6.95E-04 -3.04E-04 2001.88569 -6. 6 3 3 5 5 0 1.02E-05 2. 1.02E-05 -.1 -1.12E-04 -2.28E-04 3.54E-03 2003.63545 -9. 5 1 4 6 1 5 9.63E-06 4. 1.03E-05 -6.6 3.22E-03 -5.39E-05 3.22E-05 2004.18785 8. 5 2 4 6 2 5 1.96E-05 5. 2.03E-05 -3.4 4.89E-03 -5.86E-04 2.00E-04 2012.15415 30. 4 2 2 5 2 3 3.61E-05 2. 3.67E-05 -1.7 6.18E-03 -2.03E-04 8.15E-05 2014.23510 121. 7 0 7 7 2 6 4.44E-07 15. 4.52E-07 -1.8 -6.24E-04 -5.84E-05 9.95E-06 2014.72844 27. 6 1 6 7 1 7 1.05E-05 6. 1.07E-05 -1.7 3.26E-03 1.58E-05 -4.20E-06 2014.83462 30. 6 0 6 7 0 7 3.21E-05 5. 3.20E-05 .2 5.66E-03 1.80E-06 2.60E-06 2019.04610 132. 6 1 5 6 3 4 2.20E-06 15. 1.89E-06 14.1 -1.27E-03 -1.69E-04 6.36E-05 2021.26990 78. 8 6 2 8 6 3 5.62E-07 15. 6.12E-07 -8.9 7.47E-04 1.30E-05 2.22E-05 2022.98790 -42. 4 1 3 4 3 2 1.48E-06 15. 1.69E-06 -14.3 -1.22E-03 -1.99E-04 1.15E-04 2023.18305 99. 7 1 7 7 1 6 1.52E-06 15. 1.50E-06 1.5 1.10E-03 1.64E-04 -4.02E-05 2023.62880 62. 7 6 2 7 6 1 1.90E-06 6. 1.75E-06 7.8 1.30E-03 -7.36E-06 3.11E-05 2023.63910 70. 7 6 1 7 6 2 5.98E-07 15. 5.84E-07 2.4 7.50E-04 -4.24E-06 1.79E-05 2024.38910 -6. 3 3 0 4 3 1 7.04E-06 6. 7.17E-06 -1.8 2.66E-03 7.48E-05 -5.68E-05 2025.25415 -7. 3 3 1 4 3 2 2.15E-05 4. 2.16E-05 -.5 4.62E-03 1.34E-04 -1.01E-04 *2025.89082 30. 6 6 0 6 6 1 6.60E-06 10. 6.06E-06 8.2 2.47E-03 -5.39E-05 4.17E-05 2025.89976 25. 4 2 3 5 2 4 1.34E-05 14. 1.34E-05 .1 3.78E-03 -1.82E-04 5.89E-05 2026.94092 -6. 4 1 3 5 1 4 4.95E-05 8. 5.38E-05 -8.6 7.39E-03 -1.33E-04 7.60E-05 2034.14260 8. 5 1 5 6 1 6 5.56E-05 4. 5.56E-05 .0 7.38E-03 1.18E-04 -3.74E-05 2034.19130 14. 6 0 6 6 2 5 2.86E-06 10. 2.85E-06 .5 -1.57E-03 -1.51E-04 3.91E-05 2034.36267 -12. 5 0 5 6 0 6 1.87E-05 5. 1.85E-05 1.0 4.30E-03 -2.55E-06 4.01E-06 2035.87470 7. 5 2 4 4 4 1 3.10E-07 15. 2.59E-07 16.5 -2.25E-04 -6.62E-04 3.78E-04 2036.00710 36. 1 0 1 2 2 0 3.66E-07 15. 4.32E-07 -18.0 6.47E-04 2.95E-05 -1.89E-05 2040.01669 -3. 3 2 1 4 2 2 1.63E-05 3. 1.77E-05 -8.4 4.25E-03 -7.22E-05 2.18E-05 2048.64945 -3. 3 2 2 4 2 3 5.60E-05 4. 5.60E-05 -.1 7.58E-03 -1.18E-04 2.17E-05 2051.39235 -8. 3 1 2 4 1 3 2.68E-05 3. 2.72E-05 -1.6 5.25E-03 -7.81E-05 4.31E-05 2051.98980 -84. 5 0 5 5 2 4 1.85E-06 10. 1.71E-06 7.4 -1.23E-03 -1.16E-04 3.61E-05 2053.86439 0. 4 0 4 5 0 5 8.47E-05 3. 8.60E-05 -1.5 9.28E-03 -2.22E-05 1.71E-05 2054.43245 3. 4 1 4 5 1 5 2.61E-05 2. 2.62E-05 -.2 5.22E-03 -1.52E-04 5.17E-05 2058.49498 -3. 7 5 3 7 5 2 2.78E-06 15. 3.09E-06 -11.3 1.65E-03 8.94E-05 2.01E-05 2059.76090 71. 7 2 6 7 2 5 2.91E-06 15. 3.14E-06 -7.9 1.27E-03 8.09E-04 -3.10E-04 2060.64657 -10. 6 5 2 6 5 1 2.60E-06 7. 2.63E-06 -1.2 1.58E-03 2.23E-05 2.16E-05 2060.71595 -2. 6 5 1 6 5 2 7.69E-06 6. 7.89E-06 -2.6 2.73E-03 3.87E-05 3.73E-05 2062.55039 19. 5 5 1 5 5 0 1.80E-05 5. 1.84E-05 -2.0 4.30E-03 -7.53E-05 5.87E-05 2062.55690 4. 5 5 0 5 5 1 5.97E-06 3. 6.13E-06 -2.7 2.49E-03 -4.35E-05 3.39E-05 2066.61470 10. 4 0 4 4 2 3 7.56E-06 4. 7.35E-06 2.8 -2.58E-03 -2.12E-04 7.82E-05 2067.77917 11. 2 2 0 3 2 1 5.24E-05 3. 5.26E-05 -.3 7.23E-03 7.07E-05 -5.14E-05 2071.95009 -10. 2 2 1 3 2 2 1.78E-05 3. 1.79E-05 -.8 4.22E-03 5.43E-05 -3.77E-05 2073.37822 3. 3 0 3 4 0 4 3.86E-05 5. 3.92E-05 -1.5 6.27E-03 -2.93E-05 1.85E-05 2073.99122 2. 3 1 3 4 1 4 1.10E-04 3. 1.11E-04 -.8 1.06E-02 -7.74E-05 2.40E-05 2076.03280 0. 5 1 5 5 1 4 1.10E-05 8. 1.02E-05 7.1 2.40E-03 1.37E-03 -5.74E-04 2076.97192 8. 2 1 1 3 1 2 1.01E-04 2. 1.01E-04 -.2 1.01E-02 -8.45E-05 4.54E-05 2082.90739 5. 2 0 2 2 2 1 3.60E-06 10. 3.53E-06 2.0 -1.86E-03 -5.01E-05 3.22E-05 2085.37290 4. 6 2 5 6 2 4 4.90E-06 10. 4.70E-06 4.1 1.12E-03 1.82E-03 -7.79E-04 2086.83550 -6. 7 4 4 7 4 3 4.50E-06 12. 4.61E-06 -2.4 1.82E-03 4.24E-04 -9.44E-05 2090.39830 6. 7 3 5 7 3 4 5.93E-06 6. 5.75E-06 3.0 1.52E-03 1.40E-03 -5.28E-04 2090.89849 7. 6 4 3 6 4 2 3.39E-06 5. 3.86E-06 -13.9 1.77E-03 2.34E-04 -4.40E-05 2092.98835 8. 6 4 2 6 4 3 1.16E-05 3. 1.16E-05 -.1 3.07E-03 4.25E-04 -8.46E-05 2093.31628 -1. 2 0 2 3 0 3 1.38E-04 3. 1.39E-04 -1.0 1.18E-02 -6.57E-05 3.91E-05 2093.40956 2. 5 4 2 5 4 1 2.67E-05 3. 2.64E-05 1.3 4.91E-03 2.46E-04 -2.16E-05 2093.64324 53. 7 4 3 7 4 4 1.37E-06 10. 1.56E-06 -14.2 1.04E-03 2.81E-04 -6.97E-05 2093.86395 16. 5 4 1 5 4 2 9.14E-06 12. 8.80E-06 3.7 2.84E-03 1.44E-04 -1.34E-05 2094.09290 -4. 2 1 2 3 1 3 4.04E-05 3. 4.11E-05 -1.7 6.42E-03 -5.60E-06 -2.83E-06 2095.19829 4. 4 4 1 4 4 0 1.87E-05 5. 1.85E-05 1.2 4.31E-03 -5.92E-05 4.54E-05 2095.25185 6. 4 4 0 4 4 1 5.51E-05 3. 5.53E-05 -.4 7.46E-03 -1.02E-04 7.85E-05 2097.10575 -5. 8 4 4 8 4 5 1.61E-06 16. 1.75E-06 -8.9 9.67E-04 5.06E-04 -1.49E-04 2103.33174 8. 1 1 0 2 1 1 2.94E-05 6. 2.97E-05 -1.0 5.45E-03 0.00E+00 0.00E+00 2104.64520 8. 6 3 4 6 3 3 5.30E-06 12. 5.07E-06 4.3 1.49E-03 1.23E-03 -4.67E-04 2111.50610 95. 5 2 4 5 2 3 2.57E-06 15. 2.20E-06 14.5 3.33E-03 -3.45E-03 1.60E-03 2113.81043 6. 5 3 3 5 3 2 3.33E-05 1. 3.34E-05 -.2 4.24E-03 2.46E-03 -9.26E-04 2114.52861 9. 1 0 1 2 0 2 4.48E-05 3. 4.51E-05 -.6 6.72E-03 -2.42E-05 1.42E-05 2114.63961 13. 1 1 1 2 1 2 9.85E-05 3. 9.83E-05 .2 9.90E-03 4.71E-05 -3.01E-05 2119.23174 12. 4 3 2 4 3 1 2.05E-05 3. 2.17E-05 -5.8 3.96E-03 1.10E-03 -4.05E-04 2120.18510 -316. 4 1 3 3 3 0 4.68E-07 15. 3.88E-07 17.1 -6.50E-04 2.45E-06 2.42E-05 2121.64782 13. 4 3 1 4 3 2 6.47E-05 2. 6.48E-05 -.2 6.66E-03 2.22E-03 -8.31E-04 2121.74485 8. 5 3 2 5 3 3 1.04E-05 5. 1.09E-05 -4.6 2.04E-03 2.07E-03 -8.05E-04 2122.45414 -2. 3 3 1 3 3 0 1.20E-04 3. 1.18E-04 1.4 1.09E-02 -1.13E-04 8.32E-05 2122.85480 2. 3 3 0 3 3 1 3.98E-05 4. 3.95E-05 .8 6.30E-03 -6.36E-05 4.72E-05 2123.17464 13. 3 1 3 3 1 2 2.01E-05 3. 2.11E-05 -5.2 5.01E-03 -8.41E-04 4.29E-04 2127.15135 28. 4 2 3 4 2 2 7.05E-06 4. 7.17E-06 -1.7 3.24E-03 -1.08E-03 5.19E-04 2137.33075 7. 3 2 2 3 2 1 6.60E-05 4. 6.66E-05 -.9 8.68E-03 -1.03E-03 5.10E-04 2137.37165 13. 0 0 0 1 0 1 9.10E-05 3. 8.88E-05 2.4 9.42E-03 0.00E+00 0.00E+00 2139.92689 20. 2 1 2 2 1 1 1.61E-05 4. 1.67E-05 -4.0 4.20E-03 -2.23E-04 1.20E-04 2142.25134 -8. 2 2 1 2 2 0 5.67E-05 6. 5.53E-05 2.4 7.46E-03 -5.45E-05 3.74E-05 2143.98110 -116. 5 1 4 4 3 1 3.01E-07 15. 3.41E-07 -13.4 -6.28E-04 3.96E-05 4.66E-06 2144.80871 19. 2 2 0 2 2 1 1.67E-04 1. 1.66E-04 .3 1.29E-02 -7.69E-05 5.50E-05 2146.72920 37. 7 3 4 7 3 5 3.66E-07 15. 4.38E-07 -19.7 9.77E-04 -6.06E-04 2.91E-04 2149.12983 -41. 3 2 1 3 2 2 2.56E-05 5. 2.36E-05 7.7 5.07E-03 -4.23E-04 2.14E-04 2151.19511 5. 1 1 1 1 1 0 1.25E-04 2. 1.25E-04 .3 1.12E-02 -5.19E-05 3.35E-05 2153.24110 -110. 5 0 5 4 2 2 4.25E-07 15. 4.06E-07 4.6 -7.31E-04 1.33E-04 -3.85E-05 2155.29596 16. 4 0 4 3 2 1 2.33E-06 9. 1.97E-06 15.3 -1.57E-03 2.49E-04 -7.96E-05 2158.10631 10. 4 2 2 4 2 3 2.86E-05 3. 3.01E-05 -5.3 5.89E-03 -8.26E-04 4.22E-04 2162.01461 10. 1 1 0 1 1 1 4.36E-05 4. 4.35E-05 .2 6.60E-03 0.00E+00 0.00E+00 2171.81845 17. 5 2 3 5 2 4 4.38E-06 10. 4.31E-06 1.6 2.25E-03 -3.69E-04 1.95E-04 2172.32391 0. 2 1 1 2 1 2 6.00E-05 2. 5.86E-05 2.3 7.74E-03 -1.74E-04 9.13E-05 2184.74685 8. 1 0 1 0 0 0 3.68E-05 4. 3.66E-05 .6 6.03E-03 3.33E-05 -1.96E-05 2187.37853 13. 3 1 2 3 1 3 1.06E-05 4. 1.04E-05 2.0 3.29E-03 -1.32E-04 6.94E-05 2189.41334 7. 6 2 4 6 2 5 5.26E-06 21. 5.65E-06 -7.4 2.56E-03 -4.10E-04 2.26E-04 2198.60965 11. 2 1 2 1 1 1 4.85E-05 1. 4.75E-05 2.0 6.80E-03 1.72E-04 -8.32E-05 2206.20725 6. 4 1 3 4 1 4 1.82E-05 3. 1.77E-05 2.6 4.30E-03 -1.93E-04 1.02E-04 2206.65612 30. 2 0 2 1 0 1 2.01E-04 5. 1.98E-04 1.5 1.40E-02 8.07E-05 -4.82E-05 2207.38549 3. 6 5 2 5 5 1 1.26E-06 24. 1.17E-06 7.5 1.25E-03 -2.64E-04 9.05E-05 2207.43048 33. 6 5 1 5 5 0 3.96E-06 11. 3.48E-06 12.1 2.17E-03 -4.57E-04 1.57E-04 2208.87953 4. 2 1 1 1 1 0 1.42E-04 3. 1.40E-04 1.5 1.17E-02 2.57E-04 -1.36E-04 2214.36022 8. 3 2 2 2 2 1 1.10E-04 3. 1.11E-04 -1.2 9.75E-03 1.43E-03 -6.33E-04 2215.67292 8. 5 4 2 4 4 1 1.18E-05 5. 1.17E-05 1.1 4.10E-03 -1.07E-03 3.90E-04 2215.94092 46. 5 4 1 4 4 0 3.76E-06 15. 3.89E-06 -3.6 2.37E-03 -6.21E-04 2.26E-04 2217.69779 55. 4 3 2 3 3 1 5.30E-06 15. 4.33E-06 18.2 3.66E-03 -2.62E-03 1.04E-03 2218.52682 24. 3 1 3 2 1 2 2.17E-04 2. 2.15E-04 1.0 1.44E-02 4.95E-04 -2.28E-04 2218.84769 6. 4 3 1 3 3 0 8.87E-06 6. 9.06E-06 -2.2 6.14E-03 -5.21E-03 2.08E-03 2219.43155 8. 3 2 1 2 2 0 3.55E-05 1. 3.56E-05 -.3 5.63E-03 6.14E-04 -2.77E-04 2220.77330 10. 2 2 1 2 0 2 1.55E-06 36. 1.46E-06 5.9 -1.18E-03 -7.82E-05 4.97E-05 2224.76934 25. 3 2 2 3 0 3 9.23E-06 5. 8.91E-06 3.4 -2.97E-03 -8.58E-05 7.54E-05 2225.86483 4. 3 0 3 2 0 2 7.87E-05 3. 7.94E-05 -.9 8.90E-03 3.36E-05 -2.24E-05 2229.80512 25. 7 5 3 6 5 2 2.75E-06 12. 3.21E-06 -16.6 2.10E-03 -4.66E-04 1.61E-04 2229.89659 16. 8 2 6 8 2 7 1.17E-06 24. 1.07E-06 8.5 1.08E-03 -1.14E-04 7.18E-05 2230.04001 -35. 7 5 2 6 5 1 9.33E-07 15. 1.07E-06 -14.2 1.21E-03 -2.69E-04 9.34E-05 2232.60130 30. 4 2 3 4 0 4 3.10E-06 20. 3.18E-06 -2.7 -1.82E-03 2.72E-05 1.35E-05 2233.21245 30. 3 1 2 2 1 1 6.64E-05 2. 6.61E-05 .5 8.05E-03 1.69E-04 -9.17E-05 2236.26472 13. 4 2 3 3 2 2 4.95E-05 2. 4.93E-05 .4 6.37E-03 1.14E-03 -4.92E-04 2237.77784 7. 4 1 4 3 1 3 7.93E-05 3. 7.86E-05 .9 8.43E-03 7.53E-04 -3.21E-04 2239.48908 10. 5 3 3 4 3 2 1.67E-05 4. 1.55E-05 7.5 6.55E-03 -4.32E-03 1.71E-03 2239.50732 7. 6 4 2 5 4 1 1.14E-05 4. 1.16E-05 -1.9 4.16E-03 -1.18E-03 4.32E-04 2242.73435 14. 4 0 4 3 0 3 2.35E-04 2. 2.32E-04 1.1 1.53E-02 0.00E+00 -1.74E-05 2243.44210 46. 5 3 3 5 1 4 3.06E-06 15. 2.71E-06 11.6 -1.41E-03 -3.75E-04 1.45E-04 2244.70750 20. 5 2 4 5 0 5 6.83E-06 11. 6.18E-06 9.4 -2.69E-03 2.42E-04 -4.38E-05 2246.78750 9. 4 2 2 3 2 1 1.36E-04 3. 1.35E-04 1.1 1.11E-02 9.35E-04 -4.28E-04 2248.00359 -11. 6 1 5 6 1 6 6.34E-06 6. 5.83E-06 8.1 2.44E-03 -5.99E-05 3.22E-05 2252.87743 39. 8 5 3 7 5 2 1.79E-06 5. 1.97E-06 -10.2 1.66E-03 -3.87E-04 1.33E-04 2255.29926 25. 5 1 5 4 1 4 1.86E-04 2. 1.82E-04 1.9 1.39E-02 -5.64E-04 2.14E-04 2255.39045 -5. 4 1 3 3 1 2 1.93E-04 2. 1.93E-04 .0 1.38E-02 2.50E-04 -1.39E-04 2257.45752 1. 5 2 4 4 2 3 1.39E-04 2. 1.37E-04 1.3 9.94E-03 3.02E-03 -1.25E-03 2258.69215 2. 5 0 5 4 0 4 6.71E-05 3. 6.60E-05 1.7 8.14E-03 -1.31E-05 -1.47E-06 2260.59320 -5. 7 4 4 6 4 3 8.00E-06 12. 8.16E-06 -2.0 3.49E-03 -9.95E-04 3.59E-04 2260.82700 0. 6 3 4 5 3 3 5.17E-06 18. 5.08E-06 1.7 3.38E-03 -1.83E-03 7.06E-04 2263.98540 20. 7 4 3 6 4 2 2.78E-06 15. 2.53E-06 9.2 1.99E-03 -6.26E-04 2.28E-04 2266.38310 91. 7 4 4 7 2 5 4.25E-07 15. 4.17E-07 2.0 -5.61E-04 -1.55E-04 7.11E-05 2267.88160 77. 7 1 6 7 1 7 9.68E-07 15. 1.03E-06 -6.1 1.02E-03 -1.37E-05 7.52E-06 2272.41070 -11. 6 2 5 5 2 4 1.62E-05 3. 1.54E-05 4.7 4.80E-03 -1.41E-03 5.45E-04 2272.98912 13. 6 1 6 5 1 5 4.80E-05 5. 4.87E-05 -1.5 7.04E-03 -8.19E-05 2.56E-05 2273.06990 6. 5 2 3 4 2 2 3.76E-05 3. 3.87E-05 -3.0 6.02E-03 3.70E-04 -1.73E-04 2274.42960 0. 5 1 4 4 1 3 4.97E-05 2. 5.00E-05 -.5 7.03E-03 9.57E-05 -5.62E-05 2274.71082 13. 6 0 6 5 0 5 1.52E-04 1. 1.49E-04 1.8 1.22E-02 -3.08E-05 2.92E-06 2277.53460 8. 6 3 3 5 3 2 5.26E-05 5. 5.05E-05 4.0 5.43E-03 2.91E-03 -1.23E-03 2286.63587 -8. 8 1 7 8 1 8 1.37E-06 6. 1.50E-06 -9.6 1.23E-03 -8.14E-06 4.40E-06 2289.89414 16. 6 1 5 5 1 4 1.01E-04 2. 9.85E-05 2.5 9.90E-03 7.95E-05 -5.39E-05 2290.15915 20. 7 1 7 6 1 6 9.86E-05 4. 9.91E-05 -.5 1.00E-02 -5.68E-05 1.31E-05 2290.99335 7. 7 0 7 6 0 6 3.24E-05 1. 3.34E-05 -3.2 5.80E-03 -1.49E-05 1.30E-06 2291.06688 21. 7 2 6 6 2 5 4.89E-05 2. 4.74E-05 3.0 7.24E-03 -5.41E-04 1.88E-04 2296.73070 5. 6 2 4 5 2 3 7.86E-05 3. 7.90E-05 -.5 8.69E-03 3.85E-04 -1.86E-04 2297.95261 -64. 3 2 1 2 0 2 4.63E-06 12. 3.92E-06 15.4 1.97E-03 6.61E-05 -5.65E-05 2304.09411 42. 7 3 4 6 3 3 1.12E-05 10. 1.09E-05 2.7 2.90E-03 6.83E-04 -2.80E-04 2307.39690 -16. 8 2 7 7 2 6 9.76E-06 11. 9.45E-06 3.2 3.14E-03 -9.93E-05 2.88E-05 2307.44775 14. 8 0 8 7 0 7 6.05E-05 2. 6.05E-05 -.1 7.80E-03 -1.81E-05 1.03E-06 2316.75860 -12. 7 2 5 6 2 4 1.43E-05 9. 1.48E-05 -3.1 3.78E-03 1.19E-04 -5.97E-05 2322.56993 3. 9 2 8 8 2 7 1.35E-05 15. 1.44E-05 -6.8 3.85E-03 -6.36E-05 1.31E-05 2323.78165 -11. 9 1 9 8 1 8 3.25E-05 4. 3.28E-05 -1.1 5.74E-03 -1.40E-05 4.37E-07 2323.96347 22. 9 0 9 8 0 8 1.14E-05 4. 1.10E-05 3.9 3.32E-03 -6.64E-06 9.09E-08 2373.27780 23. 12 0 12 11 0 11 3.48E-06 15. 2.89E-06 16.9 1.70E-03 -2.10E-06 -1.80E-07 2389.53250 42. 13 1 13 12 1 12 1.30E-06 15. 1.07E-06 17.8 1.03E-03 -1.01E-06 4.98E-08 2407.16620 41. 6 3 3 5 1 4 4.22E-06 15. 4.15E-06 1.6 2.21E-03 -1.36E-04 -3.45E-05 2411.03020 90. 4 4 1 3 2 2 3.94E-07 15. 3.99E-07 -1.3 5.81E-04 1.35E-04 -8.41E-05 2429.93340 60. 6 2 4 5 0 5 4.76E-06 15. 4.19E-06 12.0 2.06E-03 7.94E-05 -9.63E-05 2437.25610 38. 5 4 2 4 2 3 2.00E-06 15. 1.97E-06 1.3 1.30E-03 2.77E-04 -1.68E-04 2437.40210 103. 6 4 2 5 2 3 2.82E-06 15. 2.78E-06 1.4 1.56E-03 2.64E-04 -1.52E-04 2440.41970 17. 7 3 4 6 1 5 1.16E-06 15. 1.28E-06 -10.6 1.19E-03 -1.84E-05 -4.05E-05 2451.96050 44. 7 4 3 6 2 4 9.64E-07 15. 8.91E-07 7.5 8.81E-04 1.36E-04 -7.28E-05 2463.87820 62. 5 5 1 4 3 2 7.14E-07 15. 5.90E-07 17.4 6.77E-04 2.21E-04 -1.30E-04 2464.40580 16. 6 3 4 5 1 5 7.92E-07 15. 7.07E-07 10.7 7.62E-04 1.54E-04 -7.42E-05 2469.21120 50. 8 4 4 7 2 5 2.00E-06 15. 1.96E-06 1.8 1.29E-03 2.03E-04 -9.36E-05 2482.61020 13. 8 3 5 7 1 6 2.05E-06 15. 1.92E-06 6.2 1.44E-03 2.34E-05 -7.19E-05 2497.68860 -7. 7 4 4 6 2 5 1.82E-06 15. 1.59E-06 12.7 1.17E-03 2.22E-04 -1.27E-04 2510.51950 -71. 7 3 5 6 1 6 1.38E-06 15. 1.43E-06 -3.4 1.10E-03 1.97E-04 -1.03E-04 2510.95040 51. 7 5 3 6 3 4 9.19E-07 15. 7.79E-07 15.2 7.97E-04 2.04E-04 -1.18E-04 2514.16810 -77. 8 5 3 7 3 4 7.25E-07 15. 6.25E-07 13.8 7.27E-04 1.48E-04 -8.38E-05 2530.67980 -38. 7 6 2 6 4 3 3.36E-07 15. 2.71E-07 19.2 4.48E-04 1.62E-04 -8.93E-05 2544.41920 -17. 8 2 6 7 0 7 8.28E-07 15. 9.33E-07 -12.6 9.64E-04 8.29E-05 -8.15E-05 2571.91000 -84. 9 4 6 8 2 7 5.02E-07 15. 4.92E-07 2.0 6.53E-04 1.10E-04 -6.20E-05 Computed frequencies (cm-1) derived from energy levels given in ref. 1 for the (010) state and Table 1 for the upper state. o-c, observed minus computed þ 105 (o-c)%, observed minus computed line strengths given in percent. Computed values are derived from constants obtained in this work. Z(020), Z(100), Z(001) are the contributions of the three states from which the computed strengths are derived: S(calc.) = [Z(020)+Z(100)+Z(001)]2